Methanol carbonylation system with multiple absorber feed options
First Claim
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1. An apparatus for producing acetic acid comprising:
- (a) a reactor for carbonylating methanol or its reactive derivatives, the reactor containing a catalyst selected from rhodium catalysts, iridium catalysts and mixtures thereof, and a methyl iodide promoter in an acetic acid reaction mixture;
(b) a feed system for providing carbon monoxide and methanol or its reactive derivatives to the reactor;
(c) a flash system configured to receive a stream of the reaction mixture and separate it into (i) at least a first liquid recycle stream, and (ii) a crude process stream containing acetic acid;
(d) a first distillation column coupled to the flash system, the first distillation column being adapted to separate low boiling components including methyl iodide from the crude process stream, and generate a purified process stream, the first distillation column and optionally the reactor and flash system also operating to generate a vent gas stream comprising volatile organic components including methyl iodide;
(e) an absorber tower adapted for receiving the vent gas stream and removing methyl iodide therefrom with a first or a second scrubber solvent, the first and second scrubber solvents being different solvents, the absorber tower also being coupled to a first scrubber solvent source and a second scrubber solvent source which are capable of supplying the different first and second scrubber solvents; and
(f) a switching system for alternatively providing the first or the second scrubber solvents to the absorber tower from either the first scrubber solvent source or the second scrubber solvent source;
wherein the apparatus is configured such that the first and second scrubber solvents are supplied to the top of the absorber tower only.
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Abstract
A methanol carbonylation system 10 includes an absorber tower 75 adapted for receiving a vent gas stream and removing methyl iodide therefrom with a scrubber solvent, the absorber tower being coupled to first and second scrubber solvent sources 16, 56 which are capable of supplying different first and second scrubber solvents. A switching system including valves 90, 92, 94, 96, 98 alternatively provides first or second scrubber solvents to the absorber tower and returns the used solvent and sorbed material to the carbonylation system to accommodate different operating modes.
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Citations
19 Claims
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1. An apparatus for producing acetic acid comprising:
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(a) a reactor for carbonylating methanol or its reactive derivatives, the reactor containing a catalyst selected from rhodium catalysts, iridium catalysts and mixtures thereof, and a methyl iodide promoter in an acetic acid reaction mixture; (b) a feed system for providing carbon monoxide and methanol or its reactive derivatives to the reactor; (c) a flash system configured to receive a stream of the reaction mixture and separate it into (i) at least a first liquid recycle stream, and (ii) a crude process stream containing acetic acid;
(d) a first distillation column coupled to the flash system, the first distillation column being adapted to separate low boiling components including methyl iodide from the crude process stream, and generate a purified process stream, the first distillation column and optionally the reactor and flash system also operating to generate a vent gas stream comprising volatile organic components including methyl iodide;(e) an absorber tower adapted for receiving the vent gas stream and removing methyl iodide therefrom with a first or a second scrubber solvent, the first and second scrubber solvents being different solvents, the absorber tower also being coupled to a first scrubber solvent source and a second scrubber solvent source which are capable of supplying the different first and second scrubber solvents; and (f) a switching system for alternatively providing the first or the second scrubber solvents to the absorber tower from either the first scrubber solvent source or the second scrubber solvent source; wherein the apparatus is configured such that the first and second scrubber solvents are supplied to the top of the absorber tower only. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18)
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19. An apparatus for producing acetic acid comprising:
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(a) a reactor for carbonylating methanol or its reactive derivatives, the reactor containing a catalyst selected from rhodium catalysts, iridium catalysts and mixtures thereof, and a methyl iodide promoter in an acetic acid reaction mixture; (b) a feed system for providing carbon monoxide and methanol or its reactive derivatives to the reactor; (c) a flash system configured to receive a stream of the reaction mixture and separate it into (i) at least a first liquid recycle stream, and (ii) a crude process stream containing acetic acid; (d) a first distillation column coupled to the flash system, the first distillation column being adapted to separate low boiling components including methyl iodide from the crude process stream, and generate a purified process stream, the first distillation column and optionally the reactor and flash system also operating to generate a vent gas stream comprising volatile organic components including methyl iodide; (e) optionally, a second distillation column adapted to receive the purified process stream and remove water therefrom to generate a purified and dried process stream; (f) an absorber tower adapted for receiving the vent gas stream and removing methyl iodide therefrom with a first or a second scrubber solvent, the first scrubber solvent consisting essentially of methanol and the second scrubber solvent consisting essentially of acetic acid, the absorber tower also being coupled to a first scrubber solvent source and a second scrubber solvent source which are capable of supplying the first and second scrubber solvents; and (g) a switching system for alternatively providing the first or the second scrubber solvents to the absorber tower from either the first scrubber solvent source or the second scrubber solvent source, wherein further a return stream from the absorber tower is selectively coupled by the switching system to both of the following;
(i) the reactor or the feed system to the reactor; and
(ii) the first distillation column or the second distillation column such that the return stream may be alternatively provided to either;
(i) the reactor or the feed system to the reactor or (ii) the first distillation column,wherein the apparatus is configured such that the first and second scrubber solvents are supplied to the top of the absorber tower only.
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Specification