Electrochemical energy storage systems and methods featuring large negative half-cell potentials

• US 9,559,374 B2
• Filed: 07/24/2013
• Issued: 01/31/2017
• Est. Priority Date: 07/27/2012
• Status: Active Grant

• Current Assignee: Lockheed Martin Corporation (Martin Marietta Corporation)
• Original Assignee: Lockheed Martin Advanced Energy Storage, LLC (Martin Marietta Corporation)
• Inventors: Amadeo, Desiree, Tyagi, Nitin, Esswein, Arthur J., Reece, Steven Y., Goeltz, John, King, Evan R., Jarvi, Thomas D.
• Primary Examiner(s): Cantelmo, Gregg
• Application Number:
  US13/949,486
• Publication Number:
  US 20140028261A1
• Time in Patent Office: 1,287 Days
• US Class Current: 1/1
• CPC Class Codes: H01M 4/96 Carbon-based electrodes
• CPC Class Codes: H01M 8/04276 Arrangements for managing the electrolyte stream, e.g. heat exchange
• CPC Class Codes: H01M 8/188 by recharging of redox couples containing fluids; Redox flow type batteries
• CPC Class Codes: H01M 8/20 Indirect fuel cells, e.g. fuel cells with redox couple being irreversible H01M8/18 takes precedence
• CPC Class Codes: H02J 7/0068 Battery or charger load switching, e.g. concurrent charging and load supply H02J7/0013 takes precedence
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

The invention concerns flow batteries comprising: a first half-cell comprising: (i) a first aqueous electrolyte comprising a first redox active material; and a first carbon electrode in contact with the first aqueous electrolyte; (ii) a second half-cell comprising: a second aqueous electrolyte comprising a second redox active material; and a second carbon electrode in contact with the second aqueous electrolyte; and (iii) a separator disposed between the first half-cell and the second half-cell; the first half-cell having a half-cell potential equal to or more negative than about −0.3 V with respect to a reversible hydrogen electrode; and the first aqueous electrolyte having a pH in a range of from about 8 to about 13, wherein the flow battery is capable of operating or is operating at a current density at least about 25 mA/cm².

Claims

1. A flow battery comprising:

a first half-cell comprising;

a first aqueous electrolyte comprising a first redox active material, and a first carbon electrode in contact with said first aqueous electrolyte;

a second half-cell comprising;

a second aqueous electrolyte comprising a second redox active material, and a second carbon electrode in contact with said second aqueous electrolyte; and

a separator disposed between said first half-cell and said second half-cell;

wherein said first half-cell has a half-cell potential ranging between −

0.3 V and −

0.7 V with respect to a reversible hydrogen electrode, said first aqueous electrolyte has a pH ranging between 8 and 13, and the flow battery is capable of operating at a current density ranging between 25 mA/cm² and 500 mA/cm².

2. The flow battery of claim 1, wherein the redox active materials do not plate onto the carbon electrodes during operation of said flow battery.

3. The flow battery of claim 1, wherein at least one of said first redox active material and said second redox active material is an organic compound substantially devoid of metal.

4. The flow battery of claim 1, wherein at least one of said first redox active material and said second redox active material is a metal ligand coordination compound.

5. The flow battery of claim 1, wherein said separator comprises an ionomer.

6. The flow battery claim 1, wherein the flow battery has an energy density ranging between 30 watt hour/liter and 45 watt hour/liter.

7. The flow battery of claim 1, wherein said second half-cell has a potential ranging between +1.10 V and +2.0 V versus a reversible hydrogen electrode.

8. The flow battery of claim 1, wherein at least one of said first half-cell and said second half-cell exhibits substantially reversible electrochemical kinetics.

9. The flow battery of claim 1, wherein said first aqueous electrolyte has a pH ranging between 10 and 12.

10. The flow battery of claim 1, further comprising:

a second electrolyte tank in fluidic communication with the second half-cell and a first electrolyte tank in fluidic communication with the first half-cell.

11. The flow battery of claim 10, further comprising:

a pump capable of transporting a fluid between the second electrolyte tank and

the second half-cell, or between the first electrolyte tank and the first half-cell, or both.

12. A system comprising the flow battery of claim 1, and further comprising:

a first chamber containing the first aqueous electrolyte and a second chamber containing the second aqueous electrolyte;

at least one electrolyte circulation loop in fluidic communication with each chamber, said at least one electrolyte circulation loop comprising storage tanks and piping for containing and transporting the first and second aqueous electrolytes;

and

a power conditioning unit.

13. The system of claim 12, wherein the system is connected to an electrical grid configured to provide renewables integration, peak load shifting, grid firming, baseload power generation/consumption, energy arbitrage, transmission and distribution asset deferral, grid support, frequency regulation, or a combination thereof.

14. The system of claim 12, wherein the system is configured to provide stable power for remote camps, forward operating bases, off-grid telecommunications, or remote sensors.