Silicone resin reflective substrate, manufacturing method for same, and base material composition used in reflective substrate

• US 9,574,050 B2
• Filed: 12/24/2010
• Issued: 02/21/2017
• Est. Priority Date: 03/23/2010
• Status: Active Grant

• Current Assignee: Asahi Rubber Inc.
• Original Assignee: Asahi Rubber Inc.
• Inventors: Tasaki, Masutsugu, Igarashi, Naoto, Ichikawa, Akira, Odaki, Tsutomu, Yoshida, Maimi
• Primary Examiner(s): Van Sell, Nathan
• Application Number:
  US13/636,963
• Publication Number:
  US 20130011617A1
• Time in Patent Office: 2,251 Days
• Field of Search: 428/141, 428/148, 428/328, 428/339
• US Class Current: 1/1
• CPC Class Codes: B29C 2793/0027 Cutting off
• CPC Class Codes: B29C 45/14 incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles B29C45/1671 takes precedence
• CPC Class Codes: B29C 48/002 combined with surface shaping
• CPC Class Codes: B29C 48/0022 combined with cutting
• CPC Class Codes: B29C 48/07 Flat, e.g. panels
• CPC Class Codes: B29C 48/08 flexible, e.g. films
• CPC Class Codes: B29C 48/13 Articles with a cross-section varying in the longitudinal direction, e.g. corrugated pipes
• CPC Class Codes: B29C 48/154 Coating solid articles, i.e. non-hollow articles
• CPC Class Codes: B29C 48/155 Partial coating thereof
• CPC Class Codes: B29C 48/16 Articles comprising two or more components, e.g. co-extruded layers
• CPC Class Codes: B29C 59/04 using rollers or endless belts
• CPC Class Codes: B29D 11/0074 Production of other optical elements not provided for in B29D11/00009- B29D11/0073
• CPC Class Codes: B29K 2083/00 Use of polymers having silicon, with or without sulfur, nitrogen, oxygen, or carbon only, in the main chain, as moulding material
• CPC Class Codes: B29K 2105/20 Inserts
• CPC Class Codes: B29K 2705/10 Copper
• CPC Class Codes: B29K 2995/003 Reflective
• CPC Class Codes: B29L 2007/002 Panels; Plates; Sheets
• CPC Class Codes: B29L 2009/005 coated
• CPC Class Codes: C08G 77/04 Polysiloxanes
• CPC Class Codes: C08K 2003/2241 Titanium dioxide
• CPC Class Codes: C08K 3/22 : of metals
• CPC Class Codes: C08K 9/02 : Ingredients treated with inorganic substances
• CPC Class Codes: C08K 9/06 : with silicon-containing compounds
• CPC Class Codes: C08L 83/04 : Polysiloxanes
• CPC Class Codes: C09C 1/3684 : Treatment with organo-silicon compounds
• CPC Class Codes: C09C 3/12 : Treatment with organosilicon compounds C09C3/006 takes precedence
• CPC Class Codes: C09D 183/04 : Polysiloxanes
• CPC Class Codes: C09D 5/004 : Reflecting paints; Signal paints
• CPC Class Codes: C09D 7/62 : modified by treatment with other compounds
• CPC Class Codes: H01L 2224/13 : of an individual bump connector
• CPC Class Codes: H01L 2224/45144 : Gold (Au) as principal constituent
• CPC Class Codes: H01L 2224/48091 : Arched
• CPC Class Codes: H01L 2924/00 : Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
• CPC Class Codes: H01L 2924/00014 : the subject-matter covered by the group, the symbol of which is combined with the symbol of this group, being disclosed without further technical details
• CPC Class Codes: H01L 31/02008 : for solar cells or solar cell modules
• CPC Class Codes: H01L 31/022425 : for solar cells
• CPC Class Codes: H01L 31/035281 : Shape of the body
• CPC Class Codes: H01L 31/03529 : Shape of the potential jump barrier or surface barrier
• CPC Class Codes: H01L 31/048 : Encapsulation of modules
• CPC Class Codes: H01L 31/0481 : characterised by the composition of the encapsulation material
• CPC Class Codes: H01L 31/0547 : comprising light concentrating means of the reflecting type, e.g. parabolic mirrors, concentrators using total internal reflection
• CPC Class Codes: H01L 31/068 : the potential barriers being only of the PN homojunction type, e.g. bulk silicon PN homojunction solar cells or thin film polycrystalline silicon PN homojunction solar cells
• CPC Class Codes: H01L 31/0682 : back-junction, i.e. rearside emitter, solar cells, e.g. interdigitated base-emitter regions back-junction cells
• CPC Class Codes: H01L 33/56 : Materials, e.g. epoxy or silicone resin
• CPC Class Codes: H01L 33/60 : Reflective elements
• CPC Class Codes: H01L 33/62 : Arrangements for conducting electric current to or from the semiconductor body, e.g. lead-frames, wire-bonds or solder balls
• CPC Class Codes: Y02E 10/52 : PV systems with concentrators
• CPC Class Codes: Y02E 10/547 : Monocrystalline silicon PV cells
• CPC Class Codes: Y10T 428/24355 : Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
• CPC Class Codes: Y10T 428/24413 : Metal or metal compound
• CPC Class Codes: Y10T 428/24612 : Composite web or sheet
• CPC Class Codes: Y10T 428/256 : Heavy metal or aluminum or compound thereof
• CPC Class Codes: Y10T 428/269 : including synthetic resin or polymer layer or component
• CPC Class Codes: Y10T 428/31663 : As siloxane, silicone or silane

