Processes and systems for the production of alcohols

• US 9,523,104 B2
• Filed: 03/11/2014
• Issued: 12/20/2016
• Est. Priority Date: 03/12/2013
• Status: Active Grant

• Current Assignee: Gevo Incorporated
• Original Assignee: Butamax Advanced Biofuels LLC (International Flavors & Fragrances Incorporated)
• Inventors: Fuchs, Benjamin, Roesch, Brian Michael, Stolarski, Mathias E., Wood, James Gregory
• Primary Examiner(s): Carlson, Karen Cochrane
• Assistant Examiner(s): MOSS, NATALIE M
• Application Number:
  US14/203,809
• Publication Number:
  US 20140273127A1
• Time in Patent Office: 1,015 Days
• US Class Current: 1/1
• CPC Class Codes: C12P 7/06 Ethanol, i.e. non-beverage
• CPC Class Codes: C12P 7/10 substrate containing cellulosic material
• CPC Class Codes: C12P 7/16 Butanols
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel

Abstract

The present invention relates to processes and systems for the production of fermentative products such as ethanol and butanol. The present invention also provides methods for separating feed stream components for improved biomass processing productivity.

Claims

1. A method for producing product alcohol comprising:

providing a feedstock slurry comprising fermentable carbon source, undissolved solids, and oil;

separating at least a portion of the feedstock slurry forming (i) an aqueous solution comprising fermentable carbon source, (ii) a wet cake comprising solids, and (iii) an oil stream;

wherein the step of separating at least a portion of the feedstock slurry includes using a three-phase centrifuge to separate the feedstock slurry;

returning at least a portion of the oil stream to the three-phase centrifuge; and

adding the aqueous solution to a fermentation broth comprising microorganisms in a fermentor whereby a product alcohol is produced.

2. The method of claim 1, wherein the three-phase centrifuge comprises an overflow mechanism.

3. The method of claim 2, wherein the overflow mechanism is adjustable.

4. The method of claim 2, wherein the overflow mechanism is a weir.

5. The method of claim 2, wherein the overflow mechanism is used for discharging the oil stream.

6. The method of claim 2, wherein the overflow mechanism is used for discharging the aqueous solution.

7. The method of claim 1, wherein the three-phase centrifuge comprises a pressure discharge mechanism.

8. The method of claim 6, wherein the pressure discharge mechanism is adjustable.

9. The method of claim 6, wherein the pressure discharge mechanism is selected from the group consisting of a dip tube and an impeller.

10. The method of claim 6, wherein the pressure discharge mechanism is used for discharging the aqueous solution.

11. The method of claim 6, wherein the pressure discharge mechanism is used for discharging the oil stream.

12. The method of claim 1, wherein one or more control parameters of the three-phase centrifuge is adjusted to improve separation of the feedstock slurry.

13. The method of claim 12, wherein the one or more control parameters are selected from differential speed, bowl speed, flow rate, impeller position, weir position, scroll pitch, residence time, and discharge volume.

14. The method of claim 1, wherein the oil stream is separated from the feedstock slurry intermittently.

15. The method of claim 1, wherein the oil stream is separated from the feedstock slurry in batch mode.

16. The method of claim 1, further comprising the step of washing the wet cake to recover oil and fermentable sugars.

17. The method of claim 16, wherein the wet cake is washed with water, hexane, isobutanol, isohexane, ethanol, petroleum distillates, or mixtures thereof.

18. The method of claim 17, wherein the water is fresh water, backset, cook water, process water, lutter water, evaporation water, or combinations thereof.

19. The method of claim 16, wherein the washing step is repeated two or more times.

20. The method of claim 1, further comprising recombining at least a portion of the aqueous solution with at least a portion of the wet cake to form a mixture of wet cake and aqueous solution;

and adding the mixture to the fermentation broth.

21. The method of claim 1, wherein the product alcohol is methanol, ethanol, propanol, butanol, pentanol, and isomers thereof.

22. The method of claim 21, wherein butanol is 1-butanol, 2-butanol, or isobutanol.

23. The method of claim 1, wherein the feedstock slurry comprises oil in an amount that is less than about two volume percent of the feedstock slurry.

24. The method of claim 1, wherein the feedstock slurry comprises oil in an amount that is less than about one volume percent of the feedstock slurry.

25. The method of claim 1, further comprising liquefying a feedstock to create a feedstock slurry.

26. The method of claim 25, wherein the feedstock is rye, wheat, corn, corn mash, cane, cane mash, barley, cellulosic material, lignocellulosic material, or mixtures thereof.

