Pre-formed polymer matrix disc to maintain uniform cell spacing

• US 9,470,927 B2
• Filed: 09/24/2014
• Issued: 10/18/2016
• Est. Priority Date: 09/24/2013
• Status: Active Grant

• Current Assignee: Gentex Corporation
• Original Assignee: Gentex Corporation
• Inventors: Ash, Kevin L., Franz, Sue F., Theiste, David A., Tonar, William L., Kloeppner, Leroy J.
• Primary Examiner(s): PINKNEY, DAWAYNE
• Application Number:
  US14/494,826
• Publication Number:
  US 20150085338A1
• Time in Patent Office: 755 Days
• Field of Search: 359/296, 359/245, 359/315, 359/247, 359251-252, 359/108, 359237-238, 359278-279, 359290-292, 359/298, 359300-302, 359/259, 359265-275, 430 31- 32, 345/49, 345/105, 345/107, 349/33, 349/38, 438/929
• US Class Current: 1/1
• CPC Class Codes: G02F 1/133602 Direct backlight
• CPC Class Codes: G02F 1/133603 with LEDs
• CPC Class Codes: G02F 1/133626 providing two modes of illumination, e.g. day-night
• CPC Class Codes: G02F 1/1503 caused by oxidation-reduction reactions in organic liquid solutions, e.g. viologen solutions
• CPC Class Codes: G02F 1/15165 Polymers
• CPC Class Codes: G02F 1/153 Constructional details
• CPC Class Codes: G02F 1/155 Electrodes
• CPC Class Codes: G02F 1/157 Structural association of cells with optical devices, e.g. reflectors or illuminating devices
• CPC Class Codes: G02F 1/161 Gaskets; Spacers; Sealing of cells; Filling or closing of cells
• CPC Class Codes: G02F 1/163 Operation of electrochromic cells, e.g. electrodeposition cells; Circuit arrangements therefor
• CPC Class Codes: G02F 2001/15145 the electrochromic layer comprises a mixture of anodic and cathodic compounds
• CPC Class Codes: G02F 2001/164 the electrolyte is made of polymers
• CPC Class Codes: G02F 2201/44 Arrangements combining different electro-active layers, e.g. electrochromic, liquid crystal or electroluminescent layers
• CPC Class Codes: H10K 2102/3031 Two-side emission, e.g. transparent OLEDs [TOLED]
• CPC Class Codes: H10K 50/8426 Peripheral sealing arrangements, e.g. adhesives, sealants
• CPC Class Codes: H10K 50/8428 Vertical spacers, e.g. arranged between the sealing arrangement and the OLED
• CPC Class Codes: H10K 50/86 Arrangements for improving contrast, e.g. preventing reflection of ambient light
• CPC Class Codes: H10K 59/50 OLEDs integrated with light modulating elements, e.g. with electrochromic elements, photochromic elements or liquid crystal elements
• CPC Class Codes: H10K 59/8722 Peripheral sealing arrangements, e.g. adhesives, sealants
• CPC Class Codes: H10K 59/8723 Vertical spacers, e.g. arranged between the sealing arrangement and the OLED
• CPC Class Codes: H10K 59/8791 : Arrangements for improving contrast, e.g. preventing reflection of ambient light

Abstract

An emissive display system includes an electro-optic device having a first substantially transparent substrate including a first electrically conductive material associated therewith. A second substantially transparent substrate is spaced apart from the first substrate to define a cavity and includes a second electrically conductive material associated therewith. One or more spacing members are positioned within the cavity and include one or more polymer matrix discs configured to maintain a cell spacing between the first and second substrates. An electro-optic medium is disposed within the cavity and is variably transmissive such that the electro-optic device is operable between substantially clear and darkened states, and includes at least one solvent, at least one anodic material, and at least one cathodic material. A substantially transparent light emitting display is operably coupled to the electro-optic device, which is in the darkened state when the light emitting display is emitting light.

Claims

1. An emissive display system, comprising:

an electro-optic device comprising;

a first substantially transparent substrate having a first electrically conductive material associated therewith;

a second substantially transparent substrate spaced apart from the first substrate to define a cavity and having a second electrically conductive material associated therewith;

one or more spacing members positioned within the cavity, wherein the one or more spacing members comprise one or more polymer matrix discs configured to maintain a cell spacing between the first and second substrates, further wherein the one or more spacing members are variably transmissive between substantially clear and darkened states;

an electro-optic medium disposed within the cavity, the electro-optic medium being variably transmissive such that the electro-optic device is operable between substantially clear and darkened states, the electro-optic medium comprising;

at least one solvent;

at least one anodic material;

at least one cathodic material; and

a substantially transparent light emitting display operably coupled to the electro-optic device, wherein the electro-optic device is in the darkened state when the light emitting display is emitting light.

