Biological decontamination gel and method for decontaminating surfaces by using this gel

• US 9,451,765 B2
• Filed: 06/29/2011
• Issued: 09/27/2016
• Est. Priority Date: 07/02/2010
• Status: Active Grant

• Current Assignee: Commissariat a L'Energie Atomique (French Alternative Energies and Atomic Energy Commission)
• Original Assignee: Commissariat a L'Energie Atomique (French Alternative Energies and Atomic Energy Commission)
• Inventors: Cuer, Frederic, Faure, Sylvain
• Primary Examiner(s): Joyner, Kevin
• Application Number:
  US13/806,856
• Publication Number:
  US 20130171024A1
• Time in Patent Office: 1,917 Days
• Field of Search: 422/28, 424/722
• US Class Current: 1/1
• CPC Class Codes: A01N 25/04 Dispersions, emulsions, suspoemulsions, suspension concentrates or gels foams A01N25/16
• CPC Class Codes: A01N 43/40 six-membered rings
• CPC Class Codes: A01N 59/00 Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
• CPC Class Codes: A61L 2/23 Solid substances, e.g. granules, powders, blocks, tablets

Abstract

A biological decontamination gel, consisting of a colloidal solution comprising from 5 to 30% by mass, preferably 5 to 25% by mass, still preferably 8 to 20% by mass, based on the mass of the gel, of at least one inorganic viscosifying agent: 0.5 to 10 mol/L of gel, preferably 1 to 10 mol/L of gel, of at least one active biological decontamination agent; 0.05 to 5% by mass, preferably 0.05 to 2% by mass, based on the mass of the gel, of at least one super-absorbent polymer; 0.1 to 2% by mass, based on the mass of the gel, of at least one surfactant; and the remainder of solvent.

A biological decontamination method applying this gel.

Claims

1. A method for biological decontamination of a surface of a solid substrate contaminated by at least one biological species found on said surface and possibly under said surface in the depth of the substrate, wherein at least one cycle is carried out, consisting essentially of the following successive steps:

a) applying a biological decontamination gel, consisting of a colloidal solution comprising;

from 5 to 30% by mass based on the mass of the gel, of at least one inorganic viscosifying agent;

from 0.5 to 10 mol/L of gel, of at least one active biological decontamination agent;

0.05 to 5% by mass based on the mass of the gel, of at least one super absorbent polymer;

0.1 to 2% by mass, based on the mass of the gel, of at least one surfactant; and

the remainder of solvent;

on said surface;

b) maintaining the gel on the surface at least for a sufficient time so that the gel destroys and/or inactivates and/or absorbs the biological species, and so that the gel dries and forms a dry and solid residue containing said biological species;

c) removing the dry and solid residue containing said biological species.

2. The method according to claim 1, wherein the solid substrate is a porous substrate.

3. The method according to claim 1, wherein the substrate is made of at least one material selected from metals;

polymers;

glasses, cements;

mortars and concretes;

plasters;

bricks;

natural or artificial stone; and

ceramics.

4. The method according to claim 1, wherein the biological species is selected from bacteria, fungi, yeasts, viruses, toxins, spores and protozoans.

5. The method according to claim 1, wherein the biological species is selected from bio-toxic species.

6. The method according to claim 5, wherein said bio-toxic species are selected from pathogenic spores, toxins, and viruses.

7. The method according to claim 6, wherein said pathogenic spores are selected from the spores of Bacillus anthracis, and said toxins are selected from Botulinum toxin.

8. The method according to claim 1, wherein the gel is applied on the surface in an amount from 100 g to 2,000 g of gel per m² of surface.

9. The method according to claim 1, wherein the gel is applied on the solid surface by spraying, with a brush or with a hawk.

10. The method according to claim 1, wherein, during step b), the drying is carried out at a temperature from 1°

C. to 50°

C., and under a relative humidity from 20% to 80%.

11. The method according to claim 1, wherein the gel is maintained on the surface for a duration from 2 to 72 hours.

12. The method according to claim 1, wherein the dry and solid residue appears as particles with a size from 1 to 10 mm.

13. The method according to claim 1, wherein the dry and solid residue is removed from the solid surface by brushing and/or suction.

14. The method according to claim 1, wherein the described cycle is repeated from 1 to 10 times by using the same gel during all the cycles or by using different gels during one or more cycle(s).

15. The method according to claim 1, wherein, during step b), the gel, before total drying, is re-wetted with a solution of a biological decontamination agent.

16. The method according to claim 1, wherein the inorganic viscosifying agent is selected from aluminas, silicas, aluminosilicates, clays and mixtures thereof.

17. The method according to claim 16, wherein the inorganic viscosifying agent is selected from pyrogenated silicas, precipitated silicas, hydrophilic silicas, hydrophobic silicas, acid silicas, basic silicas, and mixtures thereof.

18. The method according to claim 17, wherein the inorganic viscosifying agent consists of a mixture of a precipitated silica and a pyrogenated silica.

19. The method according to claim 17, wherein the inorganic viscosifying agent consists of one or more alumina(s) representing from 5 to 30% by mass, based on the mass of the gel.

20. The method according to claim 19, wherein the inorganic viscosifying agent consists of one or more alumina(s) representing from 8 to 17% by mass, based on the mass of the gel.

21. The method according to claim 1, wherein the active biological decontamination agent is selected from bases;

acids;

oxidizing agents;

quaternary ammonium salts; and

mixtures thereof.

22. The method according to claim 21, wherein said bases are selected from the group consisting of sodium hydroxide, potassium hydroxide, and mixtures thereof.

23. The method according to claim 21, wherein said acids are selected from the group consisting of nitric acid, phosphoric acid, hydrochloric acid, sulfuric acid, and mixtures thereof.

24. The method according to claim 21, wherein said oxidizing agents are selected from the group consisting of peroxides, permanganates, persulfates, ozone, hypochlorites and mixtures thereof.

25. The method according to claim 21, wherein said quaternary ammonium salts are selected from the group consisting of hexacetylpyridinium salts.

26. The method according to claim 1, wherein the super absorbent polymer is selected from sodium poly(meth)acrylates, starches grafted with a (meth)acrylic polymer, hydrolyzed starches grafted with a (meth)acrylic polymer;

polymers based on starch, on gum, and on a cellulose derivative; and

mixtures thereof.

27. The method according to claim 1, wherein the surfactant is selected from non ionic surfactants;

and mixtures thereof.

28. The method according to claim 27, wherein said non ionic surfactants are selected from the group consisting of block copolymers;

ethoxylated fatty acids; and

mixtures thereof.

29. The method according to claim 28, wherein said block copolymers are copolymers of ethylene oxide and of propylene oxide.

30. The method of claim 10, wherein the solvent is selected from water, organic solvents and mixtures thereof.