Washcoats and coated substrates for catalytic converters and methods of making and using same

• US 9,586,179 B2
• Filed: 07/24/2014
• Issued: 03/07/2017
• Est. Priority Date: 07/25/2013
• Status: Active Grant

• Current Assignee: Umicore AG & Company KG (Umicore S.A.)
• Original Assignee: SDC Materials,Inc.
• Inventors: Yin, Qinghua, Qi, Xiwang, Biberger, Maximilian A., Leamon, David
• Primary Examiner(s): Slifka, Colin W
• Application Number:
  US14/340,351
• Publication Number:
  US 20150093312A1
• Time in Patent Office: 957 Days
• Field of Search: None
• US Class Current: 1/1
• CPC Class Codes: B01D 2255/20738 Iron
• CPC Class Codes: B01D 2255/50 Zeolites
• CPC Class Codes: B01D 2255/9025 Three layers
• CPC Class Codes: B01D 2255/91 NOx-storage component incorporated in the catalyst
• CPC Class Codes: B01D 2255/912 HC-storage component incorporated in the catalyst
• CPC Class Codes: B01D 2255/9202 Linear dimensions
• CPC Class Codes: B01D 53/945 characterised by a specific catalyst
• CPC Class Codes: B01J 2229/186 not in framework positions
• CPC Class Codes: B01J 23/40 of the platinum group metals
• CPC Class Codes: B01J 29/072 Iron group metals or copper
• CPC Class Codes: B01J 37/0219 the coating containing organic compounds
• CPC Class Codes: B01J 37/0244 Coatings comprising several layers
• CPC Class Codes: B01J 37/0246 Coatings comprising a zeolite
• CPC Class Codes: B01J 37/0248 Coatings comprising impregnated particles
• CPC Class Codes: B01J 37/349 making use of flames, plasmas or lasers
• CPC Class Codes: Y02A 50/20 Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
• CPC Class Codes: Y02T 10/12 Improving ICE efficiencies

Abstract

Disclosed are, inter alia, methods of forming coated substrates for use in catalytic converters, as well as washcoat compositions and methods suitable for using in preparation of the coated substrates, and the coated substrates formed thereby, which in some cases use iron-exchanged zeolite particles that provide enhanced performance such as lower light-off temperatures and lower pollutant levels in exhaust gases. The catalytic material is prepared by a plasma-based method, yielding catalytic material with a lower tendency to migrate on support at high temperatures, and thus less prone to catalyst aging after prolonged use. Also disclosed are catalytic converters using the coated substrates, which have favorable properties as compared to catalytic converters using catalysts deposited on substrates using solution chemistry. Also disclosed are exhaust treatment systems, and vehicles, such as diesel vehicles, particularly light-duty diesel vehicles, using catalytic converters and exhaust treatment systems using the coated substrates.

Claims

1. A coated substrate comprising:

a substrate; and

, coated on said substrate;

a washcoat layer comprising iron-exchanged zeolite particles, and

a washcoat layer comprising catalytically active Nano-on-Nano-on-micro (NNm) particles, the catalytically active Nano-on-Nano-on-micro (NNm) particles comprising composite nanoparticles bonded to micron-sized carrier particles, and the composite nanoparticles comprising a support nanoparticle and a catalytic nanoparticle.

2. The coated substrate of claim 1, wherein the iron-exchanged zeolite particles comprise between about 0.5% and about 15% iron by weight.

3. The coated substrate of claim 1, wherein the washcoat layer comprising catalytically active Nano-on-Nano-on-micro (NNm) particles further comprises a filler material comprised of micron-sized metal oxide particles, wherein the micron-sized metal oxide particles are not bonded to composite nanoparticles.

4. The coated substrate of claim 1, wherein the washcoat layer comprising catalytically active Nano-on-Nano-on-micro (NNm) particles further comprises a filler material comprised of micron-sized alumina particles impregnated with palladium by wet-chemical techniques.

5. The coated substrate of claim 1, wherein the iron-exchanged zeolite particles further comprise palladium.

6. The coated substrate of claim 1, wherein the catalytically active Nano-on-Nano-on-micro (NNm) particles comprise at least one platinum group metal.