Abstract

A versatile silicone resin reflective substrate which exhibits high reflectance of high luminance light from an LED light source over a wide wavelength from short wavelengths of approximately 340-500 nm, which include wavelengths from 380-400 nm near lower limit of the visible region, to longer wavelength in the infra-red region. The silicone resin reflective substrate has a reflective layer which contains a white inorganic filler powder dispersed in a three-dimensional cross linked silicone resin, the inorganic filler powder having a high reflective index than the silicone resin. The reflective layer is formed on a support body as a film, a solid, or a sheet. The silicone resin reflective substrate can be easily formed as a wiring substrate, a packaging case or the like, and can be manufactured at low cost and a high rate of production.

Claims

1. A silicone resin reflective substrate comprising:

a reflective layer containing

a white inorganic filler powder including titanium oxide surface-treated with Al, Al₂O₃, ZnO, ZrO₂, SiO₂ and/or silane coupling agent dispersed in a three-dimensionally cross-linked silicone resin,

the reflective layer being made from a liquid-like base material composition, or a grease-like, a plastic-like or a millable-type base material composition having a plasticity to be cured for the reflective layer so that the white inorganic filler powder is incorporated into a 3-dimensionally cross-linked silicone resin, containing;

a polymerizable silicone resin,

the white inorganic filler powder including titanium oxide surface-treated with Al, Al₂O₃, ZnO, ZrO₂, SiO₂ and/or silane coupling agent, which has a higher refractive index than that of the three-dimensionally cross-linked silicone resin and is dispersed in the base material composition,

an adhesive component of a silane compound or siloxane compound having a reactive functional group, and

a reaction inhibitor;

the reflective layer being bonded to a support body as a film-like shape, 3-dimensional-like shape or plate-like shape; and

the silicone resin reflective substrate maintaining reflectance of a level of 85% or more at a region of 450 to 1000 nm and a level of 90% or more at a region of 450 nm by the reflective layer.

2. The silicone resin reflective substrate according to claim 1, wherein the silicone resin contains a non-cyclic dimethylsiloxy repeating unit as a main component.

3. The silicone resin reflective substrate according to claim 1, wherein an amount of a polysiloxane having 4-10 siloxy group repeating units in the silicone resin is 300 ppm at a maximum.

4. The silicone resin reflective substrate according to claim 1, wherein the reflective layer is formed to have a thickness of 1-2,000 μ

m.

5. The silicone resin reflective substrate according to claim 1, wherein a refractive index of the silicone resin is not less than 1.35 and less than 1.65.

6. The silicone resin reflective substrate according to claim 1, wherein the white inorganic filler powder further includes at least one of a light reflective agent selected from the group consisting of alumina, barium sulfate, magnesia, aluminum nitride, boron nitride, barium titanate, kaolin, talc, calcium carbonate, zinc oxide, silica, mica powder, glass powder, nickel powder, and aluminum powder.

7. The silicone resin reflective substrate according to claim 6, wherein the white inorganic filler powder is subjected to a silane-coupling treatment and dispersed in the silicone resin.

8. The silicone resin reflective substrate according to claim 1, wherein the white inorganic filler powder is an anatase-type titanium oxide or a rutile-type titanium oxide.

9. The silicone resin reflective substrate according to claim 8, wherein said titanium oxide is surface-treated and covered with Al, Al₂O₃, ZnO, ZrO₂, and/or SiO₂.

10. The silicone resin reflective substrate according to claim 1, wherein the white inorganic filler powder has an average particle size of 0.05-50 μ

m and is contained in the silicone resin in the ratio of 2 to 80% by mass.

11. The silicone resin reflective substrate according to claim 1, wherein the white inorganic filler powder and a fluorescent substance are dispersed and contained in the reflective layer.

12. The silicone resin reflective substrate according to claim 11, wherein at least one of the white inorganic filler powder and the fluorescent substance is exposed to the air on a surface of the reflective layer.

13. The silicone resin reflective substrate according to claim 1, wherein the surface of the reflective layer is made into a continuous non-specular surface of a nanometer-micrometer size concavo-convex shape, prism shape and/or pearskin shape.

14. The silicone resin reflective substrate according to claim 1, wherein a part of the white inorganic filler powder is exposed to the air on the surface of the silicone resin by treating at least a part of the surface of the silicone resin reflective substrate using polishing, roughening, die molding or stamp molding with using scabrous die, and/or chemical etching.

15. The silicone resin reflective substrate according to claim 1, wherein the reflective layer which covers the support body to which a conductive pattern is attached, is polished, so that the conductive pattern is exposed to the air.

