Efficient volatile metal removal from low rank coal in gasification, combustion, and processing systems and methods

• US 9,598,653 B2
• Filed: 11/06/2015
• Issued: 03/21/2017
• Est. Priority Date: 05/22/2009
• Status: Active Grant

• Current Assignee: Western Research Institute
• Original Assignee: The University of Wyoming Research Corporation
• Inventors: Bland, Alan E., Sellakumar, Kumar Muthusami, Newcomer, Jesse D.
• Primary Examiner(s): GRAVINI, STEPHEN MICHAEL
• Application Number:
  US14/934,459
• Publication Number:
  US 20160102260A1
• Time in Patent Office: 501 Days
• Field of Search: 343/80, 343/81, 344/13, 344/97, 423/215.5, 604/07, 607/81, 29/52, 296/235, 298/90, 481/97.R, 482/10, 122/22
• US Class Current: 1/1
• CPC Class Codes: C10J 2300/0903 Feed preparation
• CPC Class Codes: C10J 2300/0909 Drying
• CPC Class Codes: C10J 2300/093 Coal
• CPC Class Codes: C10J 2300/0969 Carbon dioxide
• CPC Class Codes: C10J 2300/1643 Conversion of synthesis gas to energy
• CPC Class Codes: C10J 2300/1656 Conversion of synthesis gas to chemicals
• CPC Class Codes: C10J 2300/1815 for carbon dioxide
• CPC Class Codes: C10J 3/02 Fixed-bed gasification of lump fuel
• CPC Class Codes: C10J 3/84 with means for removing dust or tar from the gas
• CPC Class Codes: C10L 5/366 Powders
• CPC Class Codes: C10L 9/08 by heat treatments, e.g. calcining
• CPC Class Codes: Y02E 20/16 Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
• CPC Class Codes: Y02E 20/18 Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
• CPC Class Codes: Y10T 29/49229 Prime mover or fluid pump making

Abstract

Efficient coal pre-processing systems (69) integrated with gasification, oxy-combustion, and power plant systems include a drying chamber (28), a volatile metal removal chamber (30), recirculated gases, including recycled carbon dioxide (21), nitrogen (6), and gaseous exhaust (60) for increasing the efficiencies and lowering emissions in various coal processing systems.

Claims

1. An efficient method for coal gasification comprising the steps of:

supplying wet coal in a coal gasification system assembly;

feeding said wet coal into at least one chamber of said coal gasification system assembly;

drying said wet coal in said at least one chamber to create a substantially dried coal having a coal temperature of up to about 300°

F.;

removing volatile metals from said substantially dried coal in said at least one chamber to create a volatile metal reduced dried coal having a coal temperature of up to about 600°

F.;

transferring said volatile metal reduced dried coal to a gasifier;

producing syngas from said volatile metal reduced dried coal in said gasifier;

filtering said syngas from particulate matter;

separating carbon dioxide from said syngas to create a fuel gas supply and a downstream carbon dioxide supply; and

recirculating said downstream carbon dioxide back into at least part of said coal gasification system assembly.

2. An efficient method for coal gasification according to claim 1 and further comprising the step of using said fuel gas supply to produce electricity.

3. An efficient method for coal gasification according to claim 1 and further comprising the step of using said fuel gas supply to produce chemicals.

4. An efficient method for coal gasification according to claim 1 wherein said step of recirculating said downstream carbon dioxide back into at least part of said coal gasification system assembly comprises the step of heating said downstream carbon dioxide with a heat exchanger and directing said carbon dioxide to said at least part of said coal gasification system assembly.

5. An efficient method for coal gasification according to claim 1 wherein said step of removing volatile metals from said substantially dried coal in said at least one chamber to create a volatile metal reduced dried coal comprises the step of removing up to about 87% of mercury from said coal in said at least one chamber.

6. An efficient method for coal gasification according to claim 1 and further comprising the step of removing a total of up to about 90% of mercury from said coal in said coal gasification system assembly.

7. An efficient method for coal gasification according to claim 1 wherein said step of recirculating said downstream carbon dioxide back into at least part of said coal gasification system assembly comprises the step of reacting said downstream carbon dioxide in gasification reactions of said gasification system assembly.

8. An efficient method for coal gasification according to claim 1 wherein said step of recirculating said downstream carbon dioxide back into at least part of said coal gasification system assembly comprises the step of using said downstream carbon dioxide as a heat carrier in at least part of said gasification system assembly.

9. An efficient method for coal gasification according to claim 1 wherein said step of recirculating said downstream carbon dioxide back into at least part of said coal gasification system assembly comprises the step of using said downstream carbon dioxide as a coal transporter in at least part of said gasification system assembly.

10. An efficient method for coal gasification according to claim 1 and further comprising the step of providing an air separation unit to create an output of oxygen and nitrogen from an air input.

11. An efficient method for coal gasification according to claim 1 wherein said step of feeding said wet coal into at least one chamber of said coal gasification system assembly comprises the step of feeding said wet coal into a drying chamber of said coal gasification system assembly.

12. An efficient method for coal gasification according to claim 1 wherein said step of drying said wet coal in said at least one chamber to create a substantially dried coal comprises the step of providing said substantially dried coal selected from a group consisting of at least about 90% dry, at least about 91% dry, at least about 92% dry, at least about 93% dry, at least about 94% dry, at least about 95% dry, at least about 96% dry, at least about 97% dry, at least about 98% dry, at least about 99% dry, and about 100% dry.

13. An efficient method for coal gasification according to claim 1 wherein said step of drying said wet coal in said at least one chamber to create a substantially dried coal comprises the step of pre-process drying said wet coal with recycled non-air.

14. An efficient method for coal gasification according to claim 1 and further comprising the step of recycling a first supply of recycled non-air to said at least one chamber.

15. An efficient method for coal gasification according to claim 1 wherein said step of drying said wet coal in said at least one chamber to create a substantially dried coal comprises the step of drying said wet coal for a first amount of time.

16. An efficient method for coal gasification according to claim 1 wherein said step of removing volatile metals from said substantially dried coal in said at least one chamber to create a volatile metal reduced dried coal comprises the step of removing volatile metals from said substantially dried coal in a separate volatile metal removal chamber to create a volatile metal reduced dried coal.

17. An efficient method for coal gasification according to claim 1 wherein said step of removing volatile metals from said substantially dried coal in said at least one chamber to create a volatile metal reduced dried coal having a coal temperature of up to about 600°

F. comprises the step of removing volatile metals from said substantially dried coal in said at least one chamber to create a volatile metal reduced dried coal having a coal temperature of between about 275°

F. and about 600°

F.

18. An efficient method for coal gasification according to claim 16 and further comprising the step of recycling a second supply of recycled non-air to said separate volatile metal removal chamber.

19. An efficient method for coal gasification according to claim 1 wherein said step of removing volatile metals from said substantially dried coal in said at least one chamber to create a volatile metal reduced dried coal comprises the step of heating said substantially dried coal for a second amount of time.

20. An efficient method for coal gasification according to claim 14 wherein said step of recycling said supply of recycled non-air comprises the step of recycling a supply of heated non-air to said chamber.

21. An efficient method for coal gasification according to claim 1 wherein said step of removing volatile metals from said substantially dried coal in said at least one chamber to create a volatile metal reduced dried coal comprises the step of removing volatile metals from said coal, said volatile metals selected from a group consisting of arsenic, selenium, cadmium, lead, and mercury.