CNT/fluoropolymer coating composition

• US 9,441,131 B2
• Filed: 08/26/2008
• Issued: 09/13/2016
• Est. Priority Date: 08/26/2008
• Status: Active Grant

• Current Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Original Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Inventors: Qi, Yu, Hu, Nan-Xing, Gardner, Sandra, Skorokhod, Vlad, Zhang, Qi
• Primary Examiner(s): Shosho, Callie
• Assistant Examiner(s): ENGLISH, PATRICK NOLAND
• Application Number:
  US12/198,460
• Publication Number:
  US 20100055450A1
• Time in Patent Office: 2,940 Days
• Field of Search: None
• US Class Current: 1/1
• CPC Class Codes: C08K 3/041 Carbon nanotubes
• CPC Class Codes: C08K 5/005 Stabilisers against oxidation, heat, light, ozone
• CPC Class Codes: C09D 127/12 containing fluorine atoms
• CPC Class Codes: C09D 127/18 Homopolymers or copolymers of tetrafluoroethene
• CPC Class Codes: Y10T 428/265 1 mil or less

Abstract

Exemplary embodiments provide nanotube-containing coating compositions and methods for making and using the coating compositions. In an exemplary embodiment, the coating composition can include a plurality of nanotubes (e.g., carbon nanotubes (CNTs)) dispersed stably and uniformly in a polymer matrix containing fluoropolymers. The coating composition can further include stabilizers to allow a stable and/or uniform dispersion of the plurality of nanotubes in the fluoropolymers. The nanotube coating composition can be coated on an article surface to improve mechanical robustness, and electrical and thermal conductivity of the coated article. The coated article can be used as, for example, a fuser member, a fixing member, a pressure roller, or a release agent donor member in an electrostatographic printing machine or process.

Claims

1. A coated article comprising:

a substrate, and

a coated layer disposed over the substrate and formed from a coating composition applied on the substrate, the coated layer having a thickness ranging from about 5 microns to about 20 microns, wherein the coating composition comprises;

a polyfluoroalkoxypolytetrafluorethylene fluoropolymer;

a plurality of nanotubes dispersed in a media; and

a stabilizer mixed with the fluoropolymer and the plurality of nanotubes in the media, the stabilizer being a partially neutralized polyallylamine polymer comprising i) an amino substituent and ii) an ammonium ion substituent or salt thereof at a pH value ranging from 5 to 9, the stabilizer allowing a stable dispersion of the plurality of nanotubes in the media and in the fluoropolymer, the stabilizer having a molecular weight ranging from 300 to about 100,000,

wherein the coated article is one of a fuser roll, a fixing roll, a pressure roller, and a release agent donor roll for an electrostatographic device.

2. The coated article of claim 1, wherein each of the plurality of nanotubes comprises a single wall carbon nanotube (SWCNT), a multi-wall carbon nanotube (MWCNT), or the mixtures thereof.

3. The coated article of claim 1, wherein each of the plurality of nanotubes has an inside diameter ranging from about 0.5 nanometer to about 20 nanometers as well as an outside diameter ranging from about 1 nanometer to about 80 nanometers, and has an aspect ratio ranging from about 1 to about 10000.

4. The coated article of claim 1, wherein the media for the plurality of nanotubes is a liquid selected from the group consisting of an alcohol, an aliphatic hydrocarbon of from C5 to about C18, an aromatic hydrocarbon of from C6 to C18, an ether, a ketone, an amide, and mixtures thereof.

5. The coated article of claim 1, wherein the plurality of nanotubes is present in an amount from about 0.01 percent to about 20 percent by weight of the fluoropolymer.

6. The coated article of claim 1, wherein the fluoropolymer is in a form of colloid dispersion, latex, suspension, or mixtures thereof.

7. The coated article of claim 1, wherein the fluoropolymer is in a form of a particle dispersion with an average overall particle size ranging from about 10 nanometers to about 5000 nanometers.

8. The coated article of claim 1, further comprising one or more filler particles, the filler particles comprising metal oxides, silicon carbide, boron nitride, or graphite, wherein the metal oxides are selected from the group consisting of silicon oxide, aluminum oxide, zirconium oxide, zinc oxide, tin oxide, iron oxide, magnesium oxide, manganese oxide, nickel oxide, copper oxide, antimony pentoxide, indium tin oxide, and mixtures thereof.

9. The coated article of claim 1, comprising,

the polyfluoroalkoxypolytetrafluorethylene fluoropolymer comprising a plurality of fluoropolymer latex particles in a concentration of about 10 percent to about 50 percent by weight of the coating composition,

the plurality of carbon nanotubes in a concentration of about 0.1 percent to about 10 percent by weight of the coating composition,

the partially neutralized polyallyamine stabilizer in a concentration of about 0.1 percent to about 10 percent by weight of the coating composition,

a water media of about 50 percent to about 90 percent by weight of the coating composition, and

optionally, one or more fillers of about 0.5 percent to 10 percent by weight of the coating composition.

