Nanodiamond containing composite and a method for producing the same

• US 9,598,558 B2
• Filed: 12/27/2013
• Issued: 03/21/2017
• Est. Priority Date: 12/27/2013
• Status: Active Grant

• Current Assignee: Carbodeon Ltd. Oy
• Original Assignee: Carbodeon Ltd. Oy
• Inventors: Myllymaki, Vesa
• Primary Examiner(s): Loewe, Robert S
• Application Number:
  US14/141,779
• Publication Number:
  US 20160102188A1
• Time in Patent Office: 1,180 Days
• Field of Search: None
• US Class Current: 1/1
• CPC Class Codes: C01B 21/0648 After-treatment, e.g. grinding, purification transformation of hexagonal into cubic or wurtzitic boron nitride C04B35/5831
• CPC Class Codes: C01P 2004/50 Agglomerated particles
• CPC Class Codes: C01P 2004/61 Micrometer sized, i.e. from 1-100 micrometer
• CPC Class Codes: C01P 2004/62 Submicrometer sized, i.e. from 0.1-1 micrometer
• CPC Class Codes: C01P 2004/64 Nanometer sized, i.e. from 1-100 nanometer
• CPC Class Codes: C01P 2006/12 Surface area
• CPC Class Codes: C01P 2006/32 Thermal properties
• CPC Class Codes: C08K 2003/385 Binary compounds of nitrogen with boron
• CPC Class Codes: C08K 2201/011 Nanostructured additives
• CPC Class Codes: C08K 3/04 Carbon
• CPC Class Codes: C08K 3/38 Boron-containing compounds
• CPC Class Codes: C08L 77/06 Polyamides derived from polyamines and polycarboxylic acids C08L77/10 takes precedence
• CPC Class Codes: C09C 1/44 Carbon
• CPC Class Codes: C09C 1/46 Graphite C09C1/0015 takes precedence
• CPC Class Codes: C09C 1/48 Carbon black
• CPC Class Codes: C09C 1/62 Metallic pigments or fillers C09C1/0015 takes precedence
• CPC Class Codes: C09C 3/063 Coating
• CPC Class Codes: C09K 5/08 Materials not undergoing a change of physical state when used C09K5/16, C09K5/20 take precedence

Abstract

A method for producing a composition comprising at least one filler and a nanodiamond material, and a composition comprising a nanodiamond material and at least one filler is disclosed. Further, a method for producing a nanodiamond containing thermal composite, and a nanodiamond containing thermal composite comprising nanodiamond material, at least one filler and at least one polymer is disclosed.

Claims

1. A method for producing a composition comprising at least one filler and a nanodiamond material, wherein the method comprises

(i) a nanodiamond material containing liquid medium is brought into contact with at least one filler for producing a suspension;

(ii) the liquid medium is removed from the suspension of step (i) for producing the composition comprising the at least one filler and the nanodiamond material.

2. The method according to claim 1, wherein the nanodiamond material containing liquid medium in step (i) is in a form of dispersion.

3. The method according to claim 1, wherein the nanodiamond material containing liquid medium in step (i) is in a form of suspension.

4. The method according to claim 1 wherein the liquid medium is selected from the group consisting of polar protic solvents, polar aprotic solvents, dipolar aprotic solvents, organic solvents and mixtures thereof.

5. The method according to claim 4, wherein the polar protic solvent is water, an alcohol, linear aliphatic diol, branched diol or a carboxylic acid, the polar aprotic solvent is dichloromethane, tetrahydrofuran, propylene carbonate or a lactam, the dipolar aprotic solvent is a ketone, ester, N,N-methylformamide or dimethyl sulfoxide and the organic solvent is toluene or an aromatic solvent.

6. The method according to claim 4, wherein the liquid medium is selected from the group consisting of water, methanol, ethanol, iso-propanol, linear aliphatic diols, branched diols, N-methyl-2-pyrrolidone (NMP), N-ethyl-2-pyrrolidone (NEP) and dimethyl sulfoxide (DMSO), and mixtures of any said solvents.

7. The method according to claim 1, wherein the filler is selected from the group consisting of metal, metal oxide, metal nitride, metal carbide, carbon compound, silicon compound, boron compound, ceramic materials, natural fibers, and combinations thereof.

8. The method according to claim 7, wherein the carbon compound is selected from the group consisting of diamond material other than detonation diamond, graphite, carbon black, carbon fiber, graphene, oxidized graphene, carbon soot, carbon nanotube, pyrolytic carbon, silicon carbide, aluminum carbide, carbon nitride, and combinations thereof.

9. The method according to claim 7, wherein the boron compound is selected from the group consisting of hexagonal or cubic boron nitride, boron carbide, and combinations thereof.

10. The method according to claim 1, wherein in step (i) the nanodiamond material containing liquid medium is mechanically mixed with the at least one filler, preferably the mixing is performed with a speed mixer.

11. The method according to claim 1, wherein the composition is subjected to mechanical treatment to break up formed composition agglomerates, preferably the mechanical treatment is beads milling.

12. The method according to claim 1, wherein the nanodiamond material substantially adheres on the surface of the at least one filler material.

