Bisphenol A preparation apparatus and preparation method

• US 9,573,869 B2
• Filed: 07/11/2014
• Issued: 02/21/2017
• Est. Priority Date: 07/11/2013
• Status: Active Grant

• Current Assignee: LG Chem Limited (LG Corporation)
• Original Assignee: LG Chem Limited (LG Corporation)
• Inventors: Park, Jong Suh, Shin, Joon Ho, Kim, Tae Woo, Lee, Jong Ku, Park, Se Ho
• Primary Examiner(s): WITHERSPOON, SIKARL A
• Application Number:
  US14/904,028
• Publication Number:
  US 20160159716A1
• Time in Patent Office: 956 Days
• Field of Search: 568/724, 422/187
• US Class Current: 1/1
• CPC Class Codes: B01J 19/24 Stationary reactors without moving elements inside B01J19/08, B01J19/26 take precedence; with stationary particles B01J8/02
• CPC Class Codes: B01J 2219/00103 in a heat exchanger separate from the reactor
• CPC Class Codes: B01J 2219/24 Stationary reactors without moving elements inside
• CPC Class Codes: C07B 63/00 Purification; Separation separation of optically-active compounds C07B57/00; Stabilisation; Use of additives
• CPC Class Codes: C07C 37/20 using aldehydes or ketones
• CPC Class Codes: C07C 37/685 Processes comprising at least two steps in series
• CPC Class Codes: C07C 37/74 by distillation
• CPC Class Codes: C07C 37/76 by steam distillation
• CPC Class Codes: C07C 37/82 by solid-liquid treatment; by chemisorption
• CPC Class Codes: C07C 37/84 by crystallisation
• CPC Class Codes: C07C 39/16 Bis-(hydroxyphenyl) alkanes; Tris-(hydroxyphenyl)alkanes

Abstract

Provided are an apparatus and a method for preparing bisphenol A. In the present invention, all or some of a mother liquid stream is circulated to a flash rector through a bypass line after crystallization in a process of preparing bisphenol A so as to increase a conversion rate of bisphenol A in a reactor, reduce energy, and use a heating source of phenol to be discharged to an upper side of the flash reactor, and thus the reaction efficiency of the whole process can be increased.

Claims

1. A bisphenol A preparing apparatus comprising:

a main reactor that discharges a reaction product of a reaction between phenol and acetone through a reaction product stream;

a flash reactor that separates the reaction product stream into a bisphenol A concentration stream and a phenol concentration stream;

a bisphenol A purification unit that separates the bisphenol A concentration stream into a bisphenol A purification stream and a mother liquid stream and discharges the separated mother liquid stream;

a recovery reactor that discharges a recovered reaction product, which is obtained by additionally reacting the mother liquid stream separated in the bisphenol A purification unit, to the main reactor through a recovered reaction product stream; and

a bypass line that is positioned between the recovery reactor and the main reactor and that introduces at least some of the separated mother liquid stream into the flash reactor.

2. The bisphenol A preparing apparatus of claim 1, further comprising:

a heating source that supplies heat to the flash reactor.

3. The bisphenol A preparing apparatus of claim 1, further comprising:

a dehydrator that is positioned between the main reactor and the flash reactor and separates the reaction product stream into a reactor reflux stream and a bisphenol A production stream.

4. The bisphenol A preparing apparatus of claim 1, wherein the bisphenol A purification unit comprises:

a crystallizer that crystallizes adduct of bisphenol A and phenol in the bisphenol A concentration stream; and

a solid-liquid separator that separates the crystallized adduct of bisphenol A and phenol from a mother liquid.

5. The bisphenol A preparing apparatus of claim 4, wherein the bisphenol A purification unit comprises:

a first crystallizer that crystallizes adduct of bisphenol A and phenol in the bisphenol A concentration stream;

a first solid-liquid separator that separates the crystallized adduct of bisphenol A and phenol to be discharged from the first crystallizer from the mother liquid;

a second crystallizer that recrystallizes the crystallized adduct of bisphenol A and phenol separated in the first solid-liquid separator; and

a second solid-liquid separator that separates the crystallized adduct of bisphenol A and phenol to be discharged from the second crystallizer from the mother liquid.

6. The bisphenol A preparing apparatus of claim 1, further comprising:

a bisphenol A purification device that melts crystallized adduct of bisphenol A and phenol present in the bisphenol A purification stream to be discharged from the bisphenol A purification unit to separate bisphenol A and phenol.

