Enhancing biochar performance using pyrolysis acid stream

• US 9,527,780 B2
• Filed: 05/23/2014
• Issued: 12/27/2016
• Est. Priority Date: 05/24/2013
• Status: Active Grant

• Current Assignee: Carbon Technology Holding LLC
• Original Assignee: Cool Planet Energy Systems, Inc.
• Inventors: Bontchev, Ranko Panayotov, Wilson, Richard W., Hago, Wilson
• Primary Examiner(s): HENDRICKSON, STUART L
• Application Number:
  US14/286,261
• Publication Number:
  US 20140345343A1
• Time in Patent Office: 949 Days
• US Class Current: 1/1
• CPC Class Codes: C01B 32/05 Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
• CPC Class Codes: C01B 32/366 by physical processes, e.g. by irradiation, by using electric current passing through carbonaceous feedstock or by using recyclable inert heating bodies
• CPC Class Codes: C05D 9/00 Other inorganic fertilisers
• CPC Class Codes: C05F 11/00 Other organic fertilisers
• CPC Class Codes: C05F 11/02 from peat, brown coal, and similar vegetable deposits
• CPC Class Codes: C09K 17/02 containing inorganic compounds only
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02E 50/30 Fuel from waste, e.g. synthetic alcohol or diesel

Abstract

A method of producing a modified biochar and the use of the biochar as a soil amendment. The modified biochar can be produced by contacting biochar with an acid-containing solution obtained from an acid containing stream produced in a pyrolysis process, which produces biochar. In accordance with one aspect, a cellulose-containing biomass is pyrolyzed to generate a gaseous organic acid-containing stream, which is condensed to produce an organic acid-containing solution. The biochar is then modified by contact with the organic acid-containing solution.

Claims

1. A method of producing a modified biochar comprising:

a) obtaining an acid-containing solution from a stream produced in a process for pyrolyzing biomass, wherein the acid-containing solution is produced from pyrolysis at temperatures between 300°

C. and 600°

C.; and

b) contacting a biochar with at least a portion of the acid-containing solution to provide a modified biochar.

2. The method of claim 1, wherein the acid-containing stream is produced from mild pyrolysis of the biomass at temperatures below 320°

C.

3. The method of claim 2, further comprising pyrolyzing the resulting mildly pyrolyzed biomass at higher temperatures to produce biochar.

4. The method of claim 3, wherein the mild pyrolysis step occurs at a different location than the biochar producing pyrolysis.

5. The method of claim 1, wherein the acid-containing stream is obtained from a biomass wash prior to pyrolysis.

6. The method of claim 5, wherein the biomass washing occurs at a different location than the biochar producing pyrolysis process.

7. The method of claim 5, wherein the biomass wash comprises an acid.

8. The method of claim 7, wherein some or all of the acid is recycled from a step in the pyrolysis process.

9. The method of claim 7, wherein some or all of the acid is recycled from a step in the biochar modification process.

10. The method of claim 5, wherein the biomass wash comprises water.

11. The method of claim 10, wherein some or all of the water is recycled from a step in the pyrolysis process.

12. The method of claim 10, wherein some or all of the water is recycled from a step in the biochar modification process.

13. The method of claim 1, wherein the acid-containing stream is produced from downstream processing of vapors evolved from biomass pyrolysis.

14. The method of claim 13, wherein the acid-containing stream is separated from a water insoluble stream.

15. The method of claim 1, wherein the biomass comprises a lignocellulosic material.

16. The method of claim 15, wherein the lignocellulosic material comprises one or more of corn stover, corn cobs, empty fruit bunches, wood, wood residue, sawdust, sugar cane bagasse, switchgrass, sorghum, and agricultural crop wastes.

17. The method of claim 1, wherein the acid-containing solution comprises an organic acid.

18. The method of claim 17, wherein the organic acid-containing solution contains at least one acid selected from the group consisting of acetic acid, formic acid, propionic acid, glycolic acid, and other carboxylic acids.

19. The method of claim 1, wherein the acid-containing solution comprises an inorganic acid.

20. The method of claim 1, wherein the acid-containing solution contains between 10% to nearly 100% water by volume.

21. The method of claim 20, wherein the acid-containing solution contains between 80-100% water by volume.

22. The method of claim 21, wherein the acid-containing solution contains between 95% and 99.9% water by volume.

23. The method of claim 1, wherein the biochar is produced by pyrolysis of the same biomass that is used to generate the acid-containing stream.

24. The method of claim 1, wherein the biochar is produced by pyrolysis of a biomass different than the biomass used to generate the acid-containing stream.

25. The method of claim 1, further comprising contacting the modified biochar with water to adjust the pH of the modified biochar.

26. The method of claim 1, wherein the modified biochar has a pH of about 6.0-7.5.

27. The method of claim 26, wherein the modified biochar has a pH of about 6.5-7.0.

28. The method of claim 1, wherein contacting the biochar with at least a portion of the acid-containing solution comprises vacuum impregnation of the biochar with at least a portion of the acid-containing solution.

29. The method of claim 28, wherein vacuum impregnation of the biochar with at least a portion of the acid-containing solution comprises placing the biochar into one or more vacuum chambers, reducing the pressure in the chambers and introducing the acid-containing solution into the chambers.