Brine treatment scaling control system and method

• US 9,561,471 B2
• Filed: 05/13/2009
• Issued: 02/07/2017
• Est. Priority Date: 05/13/2009
• Status: Active Grant

• Current Assignee: Carollo Engineers Inc
• Original Assignee: Carollo Engineers Inc
• Inventors: Zacheis, G. Adam, Juby, Graham John Gibson
• Primary Examiner(s): Keyworth, Peter
• Application Number:
  US12/454,241
• Publication Number:
  US 20130206689A1
• Time in Patent Office: 2,827 Days
• US Class Current: 1/1
• CPC Class Codes: B01D 2311/08 Specific process operations in the concentrate stream
• CPC Class Codes: B01D 2311/12 Addition of chemical agents
• CPC Class Codes: B01D 2311/25 Recirculation, recycling or bypass, e.g. recirculation of concentrate into the feed
• CPC Class Codes: B01D 2311/252 Recirculation of concentrate
• CPC Class Codes: B01D 2311/2649 Filtration
• CPC Class Codes: B01D 2321/223 Polarity reversal
• CPC Class Codes: B01D 61/025 Reverse osmosis; Hyperfiltration
• CPC Class Codes: B01D 61/027 Nanofiltration
• CPC Class Codes: B01D 61/422 Electrodialysis
• CPC Class Codes: B01D 61/58 Multistep processes
• CPC Class Codes: B01D 65/08 Prevention of membrane fouling or of concentration polarisation
• CPC Class Codes: C02F 1/441 by reverse osmosis
• CPC Class Codes: C02F 1/442 by nanofiltration
• CPC Class Codes: C02F 1/4693 electrodialysis
• CPC Class Codes: C02F 2001/5218 Crystallization
• CPC Class Codes: C02F 2103/08 Seawater, e.g. for desalination
• CPC Class Codes: C02F 2201/4613 Inversing polarity
• CPC Class Codes: C02F 2301/046 Recirculation with an external loop
• CPC Class Codes: C02F 2303/20 Prevention of biofouling
• CPC Class Codes: C02F 2303/22 Eliminating or preventing deposits, scale removal, scale prevention C02F1/042, C02F1/4602, C02F5/00 take precedence

Abstract

The present invention may be used in systems and methods for brine treatment scaling control in a water treatment system. A concentrated brine stream influent may be treated in an electrodialysis-reversal process to produce a concentrated brine stream effluent and a lower salinity diluent water, which may be potable water effluent. The concentrated brine stream effluent may be processed in a brine treatment scaling control system that may have a mixing vessel and a membrane filter with the mixing vessel seeded with calcium sulfate. A lowered salinity brine stream effluent may be produced for return to the electrodialysis-reversal process to allow operation at greater overall recovery and an elevated concentrated brine stream may be produced.

Claims

1. A method for treating a brine stream comprising:

treating a brine stream influent in an electrodialysis-reversal process to produce a concentrated brine stream effluent and a lower salinity diluent stream effluent;

processing said concentrated brine stream effluent in a brine treatment scaling control system that has a mixing vessel and a membrane filter with said mixing vessel seeded with calcium sulfate, wherein said processing produces a lowered salinity brine stream effluent and an elevated concentrated brine stream effluent; and

returning said lowered salinity brine stream effluent to a brine loop of said electrodialysis-reversal process wherein said electrodialysis-reversal process has two process flow inputs with a first input of said two process flow inputs connected to a demineralization portion of a membrane stack and a second input of said two process flow inputs connected to a concentrating portion of the membrane stack, wherein said brine loop is connected to said second input.

2. The method as in claim 1 wherein:

said concentrated brine stream effluent is filtered in said membrane filter to output said lowered salinity brine stream effluent and said elevated concentrated brine stream effluent; and

said elevated concentrated brine stream effluent is mixed in said mixing vessel to produce a mixture that is returned to said membrane filter for further processing.

3. The method as in claim 2 wherein a portion of said mixture is removed at intervals necessary to maintain the material balance in said brine treatment scaling control system.

4. The method as in claim 1 wherein:

said concentrated brine stream effluent is routed to said mixing vessel to produce a mixture that is routed to said membrane filter to produce said lowered salinity brine stream effluent and said elevated concentrated brine stream effluent wherein said elevated concentrated brine stream effluent is returned to said mixing vessel.

5. The method as in claim 4 wherein a portion of said elevated concentrated brine stream effluent is removed at intervals necessary to maintain the materials balance in said brine treatment scaling control system.

6. The method as in claim 1 wherein the calcium sulfate is a gypsum crystal form of material.

7. The method as in claim 1 wherein said membrane filter is selected from the group consisting of a nanofiltration form and a reverse osmosis form.

8. The method as in claim 1 wherein said membrane filter is selected from the group consisting of a nanofiltration filter, a reverse osmosis type filter, a tubular filter, a flat sheet filter, and a spiral configuration filter.

9. The method as in claim 2 wherein a portion of said mixture is output to the environment.