Hot dip Al coated steel sheet excellent in heat black discoloration resistance and method of production of same
First Claim
1. A hot dip Al coated steel sheet which is excellent in heat black discoloration resistance which comprises a steel sheet which consists of, by mass %,C:
- 0.0005 to less than 0.01%,Si;
0.001 to 0.05%,P;
0.002 to 0.1%,S;
0.002 to 0.1%,Al;
0.001 to 0.01%,N;
0.0015 to 0.0040%O;
0.03 to 0.08%,Mn;
0.2 to 0.8%, andfurthermore, one or both ofNi;
0.01 to 0.1% orCu;
0.01 to 0.1%,satisfies 10×
C+Ni+Cu>
0.03, andhas a balance of Fe and unavoidable impurities,on the surface of the steel sheet is providedan Al coating layer which contains, by mass %, Si;
4 to 11%, which has a balance of Al and unavoidable impurities, and which has a Knoop hardness of 90 to 110, the Al coating layer and the steel sheet interface having a less than 5 μ
m thick Al—
Fe—
Si alloy layer between them.
2 Assignments
0 Petitions
Accused Products
Abstract
In conventional Al coated steel sheet, with the Al coating as it is, black discoloration cannot be prevented at 550° C. or more. For this reason, post annealing is used to form a barrier layer and suppress the formation of Fe—Al intermetallic compounds. However, with this method, there were the problems that the steel sheet became poor in workability and, further, high temperature, long time heating was required, so there were problems from the workability, economy, and environmental aspect. The present invention provides steel sheet which has a heat black discoloration resistance even at a 550° C. or more high temperature without additional annealing after Al coating and further is excellent in workability.
That is, it is hot dip Al coated steel sheet which comprises steel sheet which contains predetermined ingredients of C, Si, P, S, Al, N, and O plus one or both of furthermore
Ni: 0.01 to 0.1% or
Cu: 0.01 to 0.1% and
satisfies 10×C+Ni+Cu>0.03 and an Al coating layer which contains Si: 4 to 11% on the surface of that steel sheet and which have a thickness 5 μm or less Al—Fe—Si alloy layer in the interface between the Al coating layer and the steel sheet.
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Citations
4 Claims
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1. A hot dip Al coated steel sheet which is excellent in heat black discoloration resistance which comprises a steel sheet which consists of, by mass %,
C: - 0.0005 to less than 0.01%,
Si;
0.001 to 0.05%,P;
0.002 to 0.1%,S;
0.002 to 0.1%,Al;
0.001 to 0.01%,N;
0.0015 to 0.0040%O;
0.03 to 0.08%,Mn;
0.2 to 0.8%, andfurthermore, one or both of Ni;
0.01 to 0.1% orCu;
0.01 to 0.1%,satisfies 10×
C+Ni+Cu>
0.03, andhas a balance of Fe and unavoidable impurities, on the surface of the steel sheet is provided an Al coating layer which contains, by mass %, Si;
4 to 11%, which has a balance of Al and unavoidable impurities, and which has a Knoop hardness of 90 to 110, the Al coating layer and the steel sheet interface having a less than 5 μ
m thick Al—
Fe—
Si alloy layer between them. - View Dependent Claims (2, 3, 4)
- 0.0005 to less than 0.01%,
Specification
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- Resources
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Current AssigneeNippon Steel Corporation
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Original AssigneeNippon Steel & Sumitomo Metal Corporation (Nippon Steel Corporation)
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InventorsMaki, Jun, Yamaguchi, Shinichi
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Primary Examiner(s)Sheikh, Humera
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Assistant Examiner(s)Wang, Lucas
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Application NumberUS13/704,786Publication NumberTime in Patent Office2,304 DaysField of Search428/653US Class Current1/1CPC Class CodesB32B 15/012 one layer being formed of a...C21D 8/0278 involving a particular surf...C22C 21/02 with silicon as the next ma...C22C 38/001 containing NC22C 38/002 containing In, Mg, or other...C22C 38/004 Very low carbon steels, i.e...C22C 38/02 containing siliconC22C 38/08 containing nickel C22C38/10...C22C 38/16 containing copperC22C 38/60 containing lead, selenium, ...C23C 2/02 Pretreatment of the materia...C23C 2/12 Aluminium or alloys based t...C23C 2/26 After-treatment C23C2/14 ta...Y10T 428/12757 Fe
