Turfgrass fungicide formulation with pigment

• US 9,485,988 B2
• Filed: 09/09/2014
• Issued: 11/08/2016
• Est. Priority Date: 06/26/2008
• Status: Active Grant

• Current Assignee: Nutrien Ag Solutions (Canada) Inc. (Nutrien Ltd.)
• Original Assignee: Suncor Energy Incorporated
• Inventors: Fefer, Michael, Liu, Jun, Ruo, Tomoki, Hevia, Sonia Edith
• Primary Examiner(s): FISHER, ABIGAIL L
• Application Number:
  US14/481,312
• Publication Number:
  US 20150065475A1
• Time in Patent Office: 791 Days
• US Class Current: 1/1
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 25/00 Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application , e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
• CPC Class Codes: A01N 25/04 Dispersions, emulsions, suspoemulsions, suspension concentrates or gels foams A01N25/16
• CPC Class Codes: A01N 25/30 characterised by the surfactants
• CPC Class Codes: A01N 27/00 Biocides, pest repellants or attractants, or plant growth regulators containing hydrocarbons
• CPC Class Codes: A01N 37/34 Nitriles
• CPC Class Codes: A01N 43/52 condensed with carbocyclic rings, e.g. benzimidazoles
• CPC Class Codes: A01N 43/653 1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
• CPC Class Codes: A01N 43/90 having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
• CPC Class Codes: A01N 47/30 Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
• CPC Class Codes: A01N 47/34 containing the groups , e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
• CPC Class Codes: A01N 47/38 containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
• CPC Class Codes: A01N 47/40 the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
• CPC Class Codes: A01N 53/00 Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
• CPC Class Codes: A01N 55/02 containing metal atoms
• CPC Class Codes: A61P 3/00 Drugs for disorders of the metabolism of the blood or the extracellular fluid A61P7/00
• CPC Class Codes: C09B 67/0067 Aqueous dispersions of phthalocyanine pigments containing only dispersing agents
• CPC Class Codes: C09B 67/0089 non ionic dispersing agent, e.g. EO or PO addition products

Abstract

Oil-in-water fungicidal formulations are prepared having pigment dispersed therein, the pigment being stable within the oil-in-water emulsion as a result of the addition of suitable silicone surfactants and suitable emulsifiers. The formulations can be prepared either as a 2-pack formulation or as a single formulation. In the case of the single formulation polyethylene glycol is also added. In either case, the formulations show a synergistic effect through the addition of the pigment, the resulting formulations having an increased efficacy. Further, the formulations show a synergistic effect when mixed with conventional chemical fungicides, both being added in reduced amounts compared to recommended rates.

Claims

1. A formulation comprising:

a paraffinic oil comprising an isoparaffinic oil;

one or more emulsifiers, each of which is independently selected from the group consisting of natural and synthetic alcohol ethoxylates, alcohol alkoxylates, glycerol oleate, and nonyl phenol ethoxylates;

a polychlorinated (Cu II) phthalocyanine;

a silicone surfactant; and

water,

wherein the silicone surfactant represents from about 0.1 wt % to about 5 wt % of the total weight of the paraffinic oil, the one or more emulsifiers, the polychlorinated (Cu II) phthalocyanine, and the silicone surfactant;

wherein the one or more emulsifiers represent from about 0.5 wt % to about 5 wt % of the total weight of the paraffinic oil, the one or more emulsifiers, the polychlorinated (Cu II) phthalocyanine, and the silicone surfactant;

wherein the polychlorinated (Cu II) phthalocyanine represents from about 1 wt % to about 10 wt % of the total weight of the paraffinic oil, the one or more emulsifiers, the polychlorinated (Cu II) phthalocyanine, and the silicone surfactant; and

wherein the formulation is an oil-in-water emulsion and the one or more emulsifiers and the silicone surfactant are selected such that the polychlorinated (Cu II) phthalocyanine is maintained in dispersion in the oil-in-water emulsion.

2. The formulation of claim 1, wherein the isoparaffinic oil is a synthetic isoparaffinic oil.

3. The formulation of claim 1, wherein the isoparaffinic oil has an independently selected carbon number distribution of from C16 to C35.

4. The formulation of claim 1, wherein each of the one or more emulsifiers is independently selected from the group consisting of polyoxyethylene(4 to 7) lauryl ether (C₁₂);

polyoxyethylene (10) cetyl ether (C₁₆), polyoxyethylene (2 to

     11) C₁₂-C₁₅ alcohols, polyoxyethylene (3 to

     9) C₁₁-C₁₄ alcohols, and polyoxyethylene (9) C₁₂-C₁₄ alcohols.

