Post-deterioration performance estimating apparatus and post-deterioration performance estimating method for energy storage device, and energy storage system

• US 9,581,653 B2
• Filed: 11/27/2013
• Issued: 02/28/2017
• Est. Priority Date: 11/30/2012
• Status: Active Grant

• Current Assignee: GS Yuasa International Ltd. (GS Yuasa Corporation)
• Original Assignee: GS Yuasa International Ltd. (GS Yuasa Corporation)
• Inventors: Tao, Yohei, Yamate, Shigeki
• Primary Examiner(s): Lee, Paul D
• Application Number:
  US14/648,650
• Publication Number:
  US 20150301118A1
• Time in Patent Office: 1,189 Days
• Field of Search: 702/63
• US Class Current: 1/1
• CPC Class Codes: G01R 31/3648 comprising digital calculation means, e.g. for performing an algorithm
• CPC Class Codes: G01R 31/367 Software therefor, e.g. for battery testing using modelling or look-up tables
• CPC Class Codes: G01R 31/385 Arrangements for measuring battery or accumulator variables for monitoring G01R31/382
• CPC Class Codes: G01R 31/389 Measuring internal impedance, internal conductance or related variables
• CPC Class Codes: G01R 31/392 Determining battery ageing or deterioration, e.g. state of health
• CPC Class Codes: H01M 10/4285 Testing apparatus
• CPC Class Codes: H01M 10/48 Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals, H01M50/569
• CPC Class Codes: H02J 7/0048 Detection of remaining charge capacity or state of charge [SOC]
• CPC Class Codes: H02J 7/005 Detection of state of health [SOH]
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

A post-deterioration performance estimating apparatus estimates a post-deterioration performance value indicating performance of an energy storage device at a predetermined deterioration point, wherein discharge capacity of the energy storage device discharging at a predetermined first current is referred to as energy storage capacity, discharge capacity of the energy storage device discharging at a second current of a current value smaller than that of the first current is referred to as small current discharge capacity, a relational expression on relation among initial capacity of the energy storage device, a first capacity decreased amount obtained by subtracting the small current discharge capacity from the initial capacity, a second capacity decreased amount obtained by subtracting the energy storage capacity from the small current discharge capacity, and a cumulative operating period as a cumulative value of operating periods of the energy storage device is referred to as a first relational expression, and the post-deterioration performance estimating apparatus includes a post-deterioration performance estimator configured to estimate the post-deterioration performance value at the deterioration point in accordance with the first relational expression and the cumulative operating period at the deterioration point.

Claims

1. A post-deterioration performance estimating apparatus wherein a post-deterioration performance value indicates performance of an energy storage device, the apparatus comprising:

a post-deterioration performance estimator apparatus configured to electronically apply a first relational expression to electronically estimate the post-deterioration performance value at a deterioration point, the first relational expression includes a first capacity decreased amount and a second capacity decreased amount,

wherein equilibrial capacity indicates discharge capacity of the energy storage device that is discharged at a second current of a current value smaller than a first current,

wherein the post-deterioration performance estimator apparatus is configured to electronically obtain the first capacity decreased amount by electronically subtracting the equilibrial capacity at the deterioration point from an initial capacity of the energy storage device,

wherein energy storage capacity indicates discharge capacity of the energy storage device that is discharged at the first current,

wherein the post-deterioration performance estimator apparatus is configured to electronically obtain the second capacity decreased amount by

electricity subtracting the energy storage capacity at the deterioration point from the equilibrial capacity,

and wherein replacement of the energy storage device is carried out at a timing based on the post-deterioration performance value.

2. The post-deterioration performance estimating apparatus according to claim 1, wherein the first relational expression includes the initial capacity and a member of an exponential function of a cumulative operating period, the cumulative operating period is a time period from an operation start point of the energy storage device to the deterioration point.

3. The post-deterioration performance estimating apparatus according to claim 1, wherein:

the first relational expression includes a second relational expression and a third relational expression,

second relational expression includes the initial capacity, the first capacity decreased amount, the second capacity decreased amount, and a resistance value of direct current resistance or alternating current resistance of the energy storage device, and

the third relational expression includes the resistance value and a cumulative operating period, the cumulative operating period is a time period from an operation start point of the energy storage device to the deterioration point.

4. The post-deterioration performance estimating apparatus according to claim 3, wherein the resistance value includes a capacity ratio, the capacity ratio is a ratio of the second capacity decreased amount to the equilibrial capacity.

5. The post-deterioration performance estimating apparatus according to claim 4, wherein the capacity ratio is a linear function of the resistance value.

6. The post-deterioration performance estimating apparatus according to claim 4, wherein the post-deterioration performance estimator apparatus includes:

a data acquiring unit configured to acquire the equilibrial capacity at the deterioration point;

a capacity ratio calculator configured to calculate the capacity ratio at the deterioration point in accordance with the resistance value at the deterioration point and the second relational expression; and

a post-deterioration performance calculator configured to calculate the post-deterioration performance value in accordance with a fourth relational expression on relation among the post-deterioration performance value, the acquired equilibrial capacity, and the calculated capacity ratio.

