System and method for temperature control in an oxygen transport membrane based reactor
First Claim
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1. A method for temperature control in a multi-stage reactively driven oxygen transport membrane based reactor comprising the steps of:
- introducing a flow of a heated oxygen containing feed stream to the multi-stage reactively driven oxygen transport membrane based reactor, the heated oxygen containing feed stream having a temperature from about 800°
C. to about 1000°
C.;
passing the heated oxygen containing feed stream across the surfaces of a plurality of oxygen transport membrane elements in a first stage of the multi-stage reactively driven oxygen transport membrane based reactor wherein the some oxygen is depleted from the heated oxygen containing feed stream to produce a first residual stream at a temperature at or above the heated oxygen containing feed stream temperature;
passing the first residual stream through a first refractory air diffusion screen disposed proximate a distal end of the first stage of the multi-stage reactively driven oxygen transport membrane based reactor and configured to maintain an operating temperature in the first stage of the multi-stage reactively driven oxygen transport membrane based reactor and allow the first residual stream to pass therethrough;
passing the first residual stream across the surfaces of a second plurality of oxygen transport membrane elements in a second stage of the multi-stage reactively driven oxygen transport membrane based reactor wherein the some oxygen is further depleted from the first residual stream to produce a second residual stream;
passing the second residual stream through a second refractory air diffusion screen disposed proximate a distal end of the second stage of the multi-stage reactively driven oxygen transport membrane based reactor and configured to maintain an operating temperature in the second stage of the multi-stage reactively driven oxygen transport membrane based reactor and allow the second residual stream to pass therethrough; and
exhausting a stream containing some or all of the second residual stream from the multi-stage reactively driven oxygen transport membrane based reactor;
wherein the operating temperature in the first stage and the operating temperature in the second stage are within about 25°
C. of each other.
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Abstract
A system and method for temperature control in an oxygen transport membrane based reactor is provided. The system and method involves introducing a specific quantity of cooling air or trim air in between stages in a multistage oxygen transport membrane based reactor or furnace to maintain generally consistent surface temperatures of the oxygen transport membrane elements and associated reactors. The associated reactors may include reforming reactors, boilers or process gas heaters.
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Citations
17 Claims
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1. A method for temperature control in a multi-stage reactively driven oxygen transport membrane based reactor comprising the steps of:
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introducing a flow of a heated oxygen containing feed stream to the multi-stage reactively driven oxygen transport membrane based reactor, the heated oxygen containing feed stream having a temperature from about 800°
C. to about 1000°
C.;passing the heated oxygen containing feed stream across the surfaces of a plurality of oxygen transport membrane elements in a first stage of the multi-stage reactively driven oxygen transport membrane based reactor wherein the some oxygen is depleted from the heated oxygen containing feed stream to produce a first residual stream at a temperature at or above the heated oxygen containing feed stream temperature; passing the first residual stream through a first refractory air diffusion screen disposed proximate a distal end of the first stage of the multi-stage reactively driven oxygen transport membrane based reactor and configured to maintain an operating temperature in the first stage of the multi-stage reactively driven oxygen transport membrane based reactor and allow the first residual stream to pass therethrough; passing the first residual stream across the surfaces of a second plurality of oxygen transport membrane elements in a second stage of the multi-stage reactively driven oxygen transport membrane based reactor wherein the some oxygen is further depleted from the first residual stream to produce a second residual stream; passing the second residual stream through a second refractory air diffusion screen disposed proximate a distal end of the second stage of the multi-stage reactively driven oxygen transport membrane based reactor and configured to maintain an operating temperature in the second stage of the multi-stage reactively driven oxygen transport membrane based reactor and allow the second residual stream to pass therethrough; and exhausting a stream containing some or all of the second residual stream from the multi-stage reactively driven oxygen transport membrane based reactor; wherein the operating temperature in the first stage and the operating temperature in the second stage are within about 25°
C. of each other. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8)
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9. A method for temperature control in a multi-stage reactively driven oxygen transport membrane based reactor comprising the steps of:
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introducing a flow of a heated oxygen containing feed stream to the multi-stage reactively driven oxygen transport membrane based reactor, the heated oxygen containing feed stream having a temperature from about 800°
C. to about 1000°
C.;passing the heated oxygen containing feed stream across the surfaces of a plurality of oxygen transport membrane elements in a first stage of the multi-stage reactively driven oxygen transport membrane based reactor wherein the some oxygen is depleted from the heated oxygen containing feed stream to produce a first residual stream at a temperature at or above the heated oxygen containing feed stream temperature; passing the first residual stream through a first refractory air diffusion screen disposed proximate a distal end of the first stage of the multi-stage reactively driven oxygen transport membrane based reactor and configured to maintain an operating temperature in the first stage of the multi-stage reactively driven oxygen transport membrane based reactor and allow the first residual stream to pass therethrough; introducing a flow of supplemental cooling air to the first residual stream at a location downstream of the first refractory air diffusion screen within the multi-stage oxygen transport membrane based reactor mixing the flow of supplemental cooling air with the first residual stream to produce a mixed stream having a mixed stream temperature; passing the mixed stream across the surfaces of a second plurality of oxygen transport membrane elements in a second stage of the multi-stage reactively driven oxygen transport membrane based reactor wherein the some oxygen is depleted from the mixed stream to produce a second residual stream at a temperature above the mixed stream temperature; passing the second residual stream through a second refractory air diffusion screen disposed proximate a distal end of the second stage of the multi-stage reactively driven oxygen transport membrane based reactor and configured to maintain an operating temperature in the second stage of the multi-stage reactively driven oxygen transport membrane based reactor and allow the second residual stream to pass therethrough; and exhausting a stream containing some or all of the second residual stream from the multi-stage reactively driven oxygen transport membrane based reactor; wherein the operating temperature in the first stage and the operating temperature in the second stage are within about 25°
C. of each other. - View Dependent Claims (10, 11, 12, 13, 14, 15, 16, 17)
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Specification