Method for quantitative determination of oxidant and apparatus for quantitative determination of oxidant

• US 9,513,227 B2
• Filed: 04/21/2014
• Issued: 12/06/2016
• Est. Priority Date: 04/26/2013
• Status: Expired due to Fees

• Current Assignee: Panasonic Intellectual Property Management Co., Ltd. (Panasonic Holdings Corporation)
• Original Assignee: Panasonic Intellectual Property Management Co., Ltd. (Panasonic Holdings Corporation)
• Inventors: Onodera, Mari, Imai, Shin-ichi, Kumagai, Hironori
• Primary Examiner(s): Mui, Christine T
• Application Number:
  US14/409,956
• Publication Number:
  US 20160011118A1
• Time in Patent Office: 960 Days
• Field of Search: 436/10, 436/8, 422/50, 422/51, 422/68.1
• US Class Current: 1/1
• CPC Class Codes: G01N 2021/755 Comparing readings with/without reagents, or before/after reaction
• CPC Class Codes: G01N 21/31 Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry G01N21/72 takes precedence
• CPC Class Codes: G01N 21/75 Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated systems in which material is burnt in a flame or plasma G01N21/72, G01N21/73
• CPC Class Codes: G01N 21/78 producing a change of colour
• CPC Class Codes: G01N 2201/061 Sources
• CPC Class Codes: G01N 2201/127 Calibration; base line adjustment; drift compensation
• CPC Class Codes: G01N 31/005 investigating the presence of an element by oxidation G01N31/12 takes precedence
• CPC Class Codes: G01N 31/228 for peroxides

Abstract

The present invention provides a method for quantitative determination of oxidant which method is capable of accurately and rapidly performing quantitative determination of oxidant at low cost, and an apparatus for quantitative determination of oxidant used in the method. The method for quantitative determination of oxidant according to the present invention is a method for quantitative determination of oxidant performing quantitative determination of oxidant in a sample using a redox reaction, the method including: adding one kind of reducing agent to a sample solution containing one or a plurality of kinds of oxidants having different lifetimes; producing an absorbance curve by measuring a time change in absorbance of the post-color-change or post-coloring reducing agent; and performing the quantitative determination of the oxidant while identifying the oxidant in the sample solution based on the obtained absorbance curve.

Claims

1. A method for quantitative determination of an oxidant in a sample using a redox reaction, the method comprising:

adding one kind of reducing agent to a sample solution containing one or a plurality of kinds of oxidants having different lifetimes;

producing an absorbance curve by measuring a time change in absorbance of the sample solution after the one kind of reducing agent is added to the sample solution; and

performing the quantitative determination of the oxidant while identifying the oxidant in the sample solution based on the obtained absorbance curve, wherein

the oxidant in the sample solution is identified by comparing the obtained absorbance curve with a separately-acquired standard approximate curve indicating a time change in absorbance of a known oxidant,

the obtained absorbance curve is broken down into at least one kind of approximate curve by a curve approximate analysis to calculate a half-value width of each approximate curve and initial absorbance at a time of zero of each approximate curve, and

the half-value width of each approximate curve is compared with a half-value width of a separately-acquired standard approximate curve of the known oxidant to identify an oxidant attributing to each approximate curve.

2. The method for quantitative determination of oxidant according to claim 1, wherein the quantitative determination of the identified oxidant is performed using the initial absorbance and a separately-acquired calibration curve indicating a relationship between absorbance and a concentration for the known oxidant.

3. The method for quantitative determination of oxidant according to claim 1, wherein the approximate curve is a Gaussian curve.

4. An apparatus for quantitative determination of an oxidant in a sample using a redox reaction, the apparatus comprising

a measuring unit including:

a reaction unit that causes a sample solution containing one or a plurality of kinds of oxidants having different lifetimes to react with one kind reducing agent;

a light source that irradiates the reaction unit with light; and

a light receiver that detects light transmitted through the reaction unit to measure absorbance of the sample solution, and

a controller including;

a storage in which a standard approximate curve indicating a time change in absorbance of a known oxidant and a calibration curve indicating a relationship between absorbance and a concentration for the known oxidant are stored; and

a calculator that produces an absorbance curve by measuring a time change in absorbance of the sample solution after the one kind of reducing agent is added to the sample solution, and performs the quantitative determination of the oxidant while identifying the oxidant in the sample solution based on the absorbance curve, wherein

the calculator breaks down the absorbance curve into at least one kind of approximate curve by a curve approximate analysis to calculate a half-value width of each approximate curve and an initial absorbance at a time of zero of each approximate curve, compares the half-value width of each approximate curve with a half-value width of the standard approximate curve of the known oxidant to identify the oxidant attributing to each approximate curve, and performs the quantitative determination of the identified oxidant using the initial absorbance and a separately-acquired calibration curve indicating a relationship between absorbance and a concentration for the known oxidant.

5. A method, comprising:

(i) adding a reducing agent to a sample solution including oxidants having different lifetimes;

(ii) after the adding (i), obtaining an absorbance curve by measuring a time change in absorbance of the sample solution;

(iii) obtaining approximate curves from the absorbance curve by a curve approximate analysis; and

(iv) identifying the oxidants by comparing each of the approximate curves with standard approximate curves, each of the standard approximate curves being obtained from an absorbance curve indicating a time change in absorbance caused by a redox reaction between a known oxidant and the reducing agent, the standard approximate curves being different from each other,

wherein in the obtaining (iii), each of the approximate curves is a Gaussian curve.

6. The method according to claim 5, wherein

in the identifying (iv), each of the standard approximate curves is a Gaussian curve.

8. The method according to claim 5, further comprising:

(v) determining a quantity of each of the oxidants by applying absorbance at a time of zero of corresponding one of the approximate curves to a calibration curve, the calibration curve indicating a relationship between absorbance and a concentration of the known oxidant corresponding to the each of the oxidants.

9. The method according to claim 5, wherein the method is performed without a masking agent.

10. The method according to claim 5, wherein the method is performed without a blank test.

7. A method, comprising:

(i) adding a reducing agent to a sample solution including oxidants having different lifetimes;

(ii) after the adding (i), obtaining an absorbance curve by measuring a time change in absorbance of the sample solution;

(iii) obtaining approximate curves from the absorbance curve by a curve approximate analysis; and

(iv) identifying the oxidants by comparing each of the approximate curves with standard approximate curves, each of the standard approximate curves being obtained from an absorbance curve indicating a time change in absorbance caused by a redox reaction between a known oxidant and the reducing agent, the standard approximate curves being different from each other, wherein

the identifying (iv) comprises;

(iv-1) calculating a half-value width of each of the approximate curves; and

(iv-2) identifying the oxidants by comparing the half-value width of each of the approximate curves with half-value widths of the standard approximate curves.