27. The method of claim 1, further comprising separating the aqueous solution forming (i) a second aqueous solution comprising fermentable carbon source, (ii) a second wet cake comprising solids, and (iii) a second oil stream.

28. The method of claim 27, wherein the aqueous solution is separated by decanter bowl centrifugation, three-phase centrifugation, disk stack centrifugation, filtering centrifugation, decanter centrifugation, filtration, microfiltration, vacuum filtration, beltfilter, pressure filtration, membrane filtration, crossflow filtration, drum filter, filtration using a screen, screen separation, rotary screen, grating, porous grating, flotation, hydrocyclone, filter press, screwpress, gravity settler, or vortex separator.

35. The method of claim 1, wherein the three-phase centrifuge comprises a pressure discharge mechanism.

36. The method of claim 35, wherein the pressure discharge mechanism is adjustable.

37. The method of claim 35, wherein the pressure discharge mechanism is selected from the group consisting of a dip tube and an impeller.

38. The method of claim 35, wherein the pressure discharge mechanism is used for discharging the aqueous solution or discharging the oil stream.

46. The method of claim 1, wherein the product alcohol is methanol, ethanol, propanol, butanol, pentanol, and isomers thereof.

47. The method of claim 46, wherein butanol is 1-butanol, 2-butanol, or isobutanol.

29. A method to improve oil recovery from a feedstock slurry comprising:

providing a feedstock slurry comprising fermentable carbon source, undissolved solids, and oil;

separating at least a portion of the feedstock slurry forming (i) an aqueous solution comprising fermentable carbon source, (ii) a wet cake comprising solids, and (iii) an oil stream; and

returning at least a portion of the oil stream to the feedstock slurry;

wherein an increased concentration of oil in the feedstock slurry improves the recovery of oil from the feedstock slurry.

30. A method for producing product alcohol comprising:

providing a feedstock slurry comprising fermentable carbon source, undissolved solids, and oil;

separating at least a portion of the feedstock slurry forming (i) an aqueous solution comprising fermentable carbon source, (ii) a wet cake comprising solids, and (iii) an oil stream;

wherein the step of separating at least a portion of the feedstock slurry includes using a three-phase centrifuge to separate the feedstock slurry;

combining the oil stream with feedstock slurry to form a mixture of oil and feedstock slurry;

returning the mixture to the three-phase centrifuge; and

adding the aqueous solution to a fermentation broth comprising microorganisms in a fermentor whereby a product alcohol is produced.

31. The method of claim 30, wherein the three-phase centrifuge comprises an overflow mechanism.

32. The method of claim 31, wherein the overflow mechanism is adjustable.

33. The method of claim 31, wherein the overflow mechanism is a weir.

34. The method of claim 31, wherein the overflow mechanism is used for discharging the oil stream or discharging the aqueous solution.

39. The method of claim 30, wherein one or more control parameters of the three-phase centrifuge is adjusted to improve separation of the feedstock slurry.

40. The method of claim 39, wherein the one or more control parameters are selected from differential speed, bowl speed, flow rate, impeller position, weir position, scroll pitch, residence time, and discharge volume.

41. The method of claim 30, wherein the oil stream is separated from the feedstock slurry intermittently.

42. The method of claim 30, wherein the oil stream is separated from the feedstock slurry in batch mode.

43. The method of claim 30, further comprising the step of washing the wet cake to recover oil and fermentable sugars.

44. The method of claim 43, wherein the wet cake is washed with water, hexane, isobutanol, isohexane, ethanol, petroleum distillates, or mixtures thereof.

45. The method of claim 30, further comprising recombining at least a portion of the aqueous solution with at least a portion of the wet cake to form a mixture of wet cake and aqueous solution;

and adding the mixture to the fermentation broth.

48. The method of claim 30, further comprising separating the aqueous solution forming (i) a second aqueous solution comprising fermentable carbon source, (ii) a second wet cake comprising solids, and (iii) a second oil stream.

49. The method of claim 48, wherein the aqueous solution is separated by decanter bowl centrifugation, three-phase centrifugation, disk stack centrifugation, filtering centrifugation, decanter centrifugation, filtration, microfiltration, vacuum filtration, beltfilter, pressure filtration, membrane filtration, crossflow filtration, drum filter, filtration using a screen, screen separation, rotary screen, grating, porous grating, flotation, hydrocyclone, filter press, screwpress, gravity settler, or vortex separator.