Three-way catalytic converter using nanoparticles

• US 9,511,352 B2
• Filed: 11/20/2013
• Issued: 12/06/2016
• Est. Priority Date: 11/21/2012
• Status: Active Grant

• Current Assignee: Umicore AG & Company KG (Umicore S.A.)
• Original Assignee: SDC Materials,Inc.
• Inventors: Qi, Xiwang, Biberger, Maximilian A.
• Primary Examiner(s): Nguyen, Cam N.
• Application Number:
  US14/442,368
• Publication Number:
  US 20160059216A1
• Time in Patent Office: 1,112 Days
• Field of Search: 502/304, 502/327, 502/328, 502332-334, 502/339, 502/349, 502/355, 502/415, 502/439, 502/527.12, 502/527.13, 423/212, 422/177, 602/72, 602/73
• US Class Current: 1/1
• CPC Class Codes: B01D 2255/1021 Platinum
• CPC Class Codes: B01D 2255/1023 Palladium
• CPC Class Codes: B01D 2255/1025 Rhodium
• CPC Class Codes: B01D 2255/2042 Barium
• CPC Class Codes: B01D 2255/2065 Cerium
• CPC Class Codes: B01D 2255/20715 Zirconium
• CPC Class Codes: B01D 2255/407 Zr-Ce mixed oxides
• CPC Class Codes: B01D 2255/9022 Two layers
• CPC Class Codes: B01D 2255/908 O2-storage component incorporated in the catalyst
• CPC Class Codes: B01D 2255/91 NOx-storage component incorporated in the catalyst
• CPC Class Codes: B01D 2255/9202 Linear dimensions
• CPC Class Codes: B01D 2258/014 Stoichiometric gasoline engines
• CPC Class Codes: B01D 53/945 characterised by a specific catalyst
• CPC Class Codes: B01J 21/04 Alumina
• CPC Class Codes: B01J 21/066 Zirconium or hafnium; Oxides or hydroxides thereof
• CPC Class Codes: B01J 23/42 Platinum
• CPC Class Codes: B01J 23/44 Palladium
• CPC Class Codes: B01J 23/462 Ruthenium
• CPC Class Codes: B01J 23/58 with alkali- or alkaline earth metals
• CPC Class Codes: B01J 23/63 with rare earths or actinides
• CPC Class Codes: B01J 35/19 : Catalysts containing parts with different compositions
• CPC Class Codes: B01J 35/23 : in a colloidal state
• CPC Class Codes: B01J 35/56 : Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
• CPC Class Codes: B01J 37/0045 : Drying a slurry, e.g. spray drying
• CPC Class Codes: B01J 37/0215 : Coating
• CPC Class Codes: B01J 37/0228 : in several steps
• CPC Class Codes: B01J 37/0244 : Coatings comprising several layers
• CPC Class Codes: B01J 37/349 : making use of flames, plasmas or lasers
• CPC Class Codes: F01N 3/101 : Three-way catalysts
• CPC Class Codes: Y02A 50/20 : Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
• CPC Class Codes: Y02T 10/12 : Improving ICE efficiencies
• CPC Class Codes: Y10T 428/24149 : Honeycomb-like
• CPC Class Codes: Y10T 428/25 : Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles

Abstract

The present disclosure relates to a substrate comprising nanomaterials for treatment of gases, washcoats for use in preparing such a substrate, and methods of preparation of the nanomaterials and the substrate comprising the nanomaterials. More specifically, the present disclosure relates to a substrate comprising nanomaterial for three-way catalytic converters for treatment of exhaust gases.

Claims

1. A coated substrate comprising:

oxidative catalytically active particles comprising oxidative composite nanoparticles bonded to first micron-sized carrier particles comprising metal oxide, wherein the oxidative composite nanoparticles comprise a first support nanoparticle comprising metal oxide and one or more oxidative catalyst nanoparticles comprising a first platinum group metal; and

reductive catalytically active particles comprising reductive composite nanoparticles bonded to second micron-sized carrier particles comprising metal oxide, wherein the reductive composite nanoparticles comprise a second support nanoparticle comprising metal oxide and one or more reductive catalyst nanoparticles comprising a second platinum group metal;

wherein the coated substrate has a platinum group metal loading of about 0.5 g/l to about 4.0 g/l.

2. The coated substrate of claim 1, wherein the coated substrate comprises at least two washcoat layers in which the oxidative catalytically active particles are in one washcoat layer and the reductive catalytically active particles are in another washcoat layer.

3. The coated substrate of claim 1, wherein the oxidative catalytically active particles and the reductive catalytically active particles are in the same washcoat layer.