7. The coated substrate of claim 1, wherein the catalytically active Nano-on-Nano-on-micro (NNm) particles comprise platinum or palladium.

8. The coated substrate of claim 7, wherein the catalytically active Nano-on-Nano-on-micro (NNm) particles comprise platinum and palladium in a weight ratio from about 8:

1 to about 1;

1.

9. The coated substrate of claim 1, wherein the washcoat layer comprising iron-exchanged zeolite particles further comprises metal-oxide particles and boehmite particles.

10. The coated substrate of claim 9, wherein the metal-oxide particles are aluminum-oxide particles.

11. The coated substrate of claim 1, wherein the iron-exchanged zeolite particles in the washcoat layer comprising iron-exchanged zeolite particles have a diameter of 0.2 microns to 8 microns.

12. The coated substrate of claim 1, wherein the washcoat layer comprising catalytically active Nano-on-Nano-on micro (NNm) particles further comprises boehmite particles and silica particles.

13. The coated substrate of claim 1, further comprising a corner-fill layer deposited directly on the substrate, wherein the corner-fill layer does not comprise catalytically active Nano-on-Nano-on-micro (NNm) particles or iron-exchanged zeolite particles.

14. The coated substrate of claim 13, wherein the corner-fill layer comprises zeolite particles that are not iron-exchanged zeolite particles.

15. A catalytic converter comprising a coated substrate according to claim 1.

16. A method of treating an exhaust gas, comprising contacting the coated substrate of claim 1 with the exhaust gas.

17. A method of forming a coated substrate, the method comprising:

a) coating a substrate with a washcoat composition comprising iron-exchanged zeolite particles; and

b) coating the substrate with a washcoat composition comprising catalytically active Nano-on-Nano-on-micro (NNm) particles comprising composite nanoparticles bonded to micron-sized carrier particles, and the composite nanoparticles comprise a support nanoparticle and a catalytic nanoparticle.

18. The method of claim 17, wherein the iron-exchanged zeolite particles comprise between about 0.5% and about 15% iron by weight.

19. The method of claim 17, wherein the washcoat composition comprising catalytically active Nano-on-Nano-on-micro (NNm) particles further comprises a filler material comprised of micron-sized metal oxide particles, wherein the micron-sized metal oxide particles are not bonded to composite nanoparticles.

20. The method of claim 17, wherein the washcoat layer comprising catalytically active Nano-on-Nano-on-micro (NNm) particles further comprises a filler material comprised of micron-sized alumina particles impregnated with palladium by wet-chemical techniques.

21. The method of claim 17, wherein the iron-exchanged zeolite particles further comprise palladium.

22. The method of claim 17, wherein the catalytically active Nano-on-Nano-on-micro (NNm) particles comprise at least one platinum group metal.

23. The method of claim 22, wherein the catalytically active Nano-on-Nano-on-micro (NNm) particles comprise platinum and palladium in a weight ratio from about 8:

1 to about 1;

1.

24. The method of claim 17, wherein the support nanoparticles have an average diameter of about 10 nm to about 20 nm.

25. The method of claim 17, wherein the catalytic nanoparticles have an average diameter of about 1 nm to about 5 nm.

26. The method of claim 17, wherein the washcoat composition comprising iron-exchanged zeolite particles further comprises metal-oxide particles and boehmite particles.

27. The method of claim 26, wherein the metal-oxide particles are aluminum-oxide particles.

28. The method of claim 17, wherein the iron-exchanged zeolite particles in the washcoat composition comprising iron-exchanged zeolite particles have a diameter of 0.2 microns to 8 microns.

29. The method of claim 17, wherein the washcoat composition comprising catalytically active Nano-on-Nano-on micro (NNm) particles further comprises boehmite particles and silica particles.

30. The method of claim 17, further comprising coating the substrate with a corner-fill layer deposited directly on the substrate.

31. The method of claim 30, wherein the corner-fill layer comprises zeolite particles.

32. The method of claim 31, wherein the zeolite particles in the corner-fill layer are iron-exchanged zeolite particles.

33. The method of claim 32, wherein the iron-exchanged zeolite particles in the corner-fill layer further comprise palladium.

34. The method of claim 30, wherein the corner-fill layer comprises catalytically active Nano-on-Nano-on micro (NNm) particles.