2. The emissive display system of claim 1, wherein the one or more spacing members are substantially transparent.

3. The emissive display system of claim 2, wherein the electro-optic medium diffuses into the one or more spacing members upon association, such that the one or more spacing members are variably transmissive.

4. The emissive display system of claim 3, wherein both of the at least one anodic and at least one cathodic materials are electroactive and at least one of the at least one anodic and at least one cathodic materials is electrochromic.

5. The emissive display system of claim 1, wherein the one or more spacing members are isocyanate reaction products.

6. The emissive display system of claim 1, wherein the one or more spacing members are substantially concealed in the electro-optic device when the electro-optic medium is in the darkened state.

7. The emissive display system of claim 1, wherein the one or more spacing members have a diameter of approximately 1 centimeter and the cell spacing is approximately 0.5 millimeters.

8. The emissive display system of claim 1, wherein the light emitting display is an organic light emitting diode display.

9. An emissive display system, comprising:

an electro-optic device comprising;

a first substantially transparent substrate having a first electrically conductive material associated therewith;

a second substantially transparent substrate spaced apart from the first substrate to define a cavity and having a second electrically conductive material associated therewith;

one or more spacing members positioned within the cavity, wherein the one or more spacing members are configured to maintain a cell spacing between the first and second substrates, further wherein the spacing members are variably transmissive between substantially clear and darkened states;

an electro-optic medium disposed within the cavity, the electro optic medium being variably transmissive such that the electro-optic device is operable between a substantially clear state and a darkened state; and

a substantially transparent light emitting display operably coupled to the electro-optic device and configured to display a visible image by selectively emitting light, wherein the electro-optic device is in the darkened state when the light emitting display is emitting light.

10. The emissive display system of claim 9, wherein the one or more spacing members are substantially transparent.

11. The emissive display system of claim 10, wherein the one or more spacing members are comprised of a crosslinked polymer matrix.

12. The emissive display system of claim 11, wherein the electro-optic medium includes at least one solvent, at least one anodic material, at least one electrochromic material, and at least one cathodic material.

13. The emissive display system of claim 12, wherein the at least one electrochromic material is in solution with the solvent and is further interspersed in the crosslinked polymer matrix of the one or more spacing members.

14. The emissive display system of claim 11, wherein the polymer matrix results from crosslinking polymer chains and further wherein the polymer chains are from the following classes of polymers:

polyacrylate, polymethacrylates, polyethers, polyesters, polycarbonates, polyvinylesters, polyurethanes, polysiloxanes, polysilanes, polyacrylonitriles, polystyrenes, polymethacrylonitriles, polyamides, polyimides, polyvinylidenehalides, and co-polymer and combinations of thereof.

15. The emissive display system of claim 14, wherein the polymer chains are cross-linked by reaction with a compound having a functional group selected from the group consisting of aromatic and aliphatic hydroxyl;

aromatic and aliphatic isocyanate;

aliphatic and aromatic isothiocyanato;

aromatic and aliphatic glycidyls;

aromatic and aliphatic amines.

16. The emissive display system of claim 9, wherein the light emitting display is an organic light emitting diode display.

17. An emissive display system, comprising:

an electro-optic device comprising;

a first substantially transparent substrate having a first electrically conductive material associated therewith;

a second substantially transparent substrate spaced apart from the first substrate to define a cavity, the second substrate having a second electrically conductive material associated therewith;

one or more substantially rigid discs disposed between the first and second substrates, wherein the one or more discs are configured to maintain a cell spacing between the first and second substrates, further wherein the one or more substantially rigid discs are variably transmissive between substantially clear and darkened states;

an electro-optic medium disposed within the cavity, the electro-optic medium being variably transmissive such that the electro-optic device is operable between a substantially clear state and a darkened state; and

a substantially transparent light emitting display operably coupled to the electro-optic device and operable between ON and OFF conditions, wherein the electro-optic device is in the darkened state when the light emitting display is emitting light in the ON condition.

18. The emissive display system of claim 17, wherein the one or more discs are comprised of a crosslinked polymer matrix and are substantially transparent.

19. The emissive display system of claim 18, wherein the electro-optic medium includes at least one electrochromic material in solution with a solvent, and further wherein the at least one electrochromic material is interspersed in the crosslinked polymer matrix of the one or more discs.

20. The emissive display system of claim 17, wherein the light emitting display is an organic light emitting diode display.