10. The coated article of claim 1, wherein the fluoropolymer comprises a mixture of a plurality of small fluoropolymer particles, having an average small particle size ranging from about 50 nanometers to about 500 nanometers, and a plurality of large fluoropolymer particles, having an average large particle size ranging from about 1 micrometer to about 50 micrometers.

11. The coated article of claim 1, wherein the pH value ranges from 8 to 9.

12. A coated article comprising:

a substrate, and

a coated layer disposed over the substrate and formed from a coating composition applied on the substrate, wherein the coating composition comprises a polyfluoroalkoxypolytetrafluorethylene fluoropolymer, a plurality of nanotubes dispersed in a media, and a stabilizer mixed with the fluoropolymer and the plurality of nanotubes in the media, the stabilizer being a partially neutralized polyallylamine polymer comprising i) an amino substituent and ii) an ammonium ion substituent or salt thereof at a pH value of 5 to 9, the stabilizer allowing a stable dispersion of the plurality of nanotubes in the media and in the fluoropolymer, wherein the fluoropolymer comprises a mixture of a plurality of small fluoropolymer particles, having an average small particle size ranging from about 50 nanometers to about 500 nanometers, and a plurality of large fluoropolymer particles, having an average large particle size ranging from about 1 micrometer to about 50 micrometers,

wherein the coated layer has a thickness ranging from about 5 microns to about 20 microns, and

wherein the coated article is one of a fuser roll, a fixing roll, a pressure roller, and a release agent donor roll for an electrostatographic device.

13. The coated article of claim 12, wherein the coated layer is formed by heating at a temperature ranging from about 200°

C. to about 400°

C.

14. The coated article of claim 12, wherein the coated layer has a surface resistivity of about 10⁸ Ω

/sq or less.

15. The coated article of claim 12, wherein the substrate is formed of a material selected from the group consisting of metals, plastics, and ceramics,

wherein the metals are selected from the group consisting of aluminum, anodized aluminum, steel, nickel, copper, and mixtures thereof, and

wherein the plastics are selected from the group consisting of polyimides, polyester, PEEK, poly(arylene ether)s, polyam ides and mixtures thereof.

16. The coated article of claim 12, wherein the substrate is in a form of a cylinder, a belt or a sheet.

17. The coated article of claim 12, further comprising one or more functional layers disposed between the substrate and the coated layer.

18. The coated article of claim 12, wherein the media for the plurality of nanotubes is a liquid selected from the group consisting of an alcohol, an aliphatic hydrocarbon of from C5 to about C18, an aromatic hydrocarbon of from C6 to C18, an ether, a ketone, an amide, and mixtures thereof.

19. The coated article of claim 12, wherein the pH value ranges from 8 to 9.

20. A coated article comprising:

a substrate, and

a coated layer disposed over the substrate and formed from a coating composition applied on the substrate, the coated layer having a thickness ranging from about 5 microns to about 20 microns,

wherein the coating composition comprises;

a polyfluoroalkoxypolytetrafluorethylene fluoropolymer;

a plurality of nanotubes dispersed in a media; and

a stabilizer mixed with the fluoropolymer and the plurality of nanotubes in the media, the stabilizer being a partially neutralized polyallylamine comprising i) an amino substituent and ii) an ammonium ion substituent or salt thereof at a pH value ranging from 5 to 9, the stabilizer allowing a stable dispersion of the plurality of nanotubes in the media and in the fluoropolymer,

wherein the coated article is one of a fuser roll, a fixing roll, a pressure roller, and a release agent donor roll for an electrostatographic device.

21. The coated article of claim 20, comprising,

the polyfluoroalkoxypolytetrafluorethylene fluoropolymer comprising a plurality of fluoropolymer latex particles in a concentration of about 10 percent to about 50 percent by weight of the coating composition,

the plurality of carbon nanotubes in a concentration of about 0.1 percent to about 10 percent by weight of the coating composition,

the partially neutralized polyallyamine stabilizer in a concentration of about 0.1 percent to about 10 percent by weight of the coating composition,

a water media of about 50 percent to about 90 percent by weight of the coating composition, and

optionally, one or more fillers of about 0.5 percent to 10 percent by weight of the coating composition.

22. The coated article of claim 20, wherein the media for the plurality of nanotubes is a liquid selected from the group consisting of an alcohol, an aliphatic hydrocarbon of from C5 to about C18, an aromatic hydrocarbon of from C6 to C18, an ether, a ketone, an amide, and mixtures thereof.

23. The coated article of claim 20, wherein the pH value ranges from 8 to 9.