5. The formulation of claim 1, wherein each of the one or more emulsifiers is independently selected from the group consisting of natural or synthetic alcohol ethoxylate, glycerol oleate, and nonyl phenol ethoxylates.

6. The formulation of claim 5, wherein each of the one or more emulsifiers is independently selected from the group consisting of polyoxyethylene (4 to 12) lauryl ether (C12);

polyoxyethylene (10) cetyl ether (C16);

polyoxyethylene (10) stearyl ether (C18);

polyoxyethylene (10) oleyl ether (C18 monounsaturated);

polyoxyethylene (2 to

     11) C12-C15 alcohols;

polyoxyethylene (3 to

     9) C11-C14 alcohols;

polyoxyethylene (9) C12 C14 alcohols;

polyoxyethylene (11) C16-C18 alcohols;

polyoxyethylene (20) C12 C15 alcohols, glycerol oleate, and polyoxyethylene (2 to

     8) nonylphenol.

7. The formulation of claim 1, wherein each of the one or more emulsifiers is independently selected from a natural or synthetic alcohol ethoxylate and a glycerol oleate.

8. The formulation of claim 7, wherein each of the one or more emulsifiers is independently selected from the group consisting of polyoxyethylene (4 to 12) lauryl ether (C12);

polyoxyethylene (10) cetyl ether (C16);

polyoxyethylene (10) stearyl ether (C18);

polyoxyethylene (10) oleyl ether (C18 monounsaturated);

polyoxyethylene (2 to

     11) C12-C15 alcohols;

polyoxyethylene (3 to

     9) C11-C14 alcohols;

polyoxyethylene (9) C12 C14 alcohols;

polyoxyethylene (11) C16-C18 alcohols;

polyoxyethylene (20) C12 C15 alcohols, and glycerol oleate.

9. The formulation of claim 1, wherein the one or more emulsifiers represent from about 1 wt % to about 3 wt % of the total weight of the paraffinic oil, one or more emulsifiers, polychlorinated (Cu II) phthalocyanine, and silicone surfactant.

10. The formulation of claim 1, wherein the one or more emulsifiers represent about 2 wt % of the total weight of the paraffinic oil, one or more emulsifiers, polychlorinated (Cu II) phthalocyanine, and silicone surfactant.

11. The formulation of claim 1, wherein the silicone surfactant comprises polyethylene glycols (PEG) according to Formula (IV):

R₁—

O—

(CH₂—

CH₂—

O)_n—

R₂ 

 

Formula (IV)

where;

R₁═

H or CH₂═

CH—

CH₂ or COCH₃

R₂═

H or CH₂═

CH—

CH₂ or COCH₃

n is greater than or equal to 1.

12. The formulation of claim 1, wherein:

the silicone surfactant is selected from the group consisting of trisiloxanes and silicone polyethers of Formula I

13. The formulation of claim 1, wherein

the one or more emulsifiers are selected from the group consisting of polyoxyethylene(4 to 7) lauryl ether (C₁₂);

polyoxyethylene (10) cetyl ether (C₁₆), polyoxyethylene (2 to

     11) Cu-Cis alcohols, polyoxyethylene (3 to

     9) C₁₁-C₁₄ alcohols, and polyoxyethylene (9) C₁₂-C₁₄ alcohols, and

the silicone surfactant comprises polyethylene glycols (PEG) according to Formula (IV);

R₁—

O—

(CH₂—

CH₂—

O)_n—

R₂ 

 

Formula (IV)

where;

R₁═

H or CH₂═

CH—

CH₂ or COCH₃

R₂═

H or CH₂═

CH—

CH₂ or COCH₃

n is greater than or equal to 1.

14. The formulation of claim 1, wherein the formulation further comprises one or more chemical fungicides.

15. The formulation of claim 14, wherein each of the one or more chemical fungicides is independently selected from the group consisting of a demethylation inhibitor, a methyl benzimidazole carbamate, and a dicarboximide.

16. A formulation comprising:

a synthetic isoparaffinic oil;

one or more emulsifiers, each of which is independently selected from the group consisting of natural or synthetic alcohol ethoxylate, glycerol oleate, and nonyl phenol ethoxylates;

a polychlorinated (Cu II) phthalocyanine; and

a silicone surfactant, which is independently selected from the group consisting of trisiloxanes and silicone polyethers of Formula I