Method for degumming triglyceride oils

• US 9,556,399 B2
• Filed: 04/12/2016
• Issued: 01/31/2017
• Est. Priority Date: 05/06/2015
• Status: Active Grant

• Current Assignee: Archer Daniels Midland Company
• Original Assignee: Arisdyne Systems Incorporated
• Inventors: Kozyuk, Oleg, Reimers, Peter, Reinking, Paul A.
• Primary Examiner(s): Carr, Deborah D
• Application Number:
  US15/096,531
• Publication Number:
  US 20160326456A1
• Time in Patent Office: 294 Days
• Field of Search: 554/190
• US Class Current: 1/1
• CPC Class Codes: C11B 3/04 with acids
• CPC Class Codes: C11B 3/06 with bases
• CPC Class Codes: C11B 3/16 by mechanical means

Abstract

A multi-stage homogenization method for degumming triglyceride oil is used to increase oil yield and reduce impurities. Two high-pressure homogenizers are used in series. The homogenizers have multiple flow constrictions to finely disperse reagents in the oil while simultaneously suppressing cavitation in the fluid. A separation step can be used to remove the phosphatides and other impurities from the treated oil to form a purified oil product.

Claims

1. A method for degumming a triglyceride oil comprising:

a. mixing a base with an acid and oil mixture to form a pre-treated oil mixture comprising an oil phase and a water phase;

b. passing the pre-treated oil mixture at an inlet pressure through a first homogenization apparatus and a second homogenization apparatus to form a treated oil mixture, the first homogenization apparatus and the second homogenization apparatus being positioned in series with one another and the first homogenization apparatus and the second homogenization apparatus each comprising three flow constrictions in series, wherein the pressure drop in the pre-treated oil mixture across each flow constriction in the first homogenization apparatus and the second homogenization apparatus is maintained at a level such that hydrodynamic cavitation in the pre-treated oil mixture is suppressed in the first homogenization apparatus and the second homogenization apparatus;

c. separating the water phase from the oil phase to form a purified oil.

2. The method of claim 1, a flow constriction of the three flow constrictions in series in the first homogenization apparatus being adjustable.

3. The method of claim 1, the three flow constrictions in series in the first homogenization apparatus being adjustable.

4. The method of claim 2, the adjustable flow constriction in the three flow constrictions in series in the first homogenization apparatus being a valve.

5. The method of claim 4, the valve comprises an adjustable sharp edge element.

6. The method of claim 1, a flow constriction of the three flow constrictions in series in the second homogenization apparatus being adjustable.

7. The method of claim 1, the three flow constrictions in series in the second homogenization apparatus being adjustable.

8. The method of claim 6, the adjustable flow constriction in the three flow constrictions in series in the second homogenization apparatus being a valve.

9. The method of claim 8, the valve comprises an adjustable sharp edge element.

10. The method of claim 1, a flow constriction of the three flow constrictions in series in the first homogenization apparatus and the second homogenization apparatus being adjustable.

11. The method of claim 10, the three flow constrictions in series in the first homogenization apparatus and the second homogenization apparatus being adjustable.

12. The method of claim 1, the pressure drop in the pre-treated oil mixture across each flow constriction in the first homogenization apparatus and the second homogenization apparatus is in at least 25% of the upstream pressure of the pre-treated oil mixture before each flow constriction.

13. The method of claim 1, the pressure drop in the pre-treated oil across each flow constriction in the first homogenization apparatus being at least 100 psi.

14. The method of claim 13, the pressure drop in the pre-treated oil across each flow constriction in the second homogenization apparatus being at least 25 psi.

15. The method of claim 1, the pressure drop of the pre-treated oil mixture across the first homogenization apparatus being at least 60% of the inlet pressure to the first homogenization apparatus and the pre-treated oil mixture enters the second homogenization apparatus at a second inlet pressure, the pressure drop in the pre-treated oil mixture across the second homogenization apparatus being in the range of at least 60% of the second inlet pressure.

16. The method of claim 1, the inlet pressure of the pre-treated oil mixture to the first homogenization apparatus being at least 800 psi and the treated oil mixture exiting the second homogenization apparatus being at a pressure less than 10% of the inlet pressure.

17. A method for degumming a triglyceride oil comprising:

a. mixing a base with an acid and oil mixture to form a pre-treated oil mixture comprising an oil phase and a water phase, the oil in the acid and oil mixture being a crude vegetable oil, a water-degummed vegetable oil or a combination thereof;

b. passing the pre-treated oil mixture through a first homogenization apparatus and a second homogenization apparatus to form a treated oil mixture, the first homogenization apparatus and the second homogenization apparatus each comprising three flow constrictions in series, wherein the pressure drop in the pre-treated oil mixture across each flow constriction in the first homogenization apparatus and the second homogenization apparatus is maintained at a level such that hydrodynamic cavitation in the pre-treated oil mixture is suppressed in the first homogenization apparatus and the second homogenization apparatus;

c. separating the water phase from the oil phase to form a purified oil, wherein the purified oil has a phosphorus content of less than 10 ppm.

18. The method of claim 17, a flow constriction of the three flow constrictions in the first homogenization apparatus and the second homogenization apparatus being a valve.

20. The method of claim 18, the valve having a sharp edge element.

19. The method of clam 18, the valve being adjustable.