4. The coated substrate of claim 1, wherein the oxidative catalyst nanoparticles comprise platinum, palladium, or a mixture thereof.

5. The coated substrate of claim 4, wherein the oxidative catalyst nanoparticles comprise palladium.

6. The coated substrate of claim 1, wherein the first support nanoparticles comprise aluminum oxide.

7. The coated substrate of claim 1, wherein the first micron-sized carrier particles comprise aluminum oxide.

8. The coated substrate of claim 1, wherein the first micron-sized carrier particle is pre-treated at a temperature range of about 700°

C. to about 1500°

C.

9. The coated substrate of claim 1, wherein the reductive catalyst nanoparticles comprise rhodium.

10. The coated substrate of claim 1, wherein the second support nanoparticles comprise cerium zirconium oxide.

11. The coated substrate of claim 1, wherein the second micron-sized carrier particles comprise cerium zirconium oxide.

12. The coated substrate of claim 1, wherein the support nanoparticles have an average diameter of 10 nm to 20 nm.

13. The coated substrate of claim 1, wherein the catalytic nanoparticles have an average diameter of between 1 nm and 5 nm.

14. The coated substrate of claim 1, further comprising an oxygen storage component.

15. The coated substrate of claim 14, wherein the oxygen storage component is cerium zirconium oxide or cerium oxide.

16. The coated substrate of claim 1, further comprising a NOx absorber component.

17. The coated substrate of claim 16, wherein the NOx absorber is nano-sized BaO.

18. The coated substrate of claim 16, wherein the NOx absorber is micron-sized BaO.

19. The coated substrate of claim 1, wherein the substrate comprises cordierite.

20. The coated substrate of claim 1, wherein the substrate comprises a grid array structure.

21. The coated substrate of claim 1, wherein the coated substrate has a platinum group metal loading of 4 g/l or less and a light-off temperature for carbon monoxide at least 5°

C. lower than the light-off temperature of a substrate with the same platinum group metal loading deposited by wet-chemistry methods.

22. The coated substrate of claim 1, wherein the coated substrate has a platinum group metal loading of 4 g/l or less and a light-off temperature for hydrocarbon at least 5°

C. lower than the light-off temperature of a substrate with the same platinum group metal loading deposited by wet-chemistry methods.

23. The coated substrate of claim 1, wherein the coated substrate has a platinum group metal loading of 4 g/l or less and a light-off temperature for nitrogen oxide at least 5°

C. lower than the light-off temperature of a substrate with the same platinum group metal loading deposited by wet-chemistry methods.

24. The coated substrate of claim 1, wherein said coated substrate has a platinum group metal loading of about 0.5 g/l to about 4.0 g/l, and after 125,000 miles of operation in a vehicular catalytic converter, the coated substrate has a light-off temperature for carbon monoxide at least 5°

C. lower than a coated substrate prepared by depositing platinum group metals by wet chemical methods having the same platinum group metal loading after 125,000 miles of operation in a vehicular catalytic converter.

25. The coated substrate of claim 1, wherein a ratio of oxidative catalytically active particles to reductive catalytically active particles is between 6:

1 and 40;

1.

26. A catalytic converter comprising a coated substrate of claim 1.

27. An exhaust treatment system comprising a conduit for exhaust gas and a catalytic converter comprising a coated substrate of claim 1.

28. A vehicle comprising a catalytic converter according to claim 26.

29. A method of treating an exhaust gas, comprising contacting the coated substrate of claim 1 with the exhaust gas.

30. A method of treating an exhaust gas, comprising contacting the coated substrate of claim 1 with the exhaust gas, wherein the substrate is housed within a catalytic converter configured to receive the exhaust gas.

31. An oxidative washcoat composition comprising a solids content of:

35-75% by weight of oxidative catalytic active particles comprising composite oxidative nano-particles bonded to micron-sized carrier particles, and the composite oxidative nano-particles comprise a support nano-particle and an oxidative catalytic nano-particle;

5-25% by weight of micron-sized cerium zirconium oxide;

0.5-10% by weight of boehmite;

10-40% by weight micron-sized Al₂O₃, and

optionally further comprising BaO.

32. A reductive washcoat composition comprising a solids content of:

40-95% by weight of reductive catalytic active particles comprising composite reductive nano-particles bonded to micron-sized carrier particles, and the composite reductive nano-particles comprise a support nano-particle and a reductive catalytic nano-particle;

optionally comprising up to 30% by weight of micron-sized cerium zirconium oxide;

0.5-10% by weight of boehmite;

1-25% by weight micron-sized Al₂O₃; and

optionally further comprising BaO.