13. The method according to claim 12, wherein adhered nanodiamond material particle agglomerate size is less than 500 nm, preferably less than 300 nm, more preferably less than 100 nm and most preferably less than 50 nm.

14. The method according claim 12, wherein the nanodiamond material on the filler surface is able to generate coupling effect to another material.

15. The method according to claim 14, wherein the another material is selected from polymers, metals, ceramic materials or their mixtures.

16. The method according to claim 1, wherein zeta-potential value of the nanodiamond material exceeds ±

35 mV as dispersed into water.

17. A method for producing a nanodiamond containing thermal composite, wherein the method comprises

(i) nanodiamond material containing liquid medium is brought into contact with at least one filler for producing a suspension;

(ii) the liquid medium is removed from the suspension of step (i) for producing a composition comprising at least one filler and nanodiamond material; and

(iii) the composition of step (ii) and at least one polymer are mixed for producing the nanodiamond containing thermal composite.

18. The method according to claim 17, wherein the nanodiamond material containing liquid medium in step (i) is in a form of dispersion.

19. The method according to claim 18, wherein the composition of step (ii) is subjected to mechanical treatment to break up formed filler agglomerates prior step (iii), preferably the mechanical treatment is beads milling.

20. The method according to claim 17, wherein the nanodiamond material containing liquid medium in step (i) is in a form of suspension.

21. The method according to claim 17, wherein the liquid medium is selected from the group consisting of polar protic solvents, polar aprotic solvents, dipolar aprotic solvents, organic solvents and mixtures thereof.

22. The method according to claim 21, wherein the polar protic solvent is water, an alcohol, linear aliphatic diol, branched diol or a carboxylic acid, the polar aprotic solvent is dichloromethane, tetrahydrofuran, propylene carbonate or a lactam, the dipolar aprotic solvent is a ketone, an ester, N,N-methylformamide or dimethyl sulfoxide and the organic solvent is toluene or an aromatic solvent.

23. The method according to claim 21, wherein the liquid medium is selected from the group consisting of water, methanol, ethanol, iso-propanol, linear aliphatic diols, branched diols, N-methyl-2-pyrrolidone (NMP), N-ethyl-2-pyrrolidone (NEP) and dimethyl sulfoxide (DMSO), and mixtures of any said solvents.

24. The method according to claim 17, wherein the filler is selected from the group consisting of metal, metal oxide, metal nitride, metal carbide, carbon compound, silicon compound, boron compound, ceramic materials, natural fibers, and combinations thereof.

25. The method according to claim 24, wherein the carbon compound is selected from the group consisting of diamond material other than detonation diamond, graphite, carbon black, carbon fiber, graphene, oxidized graphene, carbon soot, carbon nanotube, pyrolytic carbon, silicon carbide, aluminum carbide, carbon nitride, and combinations thereof.

26. The method according to claim 24, wherein the boron compound is selected from the group consisting of hexagonal or cubic boron nitride, boron carbide, and combinations thereof.

27. The method according to claim 17, wherein in step (i) the nanodiamond material containing liquid medium is mechanically mixed with the at least one filler, preferably the mixing is performed with a speed mixer.

28. The method according to claim 17, wherein the nanodiamond material substantially adheres on surface of the at least one filler material.

29. The method according to claim 28, wherein adhered nanodiamond material particle agglomerate size is less than 500 nm, preferably less than 300 nm, more preferably less than 100 nm and most preferably less than 50 nm.

30. The method according to claim 28 wherein the nanodiamond material on the filler surface is able to generate coupling effect to the at least one polymer material.

31. The method according to claim 17, wherein zeta-potential value of the nanodiamond material exceeds ±

35 mV as dispersed into water.

32. The method according to claim 17, wherein the at least one polymer is selected from the group consisting of epoxies, silicones, thermoplastic polymer, acrylates, polyurethanes, polyesters, fluoropolymers, siloxanes, polyimides and mixtures thereof.

33. A composition comprising from 0.01 to 80 wt. % of nanodiamond material, and from 1 to 99.99 wt. % of at least one filler, wherein the nanodiamond material is substantially adhered on the surface of the at least one filler by bringing nanodiamond material containing liquid medium into contact with the at least one filler and removing the liquid medium.

34. The composition according to claim 33, wherein active surface area of the composition is lower than active surface area of a composition without the substantial adherence of nanodiamond material on surface of at least one filler material.

35. The composition according to claim 34, wherein the active surface area of the composition is at least 5% lower than active surface area of a composition without the substantial adherence of nanodiamond material on surface of at least one filler material.

36. The composition according to claim 33, wherein the composition comprises 0.01 to 40 wt.-%, preferably from 0.01 to 20 wt.-%, more preferably from 0.01 to 5 wt.-% of the nanodiamond material.

37. The composition according to claim 33, wherein the composition comprises from 10 to 90 wt.-%, preferably 15 to 85 wt.-%, more preferably from 15 to 70 wt.-%, and most preferably 20-50 wt.-% of the at least one filler.

38. The composition according to claim 33, wherein the filler is selected from the group consisting of metal, metal oxide, metal nitride, metal carbide, carbon compound, silicon compound, boron compound such as boron nitride, ceramic materials, natural fibers, and combinations thereof.

