Detection of volatile chemicals using an RFID sensing system

• US 9,482,639 B2
• Filed: 03/11/2013
• Issued: 11/01/2016
• Est. Priority Date: 03/11/2013
• Status: Expired due to Fees

• Current Assignee: Empire Technology Development LLC (Allied Inventors Management, LLC)
• Original Assignee: Empire Technology Development LLC (Allied Inventors Management, LLC)
• Inventors: Roundhill, David Max
• Primary Examiner(s): SIEFKE, SAMUEL P
• Application Number:
  US14/768,532
• Publication Number:
  US 20160003769A1
• Time in Patent Office: 1,331 Days
• US Class Current: 1/1
• CPC Class Codes: G01N 22/00 Investigating or analysing materials by the use of microwaves or radio waves, i.e. electromagnetic waves with a wavelength of one millimetre or more G01N3/00 - G01N17/00, G01N24/00 take precedence
• CPC Class Codes: G01N 27/025 a current being generated within the material by induction
• CPC Class Codes: G01N 27/122 Circuits particularly adapted therefor, e.g. linearising circuits
• CPC Class Codes: G01N 27/416 Systems G01N27/27 takes precedence
• CPC Class Codes: G01N 33/0042 SO2 or SO3
• CPC Class Codes: G01N 33/0044 Sulphides, e.g. H2S
• CPC Class Codes: G01N 33/0075 for multiple spatially distributed sensors, e.g. for environmental monitoring

Abstract

Methods, systems, and apparatuses, including computer programs encoded on computer-readable media, for monitoring volatile chemicals. A system includes an radio-frequency identification (RFID) tag composed of a patterned metal. The patterned metal is configured to absorb a volatile chemical. The RFID tag includes a non-volatile memory configured to store identification data. The RFID tag also includes a receiver that receives a signal at a frequency in a frequency range. The frequency is based upon an amount of the volatile chemical absorbed in the patterned metal. A transmitter of the RFID tag transmits the identification data in response to receiving the signal. The strength of the transmitted identification data is based upon an amount of the absorbed volatile chemical.

Claims

1. A system for detecting a volatile chemical, the system comprising:

a radio-frequency identification (RFID) tag composed of a patterned metal, wherein the patterned metal is configured to absorb a volatile chemical, and wherein the RFID tag comprises;

non-volatile memory configured to;

store identification data;

a receiver configured to;

receive a signal at a frequency in a frequency range, wherein the frequency is based upon an amount of the volatile chemical absorbed in the patterned metal;

a transmitter configured to;

transmit the identification data in response to receiving the signal, wherein a strength of the transmitted identification data is based upon an amount of the absorbed volatile chemical; and

an RFID reader configured to;

broadcast a request signal over a plurality of frequencies in the frequency range;

receive a response from the RFID tag at a particular request frequency, wherein a strength of the received response is based upon the amount of absorbed volatile chemical; and

determine a level of the volatile chemical absorbed in the patterned metal based upon the strength of the received response and the particular request frequency; and

a flow tube configured to convey a fluid, wherein the flow tube is configured to block the request signal;

an analysis chamber, wherein the RFID tag is mounted within the analysis chamber;

a first valve connecting the flow tube and the analysis chamber and configured to allow the fluid to flow from the flow tube into the analysis chamber; and

a second valve connecting the flow tube and the analysis chamber and configured to allow the fluid to flow from the analysis chamber into the flow chamber.

2. The system of claim 1, wherein the patterned metal is configured to absorb the volatile chemical from a fluid.

3. The system of claim 1, wherein a strength of the received signal is based upon the amount of the volatile chemical absorbed in the patterned metal.

4. The system of claim 1,

wherein the flow tube further comprises:

a non-metallic window portion, wherein the RFID tag is attached within the flow tube adjacent to the non-metallic window portion, and wherein the non-metallic window is configured to allow passage of the request signal.

5. The system of claim 4, wherein the non-metallic window portion is comprised of polytetraflouroethylene.

6. The system of claim 1, wherein the RFID tag is configured to control the opening and closing of the first valve and the second valve based upon the received signal.

7. The system of claim 1, further comprising a flexible substrate, wherein the RFID tag is attached to the flexible substrate.

8. The system of claim 7, wherein the flexible substrate comprises one of a polyimide film and a biaxially-oriented polyethylene terephthalate.

9. The system of claim 1, wherein the patterned metal comprises gold or silver.

10. The system of claim 9, wherein the volatile chemical is one of a sulfide or a thiol.

11. The system of claim 1, wherein the patterned metal comprises platinum or tungsten.

12. The system of claim 10, wherein the volatile chemical is sulphur dioxide.

13. A sensor for detecting a volatile chemical, the sensor comprising:

a chamber comprising a polymer section configured to flow a fluid;

a substrate attached onto an inner wall of the polymer section of the chamber;

a radio-frequency identification (RFID) tag formed on a surface of the substrate, wherein the RFID tag is composed of a patterned metal configured to absorb a volatile chemical, the RFID tag comprising;

non-volatile memory configured to store identification data;

a receiver configured to receive a signal at a frequency in a frequency range, wherein the frequency is based upon an amount of the volatile chemical absorbed in the patterned metal; and

a transmitter configured to transmit the identification data in response to receiving the signal, wherein a strength of the transmitted identification data is based upon the amount of the volatile chemical absorbed in the patterned metal; and

an RFID reader configured to;

broadcast a request signal over a plurality of frequencies in a request frequency range;

receive a response from the RFID tag at a particular request frequency; and

determine a level of the volatile chemical absorbed in the patterned metal based upon a strength of the received response from the RFID tag and the particular request frequency a flow tube configured to convey a fluid, wherein the flow tube is configured to block the request signal;

an analysis chamber, wherein the RFID tag is mounted within the analysis chamber;

a first valve connecting the flow tube and the analysis chamber and configured to allow the fluid to flow from the flow tube into the analysis chamber; and

a second valve connecting the flow tube and the analysis chamber and configured to allow the fluid to flow from the analysis chamber into the flow chamber.

14. The sensor of claim 13, wherein the patterned metal is configured to absorb the volatile chemical from the fluid.

15. The sensor of claim 13, wherein a strength of the signal is based upon the amount of the volatile chemical absorbed in the patterned metal.