Pre-smoke detector and system for use in early detection of developing fires

• US 9,547,968 B2
• Filed: 10/17/2011
• Issued: 01/17/2017
• Est. Priority Date: 10/15/2010
• Status: Active Grant

• Current Assignee: Nevada Nanotech Systems, Inc.
• Original Assignee: Nevada Nanotech Systems, Inc.
• Inventors: Adams, Jesse D., Whitten, Ralph G.
• Primary Examiner(s): Barakat, Mohamed
• Application Number:
  US13/274,765
• Publication Number:
  US 20120092175A1
• Time in Patent Office: 1,919 Days
• US Class Current: 1/1
• CPC Class Codes: G01N 1/2214 by sorption
• CPC Class Codes: G01N 2291/0256 Adsorption, desorption, surface mass change, e.g. on biosensors
• CPC Class Codes: G01N 25/00 Investigating or analyzing materials by the use of thermal means G01N3/00 - G01N23/00 take precedence
• CPC Class Codes: G01N 25/4893 by using a differential method
• CPC Class Codes: G01N 29/022 Fluid sensors based on microsensors, e.g. quartz crystal-microbalance [QCM], surface acoustic wave [SAW] devices, tuning forks, cantilevers, flexural plate wave [FPW] devices microdevices per se B81B
• CPC Class Codes: G01N 33/0047 for organic compounds
• CPC Class Codes: G01N 5/02 by absorbing or adsorbing components of a material and determining change of weight of the adsorbent, e.g. determining moisture content absorption bulbs B01D53/00
• CPC Class Codes: G08B 17/10 Actuation by presence of smoke or gases , e.g. automatic alarm devices for analysing flowing fluid materials by the use of optical means
• CPC Class Codes: G08B 17/117 by using a detection device for specific gases, e.g. combustion products, produced by the fire G08B17/103, G08B17/11 take precedence

Abstract

A pre-smoke detector and system for use in early detection of developing fires whereby vapors of marker chemicals generated during the melting and/or smoldering of common household materials are detected before detection by conventional smoke detectors. Vapors resulting from heating and resultant vaporization of substances are detected as well as vapors resulting from their breakdown, decomposition, or pyrolysis during the pre-combustion stage. Conventional smoke detectors focus on particle detection and are most effective after a developing fire has produced smoke. To minimize false alarms caused by common household odors, the pre-smoke detectors focus on detecting medium temperature pyrolysis products using sensor coatings that can be consistent with a 10 year operational lifetime and multiple orthogonal detection processes. Since virtually all marker chemicals of interest for pre-smoke detection are heavier than air, a system is described that appropriately integrates with smoke detector alarm systems present in most homes.

Claims

1. A pre-smoke detector for early detection of a fire or potential fire, comprising:

a substrate including an array of microcantilevers, at least one microcantilever having a polymeric surface coating that adsorbs one or more of types of vaporized pyrolysis products resulting from thermal decomposition of fibers and/or wiring insulation materials, the vaporized pyrolysis products being of a different chemical composition than that of the pre-decomposed fibers and/or wiring insulation materials;

a cooling device that is configured to actively cool one or more microcantilevers below ambient temperature to promote adsorption of the vaporized pyrolysis products;

an electronic circuit including a controller that cooperates with the microcantilever and is configured to analyze the adsorbed vaporized pyrolysis products;

an alarm that is configured to activate if the analyzed adsorbed vaporized pyrolysis products meet or exceed a pre-determined threshold amount; and

a resistive heater that is configured to heat the microcantilever after analyzing the adsorbed vaporized pyrolysis products, thereby cleaning the polymeric surface coating of the microcantilever.

2. The pre-smoke detector of claim 1, wherein the cooling device is configured to actively cool one or more microcantilevers up to about 60°

C. below ambient temperature to promote adsorption of the vaporized pyrolysis products.

3. The pre-smoke detector of claim 1, wherein the pre-smoke detector does not detect smoke particles.

4. The pre-smoke detector of claim 1, wherein the electronic circuit is configured to perform differential thermal analysis on one or more types of adsorbed vaporized pyrolysis products.

5. The pre-smoke detector of claim 1, wherein the electronic circuit is configured to perform thermogravimetric analysis on one or more types of adsorbed vaporized pyrolysis products.

6. The pre-smoke detector of claim 1, wherein the resistive heater provides heat sensing functions.

7. The pre-smoke detector of claim 1, wherein at least another microcantilever has a metallic surface coating that adsorbs one or more types of vaporized pyrolysis products.

8. The pre-smoke detector of claim 7, wherein the metallic surface coating is gold, palladium, platinum, or molybdenum.

9. The pre-smoke detector of claim 1, wherein one or more microcantilevers include a piezoelectric material for both driving and sensing movement of the microcantilever.

10. The pre-smoke detector of claim 1, wherein the resistive heater is configured to heat the microcantilever after analyzing the adsorbed vaporized pyrolysis products to vaporize any remaining adsorbed vaporized pyrolysis products, thereby cleaning the polymeric surface coating of the microcantilever.

