Superhydrophobic and oleophobic coatings with low VOC binder systems
First Claim
Patent Images
1. A coating composition for the application of superhydrophobic and oleophobic coatings on surfaces comprising:
- a polyurethane dispersion (PUD) comprising one or more of a polyester urethane, a polyacrylic urethane and/or a polycarbonate urethane; and
about 5 to about 30% by weight of second particles comprising one or more siloxanes, and/or one or more alkyl, haloalkyl, fluoroalkyl, or perfluoroalkyl containing moieties;
said composition optionally comprising up to about 26% by weight of third particles;
wherein said coating composition comprises less than 0.3 pounds per gallon of volatile non-exempt organic compounds; and
wherein the superhydrophobic and oleophobic coating resulting from the application of said composition to a surface retains its superhydrophobicity after 150-1,400 Taber abrasion cycles at a 1000 g load for a coating thickness range of 25-300 microns, and/or 100-2,500 Taber abrasion cycles at a 250 g load, using a CS10 wheel, as judged by the inability of more than 50% of the water droplets applied to the area of the coating subjected to said abrasion cycles to remain on the surface when the planar surface is inclined at 3 degrees.
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Abstract
Coating compositions for the preparation of superhydrophobic (SH) and/or oleophobic (OP) surfaces that employ low amounts of volatile organic compounds are described. Also described are the resulting coatings/coated surfaces and methods of their preparation. Such coatings/surfaces have a variety of uses, including their ability to prevent or resist water, dirt and/or ice from attaching to a surface.
680 Citations
25 Claims
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1. A coating composition for the application of superhydrophobic and oleophobic coatings on surfaces comprising:
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a polyurethane dispersion (PUD) comprising one or more of a polyester urethane, a polyacrylic urethane and/or a polycarbonate urethane; and about 5 to about 30% by weight of second particles comprising one or more siloxanes, and/or one or more alkyl, haloalkyl, fluoroalkyl, or perfluoroalkyl containing moieties; said composition optionally comprising up to about 26% by weight of third particles; wherein said coating composition comprises less than 0.3 pounds per gallon of volatile non-exempt organic compounds; and wherein the superhydrophobic and oleophobic coating resulting from the application of said composition to a surface retains its superhydrophobicity after 150-1,400 Taber abrasion cycles at a 1000 g load for a coating thickness range of 25-300 microns, and/or 100-2,500 Taber abrasion cycles at a 250 g load, using a CS10 wheel, as judged by the inability of more than 50% of the water droplets applied to the area of the coating subjected to said abrasion cycles to remain on the surface when the planar surface is inclined at 3 degrees. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20)
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21. A coating composition for the application of superhydrophobic and oleophobic coatings on surfaces comprising:
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a water-based polyurethane dispersion (PUD) as a binder, the PUD comprising one or more of a polyester urethane, a polyacrylic urethane and/or a polycarbonate urethane; about 5 to about 30% by weight of second particles comprising one or more siloxanes, alkyl, fluoroalkyl, or perfluoroalkyl containing moieties; said composition optionally comprising up to about 26% by weight of third particles; wherein said coating composition optionally comprises less than 0.3 pounds per gallon of volatile non-exempt organic compounds and 30-40, 40-50 or 50-60 g of one or more compatible solvents per 100 g; and wherein the superhydrophobic and oleophobic coating resulting from the application of said composition to a surface retains its superhydrophobicity after 150-1,400 Taber abrasion cycles at a 1000 g load for a coating thickness range of 25-300 microns, and/or 100-2,500 Taber abrasion cycles at a 250 g load, using a CS10 wheel, as judged by the inability of more than 50% of the water droplets applied to the area of the coating subjected to said abrasion cycles to remain on the surface when the planar surface is inclined at 3 degrees. - View Dependent Claims (22, 23, 24)
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25. A coating composition for the application of superhydrophobic coatings on surfaces comprising:
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a polyurethane dispersion (PUD) comprising one or more of a polyester urethane, a polyacrylic urethane and/or a polycarbonate urethane; and about 5 to about 30% by weight of second particles comprising one or more siloxanes, and/or one or more alkyl, haloalkyl, fluoroalkyl, or perfluoroalkyl containing moieties; said composition optionally comprising up to about 26% by weight of third particles; wherein said coating composition comprises less than 0.3 pounds per gallon of volatile non-exempt organic compounds; and wherein the superhydrophobic coating resulting from the application of said composition to a surface retains its superhydrophobicity after 150-1,400 Taber abrasion cycles at a 1000 g load for a coating thickness range of 25-300 microns, and/or 100-2,500 Taber abrasion cycles at a 250 g load, using a CS10 wheel, as judged by the inability of more than 50% of the water droplets applied to the area of the coating subjected to said abrasion cycles to remain on the surface when the planar surface is inclined at 3 degrees.
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Specification