Split electrode for organic devices

• US 9,455,417 B2
• Filed: 11/06/2014
• Issued: 09/27/2016
• Est. Priority Date: 12/13/2011
• Status: Active Grant

• Current Assignee: Universal Display Corporation
• Original Assignee: Universal Display Corporation
• Inventors: Mandlik, Prashant, Ma, Ruiqing
• Primary Examiner(s): Le, Thao X
• Assistant Examiner(s): SWAN, GARDNER W.S
• Application Number:
  US14/534,615
• Publication Number:
  US 20150069370A1
• Time in Patent Office: 691 Days
• US Class Current: 1/1
• CPC Class Codes: H10K 50/828 Transparent cathodes, e.g. comprising thin metal layers
• CPC Class Codes: H10K 50/844 Encapsulations
• CPC Class Codes: H10K 50/846 comprising getter material or desiccants
• CPC Class Codes: H10K 50/858 comprising refractive means, e.g. lenses
• CPC Class Codes: H10K 59/80523 Multilayers, e.g. opaque multilayers
• CPC Class Codes: H10K 59/80524 Transparent cathodes, e.g. comprising thin metal layers
• CPC Class Codes: H10K 59/874 including getter material or desiccant
• CPC Class Codes: H10K 71/00 Manufacture or treatment specially adapted for the organic devices covered by this subclass

Abstract

A device includes a first electrode, an organic layer disposed over the first electrode and a second electrode disposed over the organic layer. The second electrode includes a first conductive layer, a first separation layer disposed over the first conductive layer, and a second conductive layer disposed over the first separation layer, wherein the first separation layer is not a continuous layer and the first and second conductive layers are bridged where the first separation layer is not continuous. The first separation layer has an extinction coefficient that is at least 10% different from the extinction coefficient of the first conductive layer at wavelength 500 nm, or an index of refraction that is at least 10% different from the index of refraction of the first conductive layer at wavelength 500 nm.

Claims

1. A device, comprising:

a first electrode;

an organic emissive layer disposed over the first electrode; and

a second electrode disposed over the organic emissive layer, the second electrode further comprising;

a first conductive layer having an extinction coefficient and an index of refraction;

a first separation layer disposed over the first conductive layer, the first separation layer having an extinction coefficient that is at least 10% different from the extinction coefficient of the first conductive layer at 500 nm;

or wherein the first separation layer has an index of refraction that is at least 10% different from the index of refraction of the first conductive layer at 500 nm, wherein the first separation layer consists essentially of an organic material;

a second conductive layer disposed over the first separation layer; and

a barrier layer disposed over the second conductive layer, wherein the first separation layer is not a continuous layer and the first and second conductive layers are bridged where the first separation layer is not continuous.

2. The device of claim 1, wherein the first separation layer has an extinction coefficient that is at least 10% different from the extinction coefficient of the first conductive layer at 500 nm.

3. The device of claim 2, wherein the first separation layer has an extinction coefficient less than 5 at 500 nm.

4. The device of claim 2 wherein the first separation layer has an extinction coefficient less than 3 at 500 nm.

5. The device of claim 2, wherein the first separation layer has an extinction coefficient less than 1 at 500 nm.

6. The device of claim 1, wherein the first separation layer has a thickness of at least 20 nm.

7. The device of claim 1, wherein the first conductive layer has a thickness not more than 150 nm.

8. The device of claim 1, wherein the first conductive layer has a water vapor transmission rate at least 5% different from that of the first separation layer, and the second conductive layer has a water vapor transmission rate at least 5% different from that of the first separation layer.

9. The device of claim 1, wherein the first conductive layer has a water vapor transmission rate at least 10% different from that of the first separation layer, and the second conductive layer has a water vapor transmission rate at least 10% different from that of the first separation layer.

10. The device of claim 1, wherein the first conductive layer has a water vapor transmission rate at least 25% different from that of the first separation layer, and the second conductive layer has a water vapor transmission rate at least 25% different from that of the first separation layer.

11. The device of claim 1, wherein the first conductive layer is a low work function metallic layer or an inorganic layer.

12. The device of claim 11, wherein the first conductive layer is a low work function metallic layer comprising a material selected from Al, Ca and MgAg.

13. The device of claim 1, wherein the second conductive layer is a low work function metallic layer or an inorganic layer.

14. The device of claim 13, wherein the second conductive layer is a low work function metallic layer comprising a material selected from Al, Ca, and MgAg.

15. The device of claim 1, wherein the first conductive layer and the second conductive layer have the same material composition.

16. The device of claim 1, wherein the first conductive layer and the second conductive layers have different material compositions.

17. The device of claim 1, wherein the first separation layer is a metallic layer, an inorganic layer, or an organic layer.

18. The device of claim 1, wherein the device further comprises a substrate, and the first electrode is disposed over the substrate.

19. The device of claim 18, wherein the substrate is a rigid substrate having a flexural rigidity greater than 2×

10<sup>−

2</sup> Nm.

20. The device of claim 19, wherein the substrate is a flexible substrate having a flexural rigidity less than 2×

10<sup>−

2</sup> Nm.

21. The device of claim 20, wherein the first electrode is an anode, and the device further comprises:

a permeation barrier layer disposed between the anode and the substrate; and

a water reacting layer disposed between the substrate and the anode.

22. The device of claim 18, further comprising a lamination layer disposed over the barrier layer.

23. The device of claim 1, wherein the second electrode further comprises:

a second separation layer disposed over the second conductive layer, and

a third conductive layer disposed over the second separation layer.

24. The device of claim 1, wherein the first separation layer consists essentially of a single material.

25. The device of claim 1, wherein the first separation layer comprises a mixture of at least two different materials.

26. The device of claim 1, wherein the first separation layer comprises a plurality of sublayers, wherein at least two of the sublayers have a different material composition.

27. The device of claim 1, wherein the barrier layer is transparent.

28. A method, comprising:

depositing over a substrate, a first electrode, an organic emissive layer, and a second electrode, wherein depositing the second electrode comprises the following steps in sequence;

depositing a first conductive layer over the organic emissive layer, the first conductive layer having an extinction coefficient and an index of refraction;

depositing a first separation layer over the first conductive layer, wherein the first separation layer is not a continuous layer and the first separation layer having an extinction coefficient that is at least 10% different from the extinction coefficient of the first conductive layer at 500 nm;

or wherein the first separation layer has an index of refraction that is at least 10% different from the index of refraction of the first conductive layer at 500 nm, wherein the first separation layer consists essentially of an organic material; and

depositing a second conductive layer over the first separation layer, whereby the first and second conductive layers are bridged where the first separation layer is not continuous; and

depositing a barrier layer over the second conductive layer of the second electrode.