Electrodialytic separation of CO;gas from seawater

• US 9,586,181 B2
• Filed: 07/06/2011
• Issued: 03/07/2017
• Est. Priority Date: 07/06/2011
• Status: Active Grant

• Current Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Original Assignee: Palo Alto Research Center, Inc. (Xerox Holdings Corp.)
• Inventors: Eisaman, Matthew D., Littau, Karl
• Primary Examiner(s): Phasge, Arun S
• Application Number:
  US13/177,421
• Publication Number:
  US 20130008792A1
• Time in Patent Office: 2,071 Days
• Field of Search: 204/529, 204/531, 204/534, 204/537
• US Class Current: 1/1
• CPC Class Codes: B01D 2311/18 pH control
• CPC Class Codes: B01D 2311/2626 Absorption or adsorption
• CPC Class Codes: B01D 2311/2653 Degassing
• CPC Class Codes: B01D 61/445 with bipolar membranes; Water splitting
• CPC Class Codes: C02F 1/4693 electrodialysis
• CPC Class Codes: C02F 2103/08 Seawater, e.g. for desalination
• CPC Class Codes: C02F 2201/4618 Supplying or removing reactants or electrolyte
• CPC Class Codes: Y02A 20/124 Water desalination
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

A method comprises flowing process solution and electrode solution into a BPMED apparatus, applying a voltage such that the process solution is acidified and basified and dissolved CO₂ is generated, flowing the process solution out of the apparatus, and desorbing CO₂ out of the process solution. A method for desorbing CO₂ from an ocean comprises flowing seawater and electrode solution into a BPMED apparatus, applying a voltage such that dissolved CO₂ is generated, flowing the seawater out of the apparatus, and desorbing CO₂ out of the seawater. A method for producing a desalted solution and CO₂ gas comprises flowing process solution and electrode solution into a BPMED apparatus that includes one or more three-compartment cells, applying a voltage such that the process solution is acidified, basified, and desalted, flowing the process solution out of the apparatus, and desorbing CO₂ out of the process solution.

Claims

1. A method comprising:

flowing a process solution into a BPMED system with a BPMED apparatus having at least two compartments separated by membranes, wherein the process solution is one of a seawater solution, a brine or water that has absorbed gaseous CO₂;

flowing an electrode rinse solution into the BPMED apparatus only across electrodes in the BPMED apparatus;

applying a voltage to the BPMED apparatus and the process solution is acidified and basified, and dissolved CO₂ is generated in the acidified process solution;

flowing the acidified and basified process solution out of the BPMED apparatus;

desorbing the CO₂ out of the acidified process solution;

combining the acidified and basified process solution such that the process solution is approximately neutral pH; and

discharging the process solution from the BPMED system.

2. The method of claim 1 wherein the acidified process solution is flowed out of the BPMED apparatus and through a CO₂ desorption unit before being flowed to an acidified solution tank such that the desorbing occurs at the CO₂ desorption unit.

3. The method of claim 1 wherein the acidified process solution is flowed out of the BPMED apparatus and into an acidified solution tank such that the desorbing occurs at the acidified solution tank.

4. The method of claim 1 further comprising flowing the acidified process solution back through the BPMED apparatus to descale the BPMED apparatus.

5. The method of claim 1 wherein the BPMED apparatus comprises one or more three-compartment BPMED cells such that when the voltage is applied, the process solution is also desalted.

6. The method of claim 1 wherein a flow rate for flowing the process solution into the BPMED apparatus and a current applied by the voltage are selected such that an energy consumption of the BPMED apparatus is minimized.

7. The method of claim 6 wherein the flow rate is approximately 0.3 lpm per cell to 0.7 lpm per cell and the current density is approximately 19 mA/cm² to 61 mA/cm².

8. The method of claim 7 wherein the flow rate is approximately 0.5 lpm per cell and the current density is approximately 22 mA/cm².

9. The method of claim 7 wherein the flow rate is approximately 0.3 lpm per cell and the current is approximately 31 mA/cm².

10. The method of claim 1 wherein a current applied by the voltage is selected such that the process solution is acidified to a pH that minimizes an energy consumption of the BPMED apparatus.

11. The method of claim 10 wherein the pH is approximately 3 to 6.

12. The method of claim 11 wherein the pH is approximately 4.5.

13. A method for producing a desalted solution and CO₂ gas comprising:

flowing a process solution comprised of one of seawater, a brine or water, wherein the process solution has absorbed gaseous CO₂ into a BPMED system with a BPMED apparatus, wherein the BPMED apparatus includes a membrane stack comprised of one or more three-compartment cells;

flowing an electrode rinse solution into the BPMED apparatus only across electrodes in the BPMED apparatus, the process solution and the electrode rinse solution being the only solutions used;

applying a voltage to the BPMED apparatus such that the process solution is acidified, basified, and desalted;

flowing the acidified, basified, and desalted process solution out of the BPMED apparatus;

desorbing the CO₂ out of the acidified process solution;

combining the acidified and basified process solution such that the process solution is approximately neutral pH; and

discharging the process solution from the BPMED system.

14. The method of claim 13 wherein the process solution is a seawater solution such that when the process solution is desalted, desalinated water is generated.