System and method for air temperature control in an oxygen transport membrane based reactor

• US 9,452,388 B2
• Filed: 10/08/2014
• Issued: 09/27/2016
• Est. Priority Date: 10/08/2013
• Status: Active Grant

• Current Assignee: Praxair Technology Incorporated (Linde Plc)
• Original Assignee: Praxair Technology Incorporated (Linde Plc)
• Inventors: Kelly, Sean M.
• Primary Examiner(s): Greene, Jason M
• Application Number:
  US14/509,381
• Publication Number:
  US 20150098880A1
• Time in Patent Office: 720 Days
• Field of Search: 95/54
• US Class Current: 1/1
• CPC Class Codes: B01D 53/226 in serial connexion
• CPC Class Codes: B01D 53/46 Removing components of defined structure
• CPC Class Codes: B01J 19/2475 Membrane reactors
• CPC Class Codes: B01J 2208/00176 outside the reactor
• CPC Class Codes: B01J 2208/00371 gaseous
• CPC Class Codes: B01J 2219/00006 Large-scale industrial plants
• CPC Class Codes: B01J 2219/24 Stationary reactors without moving elements inside
• CPC Class Codes: B01J 8/009 Membranes, e.g. feeding or removing reactants or products to or from the catalyst bed through a membrane
• CPC Class Codes: B01J 8/025 in a cylindrical shaped bed
• CPC Class Codes: B01J 8/062 being installed in a furnace
• CPC Class Codes: B01J 8/065 Feeding reactive fluids
• CPC Class Codes: C01B 13/0251 by making use of membranes
• CPC Class Codes: C01B 2203/0233 the reforming step being a steam reforming step
• CPC Class Codes: C01B 2203/0261 containing a catalytic partial oxidation step [CPO]
• CPC Class Codes: C01B 2203/0805 Methods of heating the process for making hydrogen or synthesis gas
• CPC Class Codes: C01B 2203/0844 the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
• CPC Class Codes: C01B 2203/1241 Natural gas or methane
• CPC Class Codes: C01B 2203/148 involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
• CPC Class Codes: C01B 3/382 Multi-step processes
• CPC Class Codes: C01B 3/384 the catalyst being continuously externally heated
• CPC Class Codes: C01B 3/386 : Catalytic partial combustion
• CPC Class Codes: C07C 1/041 : Reactors
• CPC Class Codes: C07C 1/0485 : Set-up of reactors or accessories; Multi-step processes
• CPC Class Codes: Y02E 60/32 : Hydrogen storage

Abstract

A system and method for air temperature control in an oxygen transport membrane based reactor is provided. The system and method involves introducing a specific quantity of cooling air or trim air in between stages in a multistage oxygen transport membrane based reactor or furnace to maintain generally consistent surface temperatures of the oxygen transport membrane elements and associated reactors. The associated reactors may include reforming reactors, boilers or process gas heaters.

Claims

1. A method for air temperature control in a multi-stage reactively driven oxygen transport membrane based reactor comprising the steps of:

introducing a flow of a heated oxygen containing feed stream to the multi-stage reactively driven oxygen transport membrane based reactor, the heated oxygen containing feed stream having a temperature from about 800°

C. to about 1000°

C.;

passing the heated oxygen containing feed stream across the surfaces of a plurality of oxygen transport membrane elements in a first stage of the multi-stage reactively driven oxygen transport membrane based reactor wherein the some oxygen is depleted from the heated oxygen containing feed stream to produce a first residual stream at a temperature at or above the heated oxygen containing feed stream temperature;

introducing a flow of supplemental cooling air to the first residual stream within the multi-stage oxygen transport membrane based reactor;

mixing the flow of supplemental cooling air with the first residual stream within the multi-stage oxygen transport membrane based reactor to produce a mixed stream having a mixed stream temperature;

passing the mixed stream across the surfaces of a second plurality of oxygen transport membrane elements in a second stage of the multi-stage reactively driven oxygen transport membrane based reactor wherein the some oxygen is depleted from the mixed stream to produce a second residual stream at a temperature above the mixed stream temperature; and

exhausting a stream containing some or all of the second residual stream from the multi-stage reactively driven oxygen transport membrane based reactor;

wherein the heated oxygen containing feed stream temperature and the mixed stream temperature are within about 25°

C. of each other.

2. The method for air temperature control as set forth in claim 1 wherein the temperature of the first residual stream and the temperature of the second residual stream are within about 25°

C. of each other.

3. The method for air temperature control as set forth in claim 1 wherein the temperature of the exhausted stream is not greater than about 50°

C. above the heated oxygen containing feed stream.

4. The method for air temperature control as set forth in claim 1 wherein the temperature of the first residual stream is not greater than about 50°

C. above the heated oxygen containing feed stream.

5. The method for air temperature control as set forth in claim 1 wherein the temperature of the second residual stream is not greater than about 50°

C. above the heated oxygen containing feed stream.

6. The method for air temperature control as set forth in claim 1 wherein the temperature of the second residual stream is not greater than about 50°

