Organic electroluminescent materials and devices

• US 9,450,198 B2
• Filed: 04/15/2014
• Issued: 09/20/2016
• Est. Priority Date: 04/15/2014
• Status: Active Grant

• Current Assignee: Universal Display Corporation
• Original Assignee: Universal Display Corporation
• Inventors: Yamamoto, Hitoshi, Weaver, Michael S.
• Primary Examiner(s): RAABE, CHRISTOPHER M
• Application Number:
  US14/253,804
• Publication Number:
  US 20150295199A1
• Time in Patent Office: 889 Days
• Field of Search: 313/504
• US Class Current: 1/1
• CPC Class Codes: H10K 2101/10 Triplet emission
• CPC Class Codes: H10K 50/11 characterised by the electroluminescent [EL] layers
• CPC Class Codes: H10K 50/12 comprising dopants
• CPC Class Codes: H10K 50/125 specially adapted for multicolour light emission, e.g. for emitting white light

Abstract

An OLED includes a suppression mechanism and multiple dopants in its organic emissive layer. The organic emissive layer includes a host, a first compound capable of phosphorescent emission at room temperature, and a second compound capable of phosphorescent emission at room temperature. The suppression mechanism is capable of preferentially reducing the emission of light emitted by the second compound. The organic emissive layer may also contain a third compound capable of phosphorescent emission at room temperature.

Claims

1. A device, comprising

an anode;

a cathode; and

an organic emissive layer disposed between the anode and the cathode comprising;

a host;

a first compound capable of phosphorescent emission at room temperature present in an amount less than 3 weight %, the first compound having a global maximum in its visible emission spectrum at a first wavelength;

a second compound capable of phosphorescent emission at room temperature, the second compound having a global maximum in its visible emission spectrum at a second wavelength, the first wavelength longer than the second wavelength;

wherein the first compound, the second compound and the host are mixed in the emissive layer; and

a suppression mechanism capable of preferentially reducing emission of light emitted by the second compound;

wherein the difference between the first wavelength and the second wavelength is between 0 nm and 80 nm.

2. The device of claim 1, wherein the intensity of light emitted by the device at the second wavelength divided by the intensity of light emitted by the device at the first wavelength is less than 0.01.

3. The device of claim 1, wherein the difference between the first wavelength and the second wavelength is between 20 nm and 80 nm.

4. The device of claim 1, wherein the difference between the first wavelength and the second wavelength is between 40 nm and 80 nm.

5. The device of claim 1, wherein:

the first compound is capable of red phosphorescent emission, and the first wavelength is in the range 590-700 nm.

6. The device of claim 5, wherein the second wavelength is in the range 510-590 nm.

7. The device of claim 1, wherein the device emits light having a 1931 CIE coordinate of [0.66±

0.04, 0.34±

0.04].

8. The device of claim 1, wherein:

the first compound is capable of yellow phosphorescent emission, and the first wavelength is in the range 560-590 nm.

9. The device of claim 8, wherein the second wavelength is in the range 480-560 nm.

10. The device of claim 8, wherein the device emits light having a 1931 CIE coordinate of [0.44±

0.04, 0.55±

0.04].

11. The device of claim 1, wherein:

the first compound is capable of green phosphorescent emission, and the first wavelength is in the range 500-560 nm.

12. The device of claim 11, wherein the second wavelength is in the range 420-500 nm.

13. The device of claim 11, wherein the device emits light having a 1931 CIE coordinate of [0.25±

0.15, 0.65±

0.15].

14. The device of claim 1, wherein the suppression mechanism is selected from the group consisting of a micro-cavity, down-conversion filter, and an optical filter.

15. The device of claim 1, wherein the first compound is present in an amount between 1 to 2.5 weight %.

16. The device of claim 1, wherein the emissive layer does not include any compound capable of phosphorescent emission at room temperature other than the first and second compounds.

17. A device, comprising:

an anode;

a cathode; and

an organic light emission layer disposed between the anode and the cathode comprising;

a host;

a first compound capable of phosphorescent emission at room temperature present in an amount less than 3 weight %, the first compound having a having a global maximum in its visible emission spectrum at a first wavelength;

a second compound capable of phosphorescent emission at room temperature, the second compound having a global maximum in its visible emission spectrum at a second wavelength, the first wavelength longer than the second wavelength;

a third compound capable of phosphorescent emission at room temperature, the third compound having a global maximum in its visible emission spectrum at a third wavelength, the second wavelength longer than the third wavelength;

wherein the first compound, the second compound, the third compound and the host are mixed in the emissive layer; and

a suppression mechanism capable of preferentially reducing emission of light emitted by the second compound and the third compound.

18. A device, comprising

an anode;

a cathode; and

an organic light emission layer disposed between the anode and the cathode comprising;

a host;

a first compound capable of phosphorescent emission at room temperature present in an amount less than 3 weight %, the first compound having a global maximum in its visible emission spectrum at a first wavelength;

a second compound capable of phosphorescent emission at room temperature, the second compound having a global maximum in its visible emission spectrum at a second wavelength, the first wavelength longer than the second wavelength;

wherein the first compound, the second compound and the host are mixed in the emissive layer; and

a suppression mechanism capable of preferentially reducing emission of light emitted by the second compound;

wherein the difference between the first wavelength and the second wavelength is between 40 and 80 nm.