Conductive sealant compositions

• US 9,484,123 B2
• Filed: 09/10/2012
• Issued: 11/01/2016
• Est. Priority Date: 09/16/2011
• Status: Active Grant

• Current Assignee: PRC-DeSoto International, Inc. (Nouryon BV)
• Original Assignee: PRC-DeSoto International, Inc. (Nouryon BV)
• Inventors: Tan, Ponchivy, Sharaby, Ahmed
• Primary Examiner(s): Kopec, Mark
• Application Number:
  US13/608,241
• Publication Number:
  US 20130075668A1
• Time in Patent Office: 1,513 Days
• US Class Current: 1/1
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: G21F 1/02 Selection of uniform shielding materials
• CPC Class Codes: H01B 1/04 mainly consisting of carbon-silicon compounds, carbon or silicon
• CPC Class Codes: H01B 1/22 the conductive material comprising metals or alloys
• CPC Class Codes: H01B 1/24 the conductive material comprising carbon-silicon compounds, carbon or silicon
• CPC Class Codes: Y10S 977/742 Carbon nanotubes, CNTs

Abstract

Embodiments of the present disclosure are directed to sealant compositions including a base composition with at least one sulfur-containing polymer, a curing agent composition, and an electrically conductive filler including carbon nanotubes and stainless steel fibers. The electrically conductive filler can be in either or both of the base composition and the curing agent composition. The sealant compositions are substantially Ni-free and exhibit unexpectedly superior EMI/RFI shielding effectiveness.

Claims

1. A sealant composition comprising:

a base composition comprising a sulfur-containing polymer;

a curing agent composition comprising a curing agent; and

an electrically conductive filler in at least one of the base composition or the curing agent composition, the electrically conductive filler comprising carbon nanotubes and stainless steel fibers;

wherein the stainless steel fibers have an average particle dimension larger than an average particle dimension of the carbon nanotubes wherein the stainless steel fibers have an average first dimension of about 8 μ

m to about 22 μ

m, and an average second dimension of about 330 μ

m to about 1 mm.

2. The sealant composition of claim 1, wherein the electrically conductive filler is in the base composition.

3. The sealant composition of claim 1, wherein the electrically conductive filler is in the curing agent composition.

4. The sealant composition of claim 1, wherein the electrically conductive filler is in both the curing agent composition and the base composition.

5. The sealant composition of claim 1, wherein the sealant composition is substantially nickel free.

6. The sealant composition of claim 1, wherein the carbon nanotubes have an average length dimension of about 5 μ

m to about 30 μ

m, and an average diameter dimension of about 10 nm to about 30 nm.

7. The sealant composition of claim 1, wherein a volume ratio of the carbon nanotubes to the stainless steel fibers is about 1:

5 to 1;

50.

8. The sealant composition of claim 1, further comprising at least one of an adhesion promoter, a corrosion inhibitor or a plasticizer in at least one of the base composition or the curing agent composition.

9. The sealant composition of claim 1, wherein the sulfur-containing polymer is a polysulfide or a polythioether.

10. A sealant composition comprising:

a base composition comprising a sulfur-containing polymer;

a curing agent composition comprising a curing agent; and

an electrically conductive filler in at least one of the base composition or the curing agent composition, the electrically conductive filler comprising carbon nanotubes and stainless steel fibers;

wherein the carbon nanotubes have an average particle dimension larger than an average particle dimension of the stainless steel fibers wherein the stainless steel fibers have an average first dimension of about 8 μ

m to about 22 μ

m, and an average second dimension of about 330 μ

m to about 1 mm.

11. The sealant composition of claim 10, wherein the electrically conductive filler is in the base composition.

12. The sealant composition of claim 10, wherein the electrically conductive filler is in the curing agent composition.

13. The sealant composition of claim 10, wherein the electrically conductive filler is in both the curing agent composition and the base composition.

14. The sealant composition of claim 10, wherein the sealant composition is substantially nickel free.

15. The sealant composition of claim 10, wherein the carbon nanotubes have an average length dimension of about 5 μ

m to about 30 μ

m, and an average diameter dimension of about 10 nm to about 30 nm.

16. The sealant composition of claim 10, wherein a volume ratio of the carbon nanotubes to the stainless steel fibers is about 1:

5 to 1;

50.

17. The sealant composition of claim 10, further comprising at least one of an adhesion promoter, a corrosion inhibitor or a plasticizer in at least one of the base composition or the curing agent composition.

18. The sealant composition of claim 10, wherein the sulfur-containing polymer is a polysulfide or a polythioether.

19. A sealant composition comprising:

a substantially nickel-free base composition comprising a sulfur-containing polymer;

a substantially nickel-free curing agent composition comprising a curing agent; and

a substantially nickel-free electrically conductive filler in at least one of the base composition or the curing agent composition, the electrically conductive filler comprising carbon nanotubes and stainless steel fibers;

wherein the stainless steel fibers have an average particle dimension larger than an average particle dimension of the carbon nanotubes fibers wherein the stainless steel fibers have an average first dimension of about 8 μ

m to about 22 μ

m, and an average second dimension of about 330 μ

m to about 1 mm.

20. The sealant composition of claim 19, wherein the carbon nanotubes have an average length dimension of about 5 μ

m to about 30 μ

m, and an average diameter dimension of about 10 nm to about 30 nm.

21. The sealant composition of claim 19, wherein a volume ratio of the carbon nanotubes to the stainless steel fibers is about 1:

5 to 1;

50.

22. A sealant composition comprising:

a substantially nickel-free base composition comprising a sulfur-containing polymer;

a substantially nickel-free curing agent composition comprising a curing agent; and

a substantially nickel-free electrically conductive filler in at least one of the base composition or the curing agent composition, the electrically conductive filler comprising carbon nanotubes and stainless steel fibers;

wherein the carbon nanotubes have an average particle dimension larger than an average particle dimension of the stainless steel fibers wherein the stainless steel fibers have an average first dimension of about 8 μ

m to about 22 μ

m, and an average second dimension of about 330 μ

m to about 1 mm.

23. The sealant composition of claim 22, wherein the carbon nanotubes have an average length dimension of about 5 μ

m to about 30 μ

m, and an average diameter dimension of about 10 nm to about 30 nm.

24. The sealant composition of claim 22, wherein a volume ratio of the carbon nanotubes to the stainless steel fibers is about 1:

5 to 1;

50.