Composite gas sampling system

• US 9,562,833 B2
• Filed: 03/12/2014
• Issued: 02/07/2017
• Est. Priority Date: 03/15/2013
• Status: Active Grant

• Current Assignee: Mustang Sampling, LLC
• Original Assignee: Mustang Sampling, LLC
• Inventors: Querrey, Timothy Layne, Thompson, Kenneth O., Rolston, Claude A.
• Primary Examiner(s): Huls, Natalie
• Application Number:
  US14/205,526
• Publication Number:
  US 20140311213A1
• Time in Patent Office: 1,063 Days
• US Class Current: 1/1
• CPC Class Codes: G01N 1/18 with provision for splitting samples into portions G01N1/12, G01N1/14 take precedence; fraction-collection apparatus for chromatography B01D15/08
• CPC Class Codes: G01N 1/2247 Sampling from a flowing stream of gas
• CPC Class Codes: G01N 1/26 with provision for intake from several spaces
• CPC Class Codes: G01N 2001/105 from high-pressure reactors or lines
• CPC Class Codes: G01N 2001/1093 Composite sampling; Cumulative sampling
• CPC Class Codes: G01N 2001/2071 Removable sample bottle
• CPC Class Codes: G01N 2001/2261 preventing condensation (heating lines)
• CPC Class Codes: G01N 2001/2267 separating gas from liquid, e.g. bubbles
• CPC Class Codes: G01N 2030/025 Gas chromatography
• CPC Class Codes: G01N 2030/8854 involving hydrocarbons
• CPC Class Codes: G01N 2030/8886 Analysis of industrial production processes
• CPC Class Codes: G01N 30/88 Integrated analysis systems specially adapted therefor, not covered by a single one of the groups G01N30/04 - G01N30/86
• CPC Class Codes: G01N 33/0014 by eliminating a gas G01N33/0013 and G01N33/0024 take precedence
• CPC Class Codes: G01N 33/0016 by regulating a physical variable, e.g. pressure, temperature
• CPC Class Codes: G01N 33/0047 for organic compounds
• CPC Class Codes: G01N 33/0073 Control unit therefor

Abstract

A sampling system for collecting periodic composite and/or non-composite samples of vaporized gas during a transfer process from a vaporizer of a cryogenic hydrocarbon liquid including 1) a direct sample pathway to a gas analyzer for instantaneous, real-time vaporized gas analysis, 2) a speed loop pathway for directly collecting fresh vaporized gas samples for subsequent analysis, and 3) a composite sample pathway including a pressurized sample accumulator for collecting a plurality periodically obtained samples of a select volume during the transfer process to create a composite sample of the vaporized gas.

Claims

1. An apparatus for capturing a periodic gas sample following vaporizing and conditioning into a gas phase of a cryogenic liquid hydrocarbon source during transfer processing, comprising:

at least a first and a second vaporized sample input lines each incorporating at least a first direct feed line, a second speed loop line, and a third accumulator feed line;

each of the first direct feed lines of the first and second vaporized sample input lines being directly connected to a gas analyzer for on-line, real-time, periodic analysis of a non-composite gas sample;

each of the speed loop lines being connected to a speed loop having a pressure regulator, at least one high pressure pump, a plurality of solenoid controlled valves for controlled filling of a plurality of non-composite sample cylinders for storage of fresh gas samples obtained at specified processing intervals, and a by-pass outlet to a boil-off-gas system;

each of the accumulator lines including at least one solenoid controlled valve, said accumulator line for passing a gas sample of a select volume at select time intervals to a pressure regulator, a solenoid controlled valve, and a gas accumulator for receiving multiple periodic select volume gas samples to create a composite gas sample, and a valve controlled outlet from the gas accumulator, where said at least one high pressure pump maintains pressure sufficient in the gas accumulator to prevent dew point drop-out of the gas sample, and

a plurality of sample grab cylinders for receiving composite samples from the gas accumulator upon completion of source processing.

2. The apparatus of claim 1 further comprising a control unit for controlling the solenoid valves, flow operations, speed loop fresh non-composite sample collection timing, and accumulator composite gas sample retention.

3. The apparatus of claim 2 further comprising a housing cabinet including a heater and over pressure vent.

4. The apparatus of claim 3 further comprising a separate analyzer cabinet connected to or within said housing cabinet defining a housing cabinet for housing at least one gas analyzer.

5. The apparatus of claim 4 where, said analyzer is a gas chromatograph, and further includes a heater in the analyzer cabinet and a calibration gas station.

6. The apparatus of claim 1 comprising a third vaporized gas sample input line and a second, duplicate accumulator line connected to a said gas accumulator for simultaneous sampling from multiple inputs from the source.

7. The apparatus of claim 6 comprising a residual gas removal system following completion of processing sampling operations.

8. The apparatus of claim 7 where the residual gas removal system is a gas purge system and where the Boil-off-gas system comprises a boil-off gas header.

9. The apparatus of claim 7 where the residual gas removal system includes an evacuation method.

10. The apparatus of claim 1 further comprising at least one flow controller disposed in said speed loop line and a second flow controller disposed in said accumulator line for diverting the gas sample to said speed loop line, and where said at least one high pressure pump comprises a first and a second high pressure pump, said second high pressure pump being disposed in said accumulator lines.

11. The apparatus of claim 10 further comprising at least a first second and third check valves to prevent backflow respectively between said second high pressure pump and gas accumulator, said accumulator line and said speed loop line, and said sample grab cylinders and said boil-off gas system.

12. The apparatus of claim 11 further comprising a control unit for controlling the solenoid valves, flow operations, and sample introduction into said accumulator.

13. The apparatus of claim 12 where there are three non-composite sample cylinders for storage of fresh non-composite samples obtained at ⅓

, ½ and

⅔

of the elapsed processing intervals.

14. The apparatus of claim 13 where there are four removable, receiving composite sample grab cylinders.