C. above the mixed stream temperature.

7. The method for air temperature control as set forth in claim 1 wherein the flow of supplemental cooling air is a second flow of supplemental cooling air and the mixed stream is a second mixed stream having a second mixed stream temperature and wherein the method further comprises the steps of introducing a first flow of supplemental cooling air to the heated oxygen containing feed stream to produce a first mixed stream having a first mixed stream temperature wherein the first mixed stream temperature and the second mixed stream temperature are within about 25°

C. of each other.

8. The method for air temperature control as set forth in claim 7 wherein the temperature of the first residual stream is not greater than about 50°

C. above the first mixed stream temperature.

9. The method for air temperature control as set forth in claim 7 wherein the temperature of the second residual stream is not greater than about 50°

C. above the first mixed stream temperature.

10. The method for air temperature control as set forth in claim 7 further comprising a third stage of the multi-stage reactively driven oxygen transport membrane based reactor, a third flow of supplemental cooling air, a third mixed stream formed from the mixing of the third flow of supplemental cooling air with the second residual stream, and a third residual stream and wherein the first mixed stream, the second mixed stream and the third mixed stream are within about 25°

C. of each other.

11. The method for air temperature control as set forth in claim 7 further comprising a third stage of the multi-stage reactively driven oxygen transport membrane based reactor, a third flow of supplemental cooling air, a third mixed stream formed from the mixing of the third flow of supplemental cooling air with the second residual stream, and a third residual stream and wherein the first residual stream, the second residual stream and the third residual stream are within 25°

C. of each other and not greater than 50°

C. above the first mixed stream temperature.

12. The method for air temperature control as set forth in claim 1 wherein the multi-stage reactively driven oxygen transport membrane based reactor is a reactively driven oxygen transport membrane based reforming reactor.

13. The method for air temperature control as set forth in claim 1 wherein the multi-stage reactively driven oxygen transport membrane based reactor is a reactively driven oxygen transport membrane boiler.

14. The method for air temperature control as set forth in claim 1 wherein the multi-stage reactively driven oxygen transport membrane based reactor is a reactively driven oxygen transport membrane based process gas heater.

15. A multi-stage reactively driven oxygen transport membrane based reforming reactor comprising:

an air inlet configured to receive a heated oxygen containing feed stream at a temperature from about 800°

C. to about 1000°

C.;

a first plurality of oxygen transport membrane elements contained within a first stage of the multi-stage reactor and in fluid communication with the heated oxygen containing feed stream and configured to separate oxygen from the heated oxygen containing feed stream through oxygen ion transport when subjected to an elevated operational temperature and a reactively driven difference in oxygen partial pressure across the first plurality of oxygen transport membrane elements to produce an oxygen depleted first residual stream at a temperature above the heated oxygen containing feed stream;

at least one cooling air injector disposed within the oxygen transport membrane based reactor downstream of the first stage and configured to introduce a flow of supplemental cooling air to the first residual stream and produce a mixed stream having a mixed stream temperature;

a second plurality of oxygen transport membrane elements contained within a second stage of the multi-stage reactor and disposed downstream of the first stage, the second plurality of oxygen transport membrane elements in fluid communication with the mixed stream and configured to separate oxygen from the mixed stream through oxygen ion transport when subjected to an elevated operational temperature and a reactively driven difference in oxygen partial pressure across the second plurality of oxygen transport membrane elements to produce an oxygen depleted second residual stream at a temperature above the heated oxygen containing feed stream; and

an outlet disposed downstream of the second stage of the multi-stage reactively driven oxygen transport membrane based reactor and configured for exhausting a stream containing some or all of the oxygen depleted second residual stream from the multi-stage reactively driven oxygen transport membrane based reactor;

wherein the temperature of the first residual stream and the temperature of the second residual stream are within about 25°

C. of each other.

16. The multi-stage reactively driven oxygen transport membrane based reactor as set forth in claim 15 wherein the temperature of the first residual stream and the temperature of the second residual stream are within about 25°

C. of each other.

17. The multi-stage reactively driven oxygen transport membrane based reactor as set forth in claim 15 wherein the temperature of the first residual stream is not greater than about 50°

C. above the temperature of the heated oxygen containing feed stream.

18. The multi-stage reactively driven oxygen transport membrane based reactor as set forth in claim 15 wherein the temperature of the second residual stream is not greater than about 50°

C. above the temperature of the heated oxygen containing feed stream.

19. The multi-stage reactively driven oxygen transport membrane based reactor as set forth in claim 15 further comprising:

at least one second cooling air injector disposed within the oxygen transport membrane based reactor downstream of the second stage and configured to introduce a second flow of supplemental cooling air to the second residual stream and produce a second mixed stream having a second mixed stream temperature; and

a third plurality of oxygen transport membrane elements contained within a third stage of the multi-stage reactor and disposed downstream of the second stage, the third plurality of oxygen transport membrane elements in fluid communication with the second mixed stream and configured to separate oxygen from the second mixed stream through oxygen ion transport when subjected to an elevated operational temperature and a reactively driven difference in oxygen partial pressure across the third plurality of oxygen transport membrane elements to produce an oxygen depleted third residual stream at a temperature above the heated oxygen containing feed stream;

wherein the temperature of the first mixed stream and the temperature of the second mixed stream are within about 25°

C. of each other.