Hydrophilic self-cleaning coating compositions

• US 9,428,666 B2
• Filed: 03/22/2013
• Issued: 08/30/2016
• Est. Priority Date: 03/22/2013
• Status: Expired due to Fees

• Current Assignee: Empire Technology Development LLC (Allied Inventors Management, LLC)
• Original Assignee: Empire Technology Development LLC (Allied Inventors Management, LLC)
• Inventors: Adam, Georgius Abidal, Sjong, Angele, Carlson, William Brenden, Wan, Feng, Londergan, Timothy Martin
• Primary Examiner(s): CHEUNG, WILLIAM K
• Application Number:
  US14/778,977
• Publication Number:
  US 20160046826A1
• Time in Patent Office: 1,257 Days
• Field of Search: 524/186, 526/332
• US Class Current: 1/1
• CPC Class Codes: C04B 14/18 Perlite
• CPC Class Codes: C04B 14/185 expanded
• CPC Class Codes: C04B 14/307 Chromium oxide
• CPC Class Codes: C04B 20/1022 Non-macromolecular compounds
• CPC Class Codes: C04B 2103/30 Water reducers, plasticisers, air-entrainers, flow improvers
• CPC Class Codes: C04B 2103/40 Surface-active agents, dispersants
• CPC Class Codes: C04B 2103/44 Thickening, gelling or viscosity increasing agents
• CPC Class Codes: C04B 2103/54 Pigments; Dyes
• CPC Class Codes: C04B 2103/67 Biocides
• CPC Class Codes: C04B 2111/00482 Coating or impregnation materials
• CPC Class Codes: C04B 2111/2069 Self-cleaning materials, e.g. using lotus effect
• CPC Class Codes: C04B 22/00 Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators , shrinkage compensating agents
• CPC Class Codes: C04B 24/12 Nitrogen containing compounds organic derivatives of hydrazine hydrazine C04B22/00
• CPC Class Codes: C04B 24/122 Hydroxy amines
• CPC Class Codes: C04B 24/32 Polyethers, e.g. alkylphenol polyglycolether
• CPC Class Codes: C04B 24/383 Cellulose or derivatives thereof
• CPC Class Codes: C04B 26/02 Macromolecular compounds
• CPC Class Codes: C04B 26/04 obtained by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: C04B 26/06 Acrylates
• CPC Class Codes: C04B 26/32 containing silicon
• CPC Class Codes: C08K 5/17 : Amines; Quaternary ammonium compounds
• CPC Class Codes: C08K 7/26 : Silicon- containing compounds
• CPC Class Codes: C08K 9/04 : Ingredients treated with organic substances treated with macromolecular compounds C08K9/08
• CPC Class Codes: C09D 133/12 : Homopolymers or copolymers of methyl methacrylate
• CPC Class Codes: C09D 5/1687 : Use of special additives

Abstract

Hydrophilic, self-cleaning coating compositions and methods to make and use the compositions are disclosed. The coatings comprise perlite and/or expanded perlite that are activated with hydrophilic agents. The perlites when incorporated in paints provide hydrophilic, self-cleaning and/or biocidal property to the coating.

Claims

1. A coating composition, comprising:

at least one polymeric binder;

an activated perlite or an activated expanded perlite dispersed in the at least one polymeric binder; and

a hydrophilic activating agent on the activated perlite or activated expanded perlite.

2. The coating composition of claim 1, wherein the hydrophilic activating agent comprises an amine, ammonia, a hydroxylamine, ethanolamine, an ethanolamine derivative, a hydrazine, a hydrazine derivative, a quaternary ammonium salt, or any combination thereof.

3. The coating composition of claim 1, wherein the activated perlite or the activated expanded perlite further comprises transition metal ions.

4. The coating composition of claim 1, further comprising a solvent, a pigment, a coalescing agent, a rheology modifier, a plasticizer, a surfactant, or any combination thereof.

5. The coating composition of claim 1, further comprising a coalescing agent comprising a block copolymer surfactant including ethylene glycol butyl ether, diethylene glycol butyl ether, triethylene glycol butyl ether, or any combination thereof.

6. The coating composition of claim 1, wherein the at least one polymeric binder includes silicone polymers, organic polymers, or both.

7. The coating composition of claim 1, wherein the at least one polymeric binder includes a polymer of alkylacrylate, alkyl methacrylate, allyl methacrylate, acrylic acid, methacrylic acid, acrylamide, 2-hydroxyethyl methacrylate, 2-hydroxypropyl methacrylate, thioethyl methacrylate, vinyl methacrylate, vinyl benzene, 2-hydroxyethyl acrylate, butyl acrylate, 2-ethylhexyl acrylate, vinyltrimethoxysilane, vinyltriethoxysilane, vinyl formate, vinyl acetate, vinyl propionate, vinyl butyrate, vinyl hexanoate, vinyltoluene, α

-methyl styrene, chlorostyrene, or styrenesulfonic acid, a copolymer of any of the foregoing, or any combination thereof.