16. The silicone resin reflective substrate according to claim 1, wherein a metal film is attached as a conductive pattern to a surface of the silicone resin reflective substrate.

17. The silicone resin reflective substrate according to claim 16, wherein the metal film is made of at least one of a metal selected from the group consisting of Cu, Ag, Au, Ni, and Pd.

18. The silicone resin reflective substrate according to claim 16, wherein the metal film is a plating film, a metal evaporating film, a metal spraying film or a bonded metal foil.

19. The silicone resin reflective substrate according to claim 1, wherein the silicone resin reflective substrate is arranged at a back side, an outer periphery and/or a reflective surface of a light guiding material of either one of a light emitting element, a light emitting device and a photoelectric conversion element.

20. The silicone resin reflective substrate according to claim 1, wherein the reactive functional group is selected from the group consisting of a vinyl group, a phenyl group, an alkoxy group, an epoxy ring-containing group, and a methacryloyl group.

21. The silicone resin reflective substrate according to claim 1, wherein the adhesive component is selected from the group consisting of CH₂═

CHSi(OCH₃)₃, CH₂═

CHSi(OCH₂H₄OCH₃)₃, CH₂═

CH—

CO—

O(CH₂)₃SiCH₃(OCH₃)₂, CH₂═

CCH₃—

CO—

O(CH₂)₃SiCH₃(OCH₃)₂, C₆H₅Si(OCH₃)₃, C₂H₃O—

CH₂O(CH₃)₃Si(OCH₃)₃, C₂H₃O—

CH₂O(CH₂)₃SiCH₃(OCH₃)₂, 2-(2, 3-epoxypropyloxy propyl)-2, 4, 6, 8-tetramethyl-cyclotetrasiloxane, and 2-(2, 3-epoxypropyloxypropyl)-2, 4, 6, 8-tetramethyl-6-(trimethoxysilylethyl) cyclotetrasiloxane.

22. The silicone resin reflective substrate according to claim 1, wherein the reaction inhibitor is deactivated or vaporized when heated.

23. The silicone resin reflective substrate according to claim 1, wherein the reflective layer being made from the liquid-like base material composition having a viscosity of 0.5-500 Pa·

s.

24. The silicone resin reflective substrate according to claim 1, wherein the reflective layer being made from the grease-like, the plastic-like or the millable-type base material composition having a plasticity number of 100-500 mm/100.

25. The silicone resin reflective substrate according to claim 1, wherein the reaction inhibitor is deactivated when heated.

26. The silicone resin reflective substrate according to claim 1, wherein the reaction inhibitor is vaporized when heated.

27. A method for manufacturing a silicone resin reflective substrate of claim 1 comprising:

preparing a liquid-like base material composition, or a grease-like, a plastic-like or a millable-type base material composition including a reaction inhibitor, and a white inorganic filler powder including titanium oxide surface-treated with Al, Al₂O₃, ZnO, ZrO₂, SiO₂ and/or silane coupling agent dispersed in a three-dimensionally cross-linked silicone resin;

the base material composition having a plasticity to be cured for a reflective layer so that the white inorganic filler powder is incorporated into a 3-dimensional network of a three-dimensionally cross-linked silicone resin by dispersing an adhesive component of a silane compound or siloxane compound having a reactive functional group and a white inorganic filler powder including titanium oxide surface-treated with Al, Al₂O₃, ZnO, ZrO₂, SiO₂ and having a higher refractive index than that of a silicone resin into a polymerizable silicone resin base material which is to be polymerized into the 3-dimensionally-crosslinked silicone resin;

attaching the base material composition to a support body, the support body being surface treated with a reactive group-containing polysiloxane solution, in order to form a film-like, 3-dimensional-like or plate-like shape reflective layer; and

3-dimensionally crosslinking the base material composition into the 3-dimensionally-crosslinked silicone resin to form the film-like, 3-dimensional-like or plate-like shape reflective layer that is bonded to the support body to form the silicone resin reflective substrate with maintaining reflectance of a level of 85% or more at a region of 450-1,000 nm and a level of 90% or more at a region of 450 nm by the reflective layer.

28. The method for manufacturing the silicone resin reflective substrate according to claim 27, wherein the polymerization is carried out by at least one of a humidifying process, a pressurizing process and ultraviolet light irradiating process.

29. The method for manufacturing the silicone resin reflective substrate according to claim 27, wherein the polymerization is carried out by injection molding in a die, or by press-molding in a die under heat and/or pressure.

30. The method for manufacturing the silicone resin reflective substrate according to claim 29, wherein a surface of the molding die is coated with a fluoro resin.

31. The method for manufacturing the silicone resin reflective substrate according to claim 27, wherein a crosslinking agent for three dimensionally crosslinking the silicone resin, a reaction inhibitor which is deactivated or vaporized when heated, and a white inorganic filler powder which has a higher refractive index than that of the silicone resin, are dispersed in the polymerizable silicone resin base material to obtain the base material composition;

and then the polymerization is initiated when heated.