39. The composition according to claim 38, wherein the carbon compound is selected from the group consisting of diamond material other than detonation diamond, graphite, carbon black, carbon fiber, graphene, oxidized graphene, carbon soot, carbon nanotube, pyrolytic carbon, silicon carbide, aluminum carbide, carbon nitride, and combinations thereof.

40. The composition according to claim 38, wherein said boron compound is selected from the group consisting of hexagonal or cubic boron nitride, boron carbide, and combinations thereof.

41. The composition according to claim 33, wherein the nanodiamond material particles have an average primary particle size from 1 nm to 10 nm, preferably from 2 nm to 8 nm, more preferably from 3 nm to 7 nm, and most preferably from 4 nm to 6 nm.

42. The composition according to claim 33, wherein the at least one filler has an average primary particle size from 10 nm to 2000 μ

m, preferably 50 nm to 500 μ

m and more preferably 500 nm to 200 μ

m.

43. The composition according to claim 33, wherein adhered nanodiamond material particle agglomerate size is less than 500 nm, preferably less than 300 nm, more preferably less than 100 nm and most preferably less than 50 nm.

44. The composition according to claim 33, wherein the nanodiamond material on the filler surface is able to generate coupling effect to another material.

45. The composition according to claim 44, wherein the another material is selected from group of polymers, metals, ceramic materials or their mixtures.

46. The composition according claim 33, wherein zeta-potential value of the nanodiamond material exceeds ±

35 mV as dispersed into water.

47. A nanodiamond containing thermal composite comprising 0.01 to 80 wt. % of nanodiamond material, from 1 to 90 wt. % of at least one filler, and from 5 to 95 wt.-% of at least one polymer, wherein the nanodiamond material is substantially adhered on the surface of the at least one filler material by bringing nanodiamond material containing liquid medium into contact with the at least one filler and removing the liquid medium.

48. The nanodiamond containing thermal composite according to claim 47, wherein average thermal conductivity of the composite is at least 5% higher than average thermal conductivity a nanodiamond containing composite without the substantial adherence of nanodiamond material on the surface of at least one filler material.

49. The nanodiamond containing thermal composite according to claim 47, wherein the average thermal conductivity of the composite is at least 20% higher than, preferably 50% higher than, more preferably 70% higher than average thermal conductivity of a nanodiamond containing composite without the substantial adherence of nanodiamond material on the surface of at least one filler material.

50. The nanodiamond containing thermal composite according to claim 47, wherein the composite comprises from 0.01 to 40 wt.-%, preferably from 0.01 to 20 wt.-%, more preferably from 0.01 to 5 wt.-% of the nanodiamond material.

51. The nanodiamond containing thermal composite according to claim 47, wherein the composite comprises from 10 to 70 wt.-%, preferably 10 to 50 wt.-%, more preferably from 15 to 45 wt.-% of said at least one filler.

52. The nanodiamond containing thermal composite according to claim 47, wherein the composite comprises from 20 to 90 wt.-%, preferably from 50 to 85 wt.-% of the at least one polymer.

53. The nanodiamond containing thermal composite according to claim 47, wherein the at least one polymer is selected from the group consisting of epoxies, silicones, thermoplastic polymer, acrylates, polyurethanes, polyesters, fluoropolymers, siloxanes, polyimides and mixtures thereof.

54. The nanodiamond containing thermal composite according to claim 47, wherein the filler is selected from the group consisting of metal, metal oxide, metal nitride, metal carbide, carbon compound, silicon compound, boron compound, ceramic materials, natural fibers, and combinations thereof.

55. The nanodiamond containing thermal composite according to claim 54, wherein the carbon compound is selected from the group consisting of diamond material other than detonation diamond, graphite, carbon black, carbon fiber, graphene, oxidized graphene, carbon soot, carbon nanotube, pyrolytic carbon, silicon carbide, aluminum carbide, carbon nitride, and combinations thereof.

56. The nanodiamond containing thermal composite according to claim 54, wherein the boron compound is selected from the group consisting of hexagonal or cubic boron nitride, boron carbide, and combinations thereof.

57. The nanodiamond containing thermal composite according to claim 47, wherein the nanodiamond material particles have an average primary particle size from 1 nm to 10 nm, preferably from 2 nm to 8 nm, more preferably from 3 nm to 7 nm, and most preferably from 4 nm to 6 nm.

58. The nanodiamond containing thermal composite according to claim 47 wherein the at least one filler has an average primary particle size from 10 nm to 2000 μ

m, preferably 50 nm to 500 μ

m and more preferably 500 nm to 200 μ

m.

59. The nanodiamond containing thermal composite according to claim 47, wherein adhered nanodiamond material particle agglomerate size is less than 500 nm, preferably less than 300 nm, more preferably less than 100 nm and most preferably less than 50 nm.

60. The composition according to claim 47, wherein the nanodiamond material on the filler surface is able to generate coupling effect to the at least one polymer.

61. The composition according claim 47, wherein zeta-potential value of the nanodiamond material exceeds ±

35 mV as dispersed into water.