8. The coating composition of claim 1, wherein the activated perlite or the activated expanded perlite is present at about 1 weight percent to about 15 weight percent of the coating composition.

23. The coating composition of claim 1, wherein the activated perlite or activated expanded perlite dispersed in the at least one polymeric binder is present at an outer surface of the coating composition.

24. The coating composition of claim 1, further comprising a coalescing agent, wherein the activated perlite or activated expanded perlite dispersed in the at least one polymeric binder is associated with the coalescing agent and the coalescing agent is present in the coating composition at an outer surface of the coating composition.

9. A method of coating a substrate, the method comprising:

applying a coating composition to the substrate, wherein the coating composition includes;

at least one polymeric binder;

an activated perlite or an activated expanded perlite dispersed in the at least one polymeric binder; and

a hydrophilic activating agent on the activated perlite or activated expanded perlite.

10. The method of claim 9, wherein the hydrophilic activating agent comprises an amine, ammonia, a hydroxylamine, ethanolamine, an ethanolamine derivative, a hydrazine, a hydrazine derivative, a quaternary ammonium salt, or any combination thereof.

11. The method of claim 9, wherein the activated perlite or the activated expanded perlite further comprises transition metal ions.

12. The method of claim 9, wherein applying the coating composition includes applying the coating composition as a decorative coating, an industrial coating, a protective coating, a UV-protective coating, a self-cleaning coating, a biocidal coating, or any combination thereof.

13. The method of claim 9, wherein applying the coating composition to the substrate comprises applying the coating by one or more of the following:

brushing the coating composition on the substrate;

dipping the substrate in the coating composition;

spraying the coating composition on the substrate;

spreading the coating composition on the substrate; and

rolling the coating composition on the substrate.

14. The method of claim 9, wherein applying the coating composition to the substrate includes applying the coating composition on a wall, a pipe, or a vessel.

25. The method of claim 9, further comprising:

wherein the coating composition includes a coalescing agent, and

causing at least some of the coalescing agent and the activated perlite or activated expanded perlite to migrate to a surface of the coating composition.

26. The method of claim 25, wherein causing at least some of the coalescing agent and the activated perlite or activated expanded perlite to migrate to a surface of the coating composition includes curing the coating composition.

27. The method of claim 9, further comprising, prior to applying a coating composition to the substrate, applying a primer coating to the substrate to provide a bond between the coating composition and the substrate.

28. The method of claim 9, wherein:

the coating composition further includes a coalescing agent, and

the activated perlite or activated expanded perlite dispersed in the at least one polymeric binder is associated with the coalescing agent and the coalescing agent is present in the coating composition at an outer surface of the coating composition.

15. A coated article, comprising:

a substrate; and

a coating composition on the substrate, wherein the coating composition includes;

at least one polymeric binder;

an activated perlite or an activated expanded perlite dispersed in the at least one polymeric binder; and

a hydrophilic activating agent on the activated perlite or activated expanded perlite.

29. The coated article of claim 15, wherein the activated perlite or activated expanded perlite dispersed in the at least one polymeric binder is present at an outer surface of the coating composition.

30. The coated article of claim 15, wherein:

the coating composition further includes a coalescing agent, and

the activated perlite or activated expanded perlite dispersed in the at least one polymeric binder is associated with the coalescing agent and the coalescing agent is present in the coating composition at an outer surface of the coating composition.

16. A method of making a coating composition, the method comprising:

contacting a perlite or an expanded perlite with a hydrophilic activating agent to form an activated perlite or an activated expanded perlite; and

adding the activated perlite or the activated expanded perlite to a composition, wherein the composition includes at least one polymeric binder and a liquid medium.

17. The method of claim 16, wherein contacting the perlite or the expanded perlite with the hydrophilic activating agent includes contacting the perlite or the expanded perlite with an amine, ammonia, a hydroxylamine, ethanolamine, an ethanolamine derivative, a hydrazine, a hydrazine derivative, a quaternary ammonium salt, or any combination thereof.

18. The method of claim 16, wherein contacting the perlite or the expanded perlite with the hydrophilic activating agent comprises mixing the perlite or the expanded perlite with the hydrophilic activating agent for about 0.5 hour to about 4 hours.

19. The method of claim 18, further comprising removing the unreacted hydrophilic activating agent.

20. The method of claim 16, further comprising adding to the composition a solvent, a pigment, a coalescing agent, a rheology modifier, a plasticizer, a surfactant, or any combination thereof.

21. The method of claim 16, further comprising mixing a coalescing agent in the composition, the coalescing agent comprising a block copolymer surfactant including ethylene glycol butyl ether, diethylene glycol butyl ether, triethylene glycol butyl ether, or any combination thereof.

22. The method of claim 16, wherein adding the activated perlite or the activated expanded perlite to the coating composition comprises adding the activated perlite or the activated expanded perlite in an amount of about 1 weight percent to about 15 weight percent of the coating composition.