Well treatment fluids and methods utilizing nano-particles

• US 9,512,351 B2
• Filed: 09/12/2013
• Issued: 12/06/2016
• Est. Priority Date: 05/10/2007
• Status: Expired due to Fees

• Current Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Original Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Inventors: Roddy, Craig Wayne, Chatterji, Jiten, Cromwell, Roger Stanley
• Primary Examiner(s): Figueroa, John J
• Application Number:
  US14/025,638
• Publication Number:
  US 20140008067A1
• Time in Patent Office: 1,181 Days
• Field of Search: None
• US Class Current: 1/1
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: B82Y 99/00 Subject matter not provided for in other groups of this subclass
• CPC Class Codes: C04B 14/062 Microsilica, e.g. colloïdal silica preparing microsilica slurries or suspensions C04B18/148
• CPC Class Codes: C04B 14/30 Oxides other than silica ferrites C04B14/363
• CPC Class Codes: C04B 14/303 Alumina
• CPC Class Codes: C04B 14/308 Iron oxide
• CPC Class Codes: C04B 20/008 Micro- or nanosized fillers, e.g. micronised fillers with particle size smaller than that of the hydraulic binder colloidal silica C04B14/062 ; silica fume C04B18/146
• CPC Class Codes: C04B 20/10 Coating or impregnating roofing granules E04D7/005
• CPC Class Codes: C04B 2111/00008 Obtaining or using nanotechnology related materials
• CPC Class Codes: C04B 28/02 containing hydraulic cements other than calcium sulfates
• CPC Class Codes: C09K 2208/10 Nanoparticle-containing well treatment fluids
• CPC Class Codes: C09K 8/426 for plugging
• CPC Class Codes: C09K 8/428 for squeeze cementing, e.g. for repairing
• CPC Class Codes: C09K 8/467 containing additives for specific purposes
• CPC Class Codes: C09K 8/62 Compositions for forming crevices or fractures
• CPC Class Codes: C09K 8/80 Compositions for reinforcing fractures, e.g. compositions of proppants used to keep the fractures open
• CPC Class Codes: E21B 33/14 for cementing casings into boreholes
• CPC Class Codes: E21B 43/267 reinforcing fractures by propping
• CPC Class Codes: Y10S 507/906 Solid inorganic additive in defined physical form
• CPC Class Codes: Y10S 977/963 Miscellaneous

Abstract

Disclosed embodiments relate to well treatment fluids and methods that utilize nano-particles. Exemplary nano-particles are selected from the group consisting of particulate nano-silica, nano-alumina, nano-zinc oxide, nano-boron, nano-iron oxide, and combinations thereof. Embodiments also relate to methods of cementing that include the use of nano-particles. An exemplary method of cementing comprises introducing a cement composition into a subterranean formation, wherein the cement composition comprises cement, water and a particulate nano-silica. Embodiments also relate to use of nano-particles in drilling fluids, completion fluids, simulation fluids, and well clean-up fluids.

Claims

1. A method of treating a subterranean formation comprising:

providing particles, wherein the particles comprise three size ranges disjointed from one another, wherein a first size range includes nano-particles from about 7 nm to about 50 nm, wherein a second size range includes particles from about 0.05 microns to about 0.5 microns, and wherein a third size range includes particles from about 200 microns to about 800 microns, wherein the nano-particles comprise nano-boron, wherein the nano-particles are particulate and non-colloidal and encapsulated in a degradable coating;

including the particles in a treatment fluid;

introducing into the subterranean formation the treatment fluid at or above a pressure sufficient to create or enhance one or more fractures in the subterranean formation, wherein the nano-particles are included as proppant in the treatment fluid; and

depositing at least a portion of the nano-particles in the one or more fractures, wherein the fractures are prevented from fully closing upon the release of pressure and wherein the fractures form conductive channels through which fluids may flow.

2. The method of claim 1, wherein the nano-particles further comprise nano-silica.

3. The method of claim 1, wherein the nano-particles further comprise at least one nano-particle selected from the group consisting of nano-aluminum, nano-zinc oxide, nano-iron oxide and combinations thereof.

4. The method of claim 1, further comprising producing one or more hydrocarbons from a well bore penetrating the subterranean formation.

5. A method of treating a subterranean formation comprising:

providing particulate materials, wherein the particulate materials comprise three size ranges disjointed from one another, wherein a first size range includes nano-particles from about 7 nm to about 50 nm, wherein a second size range includes particles from about 0.05 microns to about 0.5 microns, and wherein a third size range includes particles from about 200 microns to about 800 microns, wherein the nano-particles comprise nano-boron, wherein the nano-particles are non-colloidal and encapsulated in a degradable coating;

including the particulate materials in a treatment fluid;

introducing the treatment fluid comprising the particulate materials into the subterranean formation at or above a pressure sufficient to create or enhance one or more fractures in the subterranean formation, wherein the fractures form conductive channels through which fluids may flow,

determining a packing volume fraction for the particulate materials in the treatment fluid.

6. The method of claim 5, wherein the nano-particles further comprise nano-silica.

7. The method of claim 5, wherein the nano-particles further comprise a particulate nano-silica.

8. The method of claim 5, wherein the nano-particles further comprise at least one nano-particle selected from the group consisting of nano-aluminum, nano-zinc oxide, nano-iron oxide and combinations thereof.

9. A method of treating a subterranean formation comprising:

providing particles, wherein the nano-particles are particulate and non-colloidal, wherein the nanoparticles comprise nano-boron;

including the nano-particles in a treatment fluid;

introducing into the subterranean formation the treatment fluid at or above a pressure sufficient to create or enhance one or more fractures in the subterranean formation, wherein the nano-particles are included as proppant in the treatment fluid; and

depositing at least a portion of the nano-particles in the one or more fractures, wherein the fractures are prevented from fully closing upon the release of pressure and wherein the fractures form conductive channels through which fluids may flow.

10. The method of claim 9, wherein the nano-particles further comprise nano-silica.

11. The method of claim 9, wherein the proppant comprises a particulate blend of at least particles less than 0.5 microns and particulates greater than 1 millimeter.

12. The method of claim 9, wherein the nano-particles have a particle size of less than or equal to about 100 nm.

13. The method of claim 9, wherein the nano-particles have a particle size in the range of from about 1 nm to about 100 nm.

14. The method of claim 9, further comprising producing one or more hydrocarbons from a well bore penetrating the subterranean formation.