In-situ subsurface decontamination of sodic soil, clay and ground water

• US 9,475,106 B2
• Filed: 05/11/2012
• Issued: 10/25/2016
• Est. Priority Date: 05/11/2011
• Status: Active Grant

• Current Assignee: William L. Lundy
• Original Assignee: William L. Lundy
• Inventors: Lundy, William L.
• Primary Examiner(s): STELLING, LUCAS A
• Application Number:
  US13/469,492
• Publication Number:
  US 20120285891A1
• Time in Patent Office: 1,628 Days
• Field of Search: 210/747.8
• US Class Current: 1/1
• CPC Class Codes: B09C 1/002 involving in-situ ground water treatment
• CPC Class Codes: B09C 1/08 chemically
• CPC Class Codes: B09C 2101/00 In situ
• CPC Class Codes: C02F 1/66 by neutralisation; pH adjustment for degassing C02F1/20; using ion-exchange C02F1/42; for flocculation or precipitation of suspended impurities C02F1/52; for removing dissolved compounds C02F1/58
• CPC Class Codes: C02F 1/683 by addition of complex-forming compounds
• CPC Class Codes: C02F 1/70 by reduction C02F1/4676 takes precedence
• CPC Class Codes: C02F 1/722 Oxidation by peroxides
• CPC Class Codes: C02F 1/725 by catalytic oxidation
• CPC Class Codes: C02F 2101/36 containing halogen
• CPC Class Codes: C02F 2103/06 Contaminated groundwater or leachate
• CPC Class Codes: C02F 2305/023 Reactive oxygen species, singlet oxygen, OH radical
• CPC Class Codes: C02F 2305/026 Fenton's reagent
• CPC Class Codes: C02F 9/00 Multistage treatment of water, waste water or sewage

Abstract

A method of decontaminating soil and ground water containing organic contaminants and metal compounds. It comprises the steps of first treating such soils and ground water with an effective amount an aqueous solution containing a peroxide and a water soluble chelating agent for a time sufficient to have the water soluble chelating agent chelate at least one of the metals of the metal compounds present in the soil and ground water. Next, the chelated metals are brought into contact with the peroxide to catalytically convert the peroxide to an oxidizing agent and hydroxyl ion. The hydroxyl ion converts the halogenated organic compound into environmentally safe, non-toxic compounds. Gases that are produced from this reaction, and from the oxidation of organic compounds, are used to diffuse solution into the soil to chelate calcium and magnesium, thereby causing the sodium to be dislodged from the soil and reduce sodicity in the soil.

Claims

1. A method of reducing sodicity in soil or clay, the soil or clay having an initial sodicity above a predetermined acceptable level as measured by the sodium adsorption ratio (SAR) of the soil or clay, and the soil or clay containing organic contaminants and a metal compound, the method comprising:

(a) treating the soil or clay with an effective amount of an alkaline aqueous solution having a pH of at least 7 and comprising an alkaline buffering agent, calcium and/or magnesium peroxide, and a chelating agent, for a time sufficient to have the chelating agent chelate the metal of the metal compound;

(b) reacting the calcium and/or magnesium peroxide with water to produce calcium and/or magnesium cations;

(c) penetrating the soil or clay with gasses to diffuse the alkaline aqueous solution into the soil or clay and generate additional reaction; and

(d) contacting the soil or clay with the alkaline aqueous solution for a time sufficient to cause the chelating agent to chelate the calcium and/or magnesium cations produced in step (b) and hold them in solution, the chelating agent chelating a sufficient amount of the calcium and/or magnesium cations in order to cause sodium cations to become dislodged from a matrix of the soil or clay into solution and to reduce the sodicity as measured by the sodium adsorption ratio of the soil or clay below the predetermined acceptable level.

2. The method of claim 1, wherein the concentration of peroxide is about 0.6 to about 4.5 Moles/Liter.

3. The method of claim 1, wherein the concentration of chelating agents is about 0.03 to about 1.5 Moles/Liter.

4. The method of claim 1, wherein the concentration of alkaline buffering agent is about 0.5 to about 2.0 lbs/ gallon.

5. The method of claim 1, wherein the pH of the alkaline aqueous solution is between 7.0 and 10.0.

6. The method of claim 1, wherein the temperature of the ground water or subsurface media rises no more than 10.0 degrees F.

7. The method of claim 1, wherein treating the soil or clay with the effective amount of the alkaline aqueous solution comprises:

spraying or injecting the alkaline aqueous solution over or into surface of the soil or clay to be treated and

injecting the solution into areas of the soil or clay exhibiting higher concentrations of contaminants.

8. The method of claim 7, wherein the alkaline aqueous solution is sprayed onto a floor or wall of an excavated area, in the amount of 0.25 -2.0 gal/ sq. ft.

9. The method of claim 7, wherein the alkaline aqueous solution is injected at a rate of 3-10 gallons per minute.

10. The method of claim 1, wherein treating the soil or clay with the effective amount of the alkaline aqueous solution comprises injecting the alkaline aqueous solution into the soil or clay at a rate of 3-10 gallons per minute.

11. The method of claim 1, wherein the initial sodicity of the soil or clay is above 70 SAR and the predetermined acceptable level is 12 SAR.

12. The method of claim 1, wherein treating the soil or clay with the effective amount of the alkaline aqueous solution comprises:

spraying or injecting the alkaline aqueous solution over or into a surface of the soil or clay to be treated;

determining areas of the soil or clay not yet reached by the solution; and

spraying or injecting the solution into the areas not yet reached by the solution.

13. The method of claim 12, wherein determining the areas not yet reached by the reagent comprises:

observing the evolution of gasses at the surface; and

identifying the areas not yet reached by the reagent as those areas known to be contaminated with the contaminant but that did not evolve gasses at the surface.

14. A method of reducing sodicity and decontaminating soil or clay, the soil or clay having an initial sodicity above a predetermined acceptable level as measured by the sodium adsorption ratio (SAR) of the soil or clay, and the soil or clay containing halogenated organic contaminants and a metal compound, the method comprising:

(a) treating the soil or clay with an effective amount of an alkaline aqueous solution having a pH of at least 7 and comprising an alkaline buffering agent, calcium and/or magnesium peroxide, and a chelating agent, for a time sufficient to have the chelating agent chelate the metal of the metal compound present in the soil or clay;

(b) reacting the chelated metal with the peroxide to catalytically convert the peroxide to oxidizing agents and hydroxide ions;

(c) reacting the calcium and and/or magnesium peroxide with water to produce calcium and/or magnesium cations;

(d) penetrating the soil or clay with gasses to diffuse the alkaline aqueous solution into the soil or clay and generating additional reactions;

(e) contacting the halogenated organic contaminants in the soil or clay with hydroxide ions to convert the contaminants through nucleophilic substitution to environmentally safe, non-toxic compounds;

(f) contacting the soil or clay with the alkaline aqueous solution for a time sufficient to cause the chelating agent to chelate the calcium and/or magnesium cations produced in step (c) and hold them in solution, the chelating agent chelating a sufficient amount of the calcium and/or magnesium ions in order to cause the sodium cations to become dislodged from a matrix of the soil or clay into solution to reduce the sodicity as measured by the sodium adsorption ratio of the soil or clay below the predetermined acceptable level;

(g) observing the evolution of gasses at a surface of the soil or clay;

(i) identifying areas known to be contaminated with contaminants but that did not evolve gases at the surface as areas not yet reached by the solution; and

(j) spraying or injecting the solution into the areas not yet reached by the the solution.