11. A system for early detection of a fire or potential fire, comprising:

a pre-smoke detector comprising;

a substrate including an array of microcantilevers, at least one microcantilever having a polymeric surface coating that adsorbs one or more of types of vaporized pyrolysis products resulting from thermal decomposition of fibers and/or wiring insulation materials, the vaporized pyrolysis products being of a different chemical composition than that of the pre-decomposed fibers and/or wiring insulation materials;

a cooling device that is configured to actively cool one or more microcantilevers below ambient temperature to promote adsorption of the vaporized pyrolysis products;

an electronic circuit including a controller that cooperates with the microcantilever and is configured to analyze the adsorbed vaporized pyrolysis products;

an alarm that is configured to activate if the analyzed vaporized pyrolysis products meet or exceed a pre-determined threshold amount, and wherein the pre-smoke detector does not detect smoke particles; and

a resistive heater that is configured to heat the microcantilever after analyzing the adsorbed vaporized pyrolysis products, thereby cleaning the polymeric surface coating of the microcantilever; and

a smoke detector that detects smoke particles and includes an alarm that is activated if smoke particles are detected and/or meet or exceed a pre-determined threshold amount,

wherein the pre-smoke detector and smoke detector are in communication with one another so that when one alarm is signaled the other is signaled.

12. The system of claim 11, wherein the pre-smoke detector is installed near a floor.

13. The system of claim 11, wherein the smoke detector is installed near a ceiling.

14. The system of claim 11, wherein the pre-smoke detector and smoke detector are in wireless communication with one another.

15. The system of claim 11, wherein the pre-smoke detector and smoke detector are in wired communication with one another.

16. The system of claim 11, wherein the cooling device is configured to actively cool one or more microcantilevers up to about 60°

C. below ambient temperature to promote adsorption of the vaporized pyrolysis products.

17. The system of claim 11, wherein the electronic circuit of the pre-smoke detector is configured to perform differential thermal analysis on one or more types of adsorbed vaporized pyrolysis products.

18. The system of claim 11, wherein the electronic circuit of the pre-smoke detector is configured to perform thermogravimetric analysis on one or more types of adsorbed vaporized pyrolysis products.

19. The system of claim 11, wherein the resistive heater provides temperature sensing functions.

20. The system of claim 11, wherein at least another microcantilever has a metallic surface coating that adsorbs one or more types of vaporized pyrolysis products.

21. The system of claim 20, wherein the metallic surface coating is gold, palladium, platinum, or molybdenum.

22. The system of claim 11, wherein one or more microcantilevers of the pre-smoke detector include a piezoelectric material for both driving and sensing movement of the microcantilever.

23. A method for early detection of a fire or potential fire, comprising:

adsorbing one or more of types of vaporized pyrolysis products on a polymeric surface coating of at least one microcantilever of an array of microcantilevers, the vaporized pyrolysis products resulting from thermal decomposition of fibers and/or wiring insulation materials and being of a different chemical composition than that of the pre-decomposed fibers and/or wiring insulation materials;

analyzing the adsorbed vaporized pyrolysis products;

activating an alarm if the analyzed vaporized pyrolysis products meet or exceed a pre-determined threshold amount; and

cleaning the polymeric surface coating of the microcantilever by heating the microcantilever after analyzing the adsorbed vaporized pyrolysis products,

wherein prior to analyzing the adsorbed vaporized pyrolysis products, actively cooling, via a cooling device, one or more microcantilevers below ambient temperature to promote adsorption of the vaporized pyrolysis products.

24. The method of claim 23, wherein actively cooling, via a cooling device, includes actively cooling, via the cooling device, one or more microcantilevers up to about 60°

C. below ambient temperature to promote adsorption of the vaporized pyrolysis products.

25. The method of claim 23, wherein analyzing the adsorbed vaporized pyrolysis products includes performing differential thermal analysis on one or more types of adsorbed vaporized pyrolysis products.

26. The method of claim 23, wherein analyzing the adsorbed vaporized pyrolysis products includes performing thermogravimetric analysis on one or more types of adsorbed vaporized pyrolysis products.

27. The method of claim 23, wherein at least another microcantilever has a metallic surface coating that adsorbs one or more types of vaporized pyrolysis products.

28. The method of claim 27, wherein the metallic surface is gold, palladium, platinum, or molybdenum.

29. The method of claim 23, wherein adsorbing one or more types of vaporized pyrolysis products on a polymeric surface coating of at least one microcantilever occurs near a floor.

30. A method for early detection of a fire or potential fire, comprising:

using a pre-smoke detector to detect one or more types of vaporized pyrolysis products resulting from thermal decomposition of fibers and/or wiring insulation materials, the pre-smoke detector comprising;

a substrate including an array of microcantilevers, at least one microcantilever having a polymeric surface coating that adsorbs one or more of types of vaporized pyrolysis products resulting from thermal decomposition of fibers and/or wiring insulation materials, the vaporized pyrolysis products being of a different chemical composition than that of the pre-decomposed fibers and/or wiring insulation materials;

a cooling device that is configured to actively cool one or more microcantilevers below ambient temperature to promote adsorption of the vaporized pyrolysis products;

an electronic circuit including a controller that cooperates with the microcantilever and is configured to analyze the adsorbed vaporized pyrolysis products;

an alarm that is configured to activate if the analyzed vaporized pyrolysis products meet or exceed a pre-determined threshold amount, and wherein the pre-smoke detector does not detect smoke particles; and

a resistive heater that is configured to heat the microcantilever after analyzing the adsorbed vaporized pyrolysis products, thereby cleaning the polymeric surface coating of the microcantilever.

31. The method of claim 30, wherein the cooling device is configured to actively cool one or more microcantilevers up to about 60°

C. below ambient temperature to promote adsorption of the vaporized pyrolysis products.