Method of preparing a slow release fertilizer

• US 9,446,993 B2
• Filed: 09/26/2012
• Issued: 09/20/2016
• Est. Priority Date: 09/26/2012
• Status: Active Grant

• Current Assignee: Upm-Kymmene Corporation
• Original Assignee: Upm-Kymmene Corporation
• Inventors: Li, Zhiyong, Zhang, Yan
• Primary Examiner(s): Smith, Jennifer A
• Application Number:
  US14/430,696
• Publication Number:
  US 20150259261A1
• Time in Patent Office: 1,455 Days
• US Class Current: 1/1
• CPC Class Codes: C05C 9/005 Post-treatment
• CPC Class Codes: C05G 5/30 Layered or coated, e.g. dust-preventing coatings
• CPC Class Codes: C05G 5/37 layered or coated with a polymer
• CPC Class Codes: C08K 3/346 Clay
• CPC Class Codes: C08K 5/06 Ethers; Acetals; Ketals; Ortho-esters
• CPC Class Codes: C08K 5/09 Carboxylic acids; Metal salts thereof; Anhydrides thereof
• CPC Class Codes: C08K 5/12 of cyclic polycarboxylic acids
• CPC Class Codes: C09D 197/005 Lignin

Abstract

Provided is a method for preparing slow release fertilizer with a coated surface. Furthermore, a formulation of the coating layer 1 comprises lignin, alkenylsuccinic anhydride, stearic acid, polyethylene glycol (PEG)-2000 and kaolin.

Claims

1. A method for preparing a slow-release fertilizer comprising the steps of:

a) dissolving lignin compounds, alkenylsuccinic anhydride, stearic acid and PEG-2000 in a solvent heated to 50-100°

C.;

b) forming a coating on the surface of urea granules using the solution obtained in step a) and drying;

c) immersing the coated granules obtained in step b) in alkenylsuccinic anhydride;

d) adsorbing kaolin onto the surface of the coated granules, wherein the coating materials are 20-80% of the total weight of the coated granules.

2. The method of claim 1, wherein:

30 to 70 parts by weight of the lignin compounds, 5 to 10 parts by weight of alkenylsuccinic anhydride, 5 to 15 parts by weight of stearic acid and 5 to 15 parts by weight of PEG-2000 are dissolved in the solvent heated to 50-100°

C.;

2 to 10 parts by weight of alkenylsuccinic anhydride are absorbed onto the coated granules; and

2 to 10 parts by weight of kaolin are adsorbed onto the surface of the coated granules.

3. The method of claim 1, wherein the solvent is selected from 1,4-dioxane, tetrahydrofuran, N,N-dimethylformamide, ethanol, methanol, hexane dimethylsulfoxide, 2-methoxyethanol or the mixture thereof.

4. The method of claim 1, wherein the lignin compounds have a lignin content higher than 80% and a weight average molecular weight more than 1500 g/mol.

5. The method of claim 1, wherein the solvent to lignin compounds ratio by weight is from 3:

1 to 7;

1.

6. The method of claim 1, wherein the drying is done at temperature in a range from 40°

C. to the boiling point of the solvent.

7. The method of claim 1, wherein the drying is done at 40-60°

C. at a pressure of 10-101 KPa.

8. The method of claim 1, wherein forming the coating on the surface of the urea granules is achieved by immersing the urea granules in the solution obtained in step a) or by spraying the solution obtained in step a) on the surface of the urea granules.

11. A fertilizer obtained by the method in claim 1.

12. The method claim 1, wherein the drying is done with hot air of 40-60°

C. with pressure of 1-7 bar.

13. The method of claim 1, wherein the alkenylsuccinic anhydride has a linear alkenyl chain of 14 to 20 carbon atoms.

9. A formulation of a coating material comprising 30-70% by weight of the lignin compounds, 10-25% by weight of alkenylsuccinic anhydride, 5-20% by weight of stearic acid, 5-15% by weight of polyethylene glycol PEG2000 and 2-15% by weight of kaolin, wherein all the weight percentages are based on a total weight of the coating material.

10. The formulation of claim 9, wherein the alkenylsuccinic anhyrdride has a linear alkenyl chain of 14 to 20 carbon atoms.