Electrochemical device manufacturing

• US 9,494,839 B2
• Filed: 04/04/2012
• Issued: 11/15/2016
• Est. Priority Date: 04/05/2011
• Status: Active Grant

• Current Assignee: Acreo Swedish ICT AB, Lintec Corporation
• Original Assignee: Acreo Swedish ICT AB, Lintec Corporation
• Inventors: Andersson Ersman, Peter, Kawahara, Jun, Katoh, Kazuya, Nilsson, David
• Primary Examiner(s): Arbes, Carl
• Application Number:
  US14/006,999
• Publication Number:
  US 20140041213A1
• Time in Patent Office: 1,686 Days
• US Class Current: 1/1
• CPC Class Codes: G02F 1/155 Electrodes
• CPC Class Codes: Y10T 29/49117 Conductor or circuit manufacturing

Abstract

A process for manufacturing an electrochemically active device comprising the steps of: —providing a substrate (110) comprising an electrode receiving surface portion (111) having substantially constant wetting tension throughout said electrode receiving surface portion, —providing a plurality of first electrodes (120) directly on said electrode receiving surface portion, —leaving intermediate portions (130) of said electrode receiving surface portion (111) free from said electrodes, —providing a layer of electrolyte (140) covering said plurality of first electrodes (120) and said intermediate portions (130), and—wherein wetting tension of the surfaces of the intermediate portions (130) is arranged to act more repelling on the electrolyte compared to the wetting tension of the surfaces of the plurality of first electrodes (120), whereby, the electrolyte is concentrated to the surfaces of the plurality of first electrodes (120), and the surfaces of the intermediate portions (130) are substantially free of electrolyte.

Claims

1. A process for manufacturing of at least a part of an electrochemically active device comprising performing the following steps in sequence directly following each other:

providing a prefabricated substrate (110) comprising an electrode receiving surface portion (111) having a substantially constant first wetting tension throughout said electrode receiving surface portion,

providing a plurality of first electrodes (120) directly on said electrode receiving surface portion having a substantially constant first wetting tension of the prefabricated substrate, wherein the surfaces of said plurality of electrodes have a second wetting tension,

leaving intermediate portions (130) of said electrode receiving surface portion (111) free from said electrodes,

providing a printable electrolyte (140) having a first corresponding surface tension,

arranging said printable electrolyte as a layer of electrolyte (140) directly on each one of said plurality of electrodes, wherein the electrolyte (140) is applied as a layer covering said plurality of first electrodes (120) and said intermediate portions (130), and

awaiting a self-patterning of the electrolyte,

wherein

said first wetting tension of said substrate is lower than or equal to said first corresponding surface tension of said electrolyte, and

said second wetting tension of said electrodes is higher than said first corresponding surface tension of said electrolyte,

which provides the self-patterning of the electrolyte.

2. A process according to claim 1, wherein the viscosity of the electrolyte is lower than 7000 mPa s, or lower than 6000 mPa s, or lower than 3000 mPa s, or lower than 1000 mPa s, or lower than 500 mPa s.

3. A process according to claim 1, wherein the material of the first electrodes has a wetting tension larger than 73 mN/m, and the material of the electrode receiving surface portion has a wetting tension of at least 38 mN/m.

4. A process according to claim 1, wherein the adhesion energy of the surface of the printed first electrodes is larger than 10 mJ/m² relative deionized water, and the material of the electrode receiving surface portion has a wetting tension of at least 38 mN/m.

5. A process according to claim 1, wherein the electrolyte has a corresponding surface tension higher than 42 mN/m, or a corresponding surface tension between 43 mN/m and 73 mN/m.

6. A process according to claim 1, wherein the thickness of the electrodes is between 0.01 μ

m and 100 μ

m, or between 0.05 μ

m and 50 μ

m, or between 1 μ

m and 20 μ

m.

7. A process according to claim 1, wherein said prefabricated substrate is flexible.

8. A process according to claim 1, wherein said layer of electrolyte is applied as one unitary layer covering said plurality of first electrodes and said intermediate portions, and wherein said layer of electrolyte is preferably applied as a substantially uniform layer.

9. A process according to claim 1, wherein said step of providing said plurality of first electrodes comprises providing the electrodes by means of printing or coating.

10. A process according to claim 1, wherein the layer of electrolyte comprises smaller and substantially larger ion-complexes, where the smaller ion-complexes have a negative electric charge and the larger ion-complexes have a positive electric charge, and/or wherein said electrolyte is a polyelectrolyte comprising poly-cations.

11. A process according to claim 1, wherein the prefabricated substrate further comprises a first portion and a second portion being different from said first portion, and wherein the process further comprising the step of extracting said first portion of the prefabricated substrate from said second portion of the prefabricated substrate and providing said first portion for use in an electrochemically active device.

12. A process according to claim 11, wherein said step of extracting said first portion of the prefabricated substrate from said second portion of the prefabricated substrate, comprises extracting a first portion of the prefabricated substrate comprising at least 5×

7 electrodes arranged in a matrix configuration.

13. A process according to claim 1, wherein the part of an electrochemically active device is used when assembling an electrochromic display device.

14. A process for manufacturing an electrochemically active device comprising:

manufacturing of a part of an electrochemically active device according to the method of claim 1;

providing a plurality of second electrodes (125), wherein said layer of electrolyte (140) is sandwiched between pairs of one first electrode (121) and one second electrode (126), and wherein the electrolyte is in ionic contact with both the first electrode (121) and the second electrode (126) of the respective pairs of one first electrode (121) and one second electrode (126).

15. A process for manufacturing an electrochemically active device according to claim 14, wherein said one first electrode is selected from said plurality of first electrodes, and said one second electrode is selected from said plurality of second electrodes.

16. A process according to claim 14, wherein in the step of providing a plurality of second electrodes, each first electrode in said plurality of first electrodes (120) and/or each second electrode in said plurality of second electrodes (125) comprises electrochemically active material.

17. The process according to claim 9, wherein the plurality of first electrodes is provided by means of a technique selected from the group consisting of screen printing, wire-bar coating, knife coating, bar coating, spin coating, dip coating and spray coating.