7. The bisphenol A preparing apparatus of claim 1, further comprising:

a mother liquid purification device that removes pentane from the mother liquid stream separated in the bisphenol A purification unit.

8. The bisphenol A preparing apparatus of claim 5, further comprising:

a first heat exchanger that exchanges heat between the phenol concentration stream separated in the flash reactor and the bisphenol A purification stream separated in the solid-liquid separator to melt the crystallized adduct of bisphenol A and phenol.

9. The bisphenol A preparing apparatus of claim 5, further comprising:

a first heat exchanger that exchanges heat between the phenol concentration stream separated in the flash reactor and the bisphenol A purification stream separated in the second solid-liquid separator to melt the crystallized adduct of bisphenol A and phenol; and

a second heat exchanger that exchanges heat between the phenol concentration stream separated in the flash reactor and the bisphenol A purification stream separated in the first solid-liquid separator to melt the crystallized adduct of bisphenol A and phenol.

10. A bisphenol A preparing method comprising:

a step of reacting phenol with acetone in a main reactor and discharging a reaction product through a reaction product stream;

a step of separating the reaction product stream into a bisphenol A concentration stream and a phenol concentration stream in a flash reactor;

a step of separating the bisphenol A concentration stream into a bisphenol A purification stream and a mother liquid stream in a bisphenol A purification unit and discharging the separated mother liquid stream;

a step of additionally reacting the separated mother liquid stream through a recovery reactor after the mother liquid stream separated in the bisphenol A purification unit, and discharging the separated mother liquid stream to the main reactor through a recovered reaction product stream; and

a step of introducing at least some of the separated mother liquid stream from the recovered reaction product stream into the flash reactor through a bypass line.

11. The bisphenol A preparing method of claim 10, further comprising:

a step of supplying heat to the flash reactor through a heating source.

12. The bisphenol A preparing method of claim 10, further comprising:

a step of separating the reaction product stream into a reactor reflux stream and a bisphenol A production stream through a dehydrator positioned between the main reactor and the flash reactor.

13. The bisphenol A preparing method of claim 10, wherein the step of separating the bisphenol A concentration stream into a bisphenol A purification stream and a mother liquid stream in a bisphenol A purification unit comprises:

a step of crystallizing adduct of bisphenol A and phenol in the bisphenol A concentration stream through a crystallizer; and

a step of separating the crystallized adduct of bisphenol A and phenol from a mother liquid through a solid-liquid separator.

14. The bisphenol A preparing method of claim 13, wherein the step of separating the bisphenol A concentration stream into a bisphenol A purification stream and a mother liquid stream in a bisphenol A purification unit comprises:

a step of crystallizing adduct of bisphenol A and phenol in the bisphenol A concentration stream through a first crystallizer;

a step of separating the crystallized adduct of bisphenol A and phenol to be discharged from the first crystallizer from a mother liquid through a first solid-liquid separator;

a step of recrystallizing the crystallized adduct of bisphenol A and phenol separated in the first solid-liquid separator through a second crystallizer; and

a step of separating the crystallized adduct of bisphenol A and phenol to be discharged from the second crystallizer from the mother liquid through the second solid-liquid separator.

15. The bisphenol A preparing method of claim 10, further comprising:

a step of melting crystallized adduct of bisphenol A and phenol present in the bisphenol A purification stream to be discharged from the bisphenol A purification unit to separate bisphenol A and phenol.

16. The bisphenol A preparing method of claim 13, further comprising:

a step of exchanging heat between the phenol concentration stream separated in the flash reactor and the bisphenol A purification stream separated in the solid-liquid separator through a first heat exchanger to melt the crystallized adduct of bisphenol A and phenol.

17. The bisphenol A preparing method of claim 14, further comprising:

a step of exchanging heat between the phenol concentration stream separated in the flash reactor and the bisphenol A purification stream separated in the second solid-liquid separator through a first heat exchanger to melt the crystallized adduct of bisphenol A and phenol; and

a step of exchanging heat between the phenol concentration stream separated in the flash reactor and the bisphenol A purification stream separated in the first solid-liquid separator through a second heat exchanger to melt the crystallized adduct of bisphenol A and phenol.

18. The bisphenol A preparing method of claim 10, wherein the step of introducing the separated mother liquid stream into the flash reactor through a bypass line comprises introducing the separated mother liquid stream of 10% to 100% by weight into the flash reactor.