7. The post-deterioration performance estimating apparatus according to claim 6, wherein the post-deterioration performance calculator is configured to calculate the post-deterioration performance value by multiplying a value obtained by subtracting the capacity ratio from one and the equilibrial capacity.

8. The post-deterioration performance estimating apparatus according to claim 3, wherein a coefficient in the second relational expression is variable depending on whether an operating temperature of the energy storage device exceeds a predetermined temperature or is not more than the predetermined temperature.

9. The post-deterioration performance estimating apparatus according to claim 3, wherein the post-deterioration performance estimator apparatus is configured to electronically estimate the post-deterioration performance value in accordance with the third relational expression on the resistance value at a time point after elapse of the cumulative operating period, the resistance value is in proportion to an exponential function that has a variable obtained by multiplying the cumulative operating period and a predetermined coefficient.

10. The post-deterioration performance estimating apparatus according to claim 9, wherein the third relational expression has the predetermined coefficient, the predetermined coefficient is an exponential function having a reciprocal of the operating temperature of the energy storage device as a variable.

11. The post-deterioration performance estimating apparatus according to claim 10, wherein the third relational expression has the coefficient in the exponential function having the reciprocal of the operating temperature of the energy storage device as the variable, the coefficient is variable depending on whether the operating temperature of the energy storage device exceeds or is not more than a predetermined temperature.

12. The post-deterioration performance estimating apparatus according to claim 3, wherein the post-deterioration performance estimator apparatus includes:

a data acquiring unit configured to acquire the cumulative operating period at the deterioration point; and

a resistance value calculator configured to calculate the resistance value at the deterioration point in accordance with the acquired cumulative operating period and the third relational expression.

13. The post-deterioration performance estimating apparatus according to claim 1, wherein:

a cumulative operating period is a time period from an operation start point of the energy storage device to the deterioration point, and

the first relational expression includes a member of a square root of the cumulative operating period and a coefficient in the member of the square root includes an exponential function that has a reciprocal of the operating temperature of the energy storage device as a variable.

14. The post-deterioration performance estimating apparatus according to claim 1, wherein the post-deterioration performance estimator apparatus includes:

a relational expression corrector configured to correct the first relational expression, the relational expression corrector is configured to electronically estimate the post-deterioration performance value in accordance with the corrected first relational expression.

15. The post-deterioration performance estimating apparatus according to claim 1, wherein:

the energy storage device is a lithium-ion secondary battery containing layered lithium transition metal oxide as a positive active material, and

the post-deterioration performance estimator apparatus is configured to electronically estimate the post-deterioration performance value in accordance with the first relational expression for the lithium-ion secondary battery.

16. An energy storage system comprising:

the post-deterioration performance estimating apparatus according to claim 1; and

the energy storage device.

17. A post-deterioration performance method wherein:

a post-deterioration performance value indicates performance of an energy storage device,

equilibrial capacity of the energy storage device indicates discharge capacity of the energy storage device that is discharged at a second current of a current value smaller than a first current, and

energy storage capacity indicates discharge capacity of the energy storage device that is discharged at the first current,

the method comprising;

electronically subtracting, by a post-deterioration performance estimator apparatus, the equilibrial capacity at a deterioration point from an initial capacity of the energy storage device to obtain a first capacity decreased amount;

electronically subtracting, by the post-deterioration performance estimator apparatus, the energy storage capacity at the deterioration point from the equilibrial capacity to obtain a second capacity decreased amount; and

electronically applying, by the post-deterioration performance estimator apparatus, a first relational expression to electronically estimate the post-deterioration performance value at the deterioration point,

wherein the first relational expression includes the first capacity decreased amount and the second capacity decreased amount,

and wherein replacement of the energy storage device is carried out at a timing based on the post-deterioration performance value.

18. An integrated circuit wherein a post-deterioration performance value indicates performance of an energy storage device, the integrated circuit comprising:

a post-deterioration performance estimator apparatus configured to electronically apply a first relational expression to electronically estimate the post-deterioration performance value at a deterioration point, the first relational expression includes a first capacity decreased amount and a second capacity decreased amount,

wherein equilibrial capacity indicates discharge capacity of the energy storage device that is discharged at a current of a second current value smaller than a first current,

wherein the post-deterioration performance estimator apparatus is configured to electronically obtain the first capacity decreased amount by electronically subtracting the equilibrial capacity at the deterioration point from an initial capacity of the energy storage device,

wherein energy storage capacity indicates discharge capacity of the energy storage device that is discharged at the first current,

wherein the post-deterioration performance estimator apparatus is configured to electronically obtain the second capacity decreased amount by electronically subtracting the energy storage capacity at the deterioration point from the equilibrial capacity,

and wherein replacement of the energy storage device is carried out at a timing based on the post-deterioration performance value.