Simplified LNG process

• US 9,612,050 B2
• Filed: 01/12/2012
• Issued: 04/04/2017
• Est. Priority Date: 01/12/2012
• Status: Active Grant

• Current Assignee: 9052151 Canada Corporation
• Original Assignee: 9052151 Canada Corporation
• Inventors: Palmer, Gary
• Primary Examiner(s): Jules, Frantz
• Assistant Examiner(s): KING, BRIAN M
• Application Number:
  US13/349,219
• Publication Number:
  US 20130180282A1
• Time in Patent Office: 1,909 Days
• Field of Search: 62611, 62617, 62618, 62620
• CPC Class Codes: F25J 1/0022 Hydrocarbons, e.g. natural gas
• CPC Class Codes: F25J 1/004 by flash gas recovery F25J1/0267 takes precedence
• CPC Class Codes: F25J 1/0208 in combination with an internal quasi-closed refrigeration loop, e.g. with deep flash recycle loop F25J1/021 takes precedence
• CPC Class Codes: F25J 1/0232 integration within a pressure letdown station of a high pressure pipeline system
• CPC Class Codes: F25J 1/0254 controlling particular process parameter, e.g. pressure, temperature
• CPC Class Codes: F25J 2205/04 in the feed line, i.e. upstream of the fractionation step
• CPC Class Codes: F25J 2220/62 Separating low boiling components, e.g. He, H2, N2, Air
• CPC Class Codes: F25J 2220/64 Separating heavy hydrocarbons, e.g. NGL, LPG, C4+ hydrocarbons or heavy condensates in general
• CPC Class Codes: F25J 2220/66 Separating acid gases, e.g. CO2, SO2, H2S or RSH
• CPC Class Codes: F25J 2230/30 Compression of the feed stream
• CPC Class Codes: F25J 2240/40 Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval
• CPC Class Codes: F25J 2245/90 the recycled stream being boil-off gas from storage
• CPC Class Codes: F25J 2270/90 External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration
• CPC Class Codes: F25J 2290/62 Details of storing a fluid in a tank

Abstract

A simplified method for production of a commercial supply liquefied natural gas (LNG) supplied in a pressurized vessel includes taking a supply of natural gas including contaminants from a stranded well or from a pipe line and extracting from the supply gas water vapor and CO2 in a fixed bed absorption system. In a first stage the supply gas is separated into first and second streams where the first stream contains all the cold energy available from the feed stream and sufficient of the contaminants are removed to meet a product specification for the composition of the LNG supply. In a second stage the first stream is liquefied by the available cool energy for commercial pressurized supply container The second stream contains natural gas which is as much as 75% of the feed stream together with substantially all the contaminants and is used as a natural gas supply.

Claims

1. A method for production of liquefied natural gas (LNG) comprising:

taking a supply stream of natural gas including contaminants including water vapor, CO2 and H2S, and by-products including light overhead gases and heavier hydrocarbons including Ethane, Propane and any other heavy components;

in a compression step, compressing said supply gas stream;

in an extracting step, extracting from the supply gas stream said water vapor, H2S and CO2 of said contaminants;

in a cooling step, cooling the entire supply gas stream excluding the contaminants extracted in said extracting step and forming a dense phase stream which is arranged to produce a two phase liquid/vapor stream on subsequent expansion;

downstream of the compressing, extracting and cooling steps in an expanding step expanding the entire compressed, cooled, dense phase, supply gas stream to form an expanded stream which is a two phase liquid/vapor stream;

at a first separation step subsequent to the expanding step, separating the expanded stream into a first stream and a second stream;

wherein the first stream contains Ethane, Propane and heavy components together with some methane;

wherein the second stream contains some methane and most of said light overhead gases;

further expanding the first stream and supplying the further expanded first stream to a second separation step comprising a fractionator or separator;

in the fractionator or separator in the second separation step, separating the first stream into an overhead vapor stream and a bottom stream;

wherein the bottom stream contains some methane and most of the said Ethane, Propane and any other heavy components;

wherein the overhead vapor stream is a cold energy supply gas stream consisting mainly of methane arranged to be sufficiently pure by having sufficient of the H2O, CO2 and H2S contaminants, and light overhead gases and heavier hydrocarbons, removed to meet a product specification for the composition of an LNG supply;

providing a commercial supply as LNG from the overhead vapor stream;

said bottom stream being removed for use separate from said commercial supply;

wherein the second stream is not supplied to the fractionator or separator in said second separation step but is instead used as a coolant in upstream heat exchangers acting on said supply gas stream after said extracting step and is removed for use separate from said commercial supply.

2. The method according to claim 1 wherein said bottom stream from the fractionator or separator is used in gaseous form as a natural gas supply.

3. The method according to claim 1 wherein said bottom stream from the fractionator or separator is used in liquid form as a low grade LNG.

4. The method according to claim 1 wherein said bottom stream and said second stream are discarded to a common discharge stream for said separate use.

5. The method according to claim 4 wherein said discharge stream is used in said separate use in gaseous form as a natural gas supply containing said heavier hydrocarbons and of lower quality than said commercial supply of LNG.

6. The method according to claim 1 wherein the LNG is supplied in a container maintained under a pressure greater than one atmosphere.

7. The method according to claim 1 wherein the overhead stream from the second separation contains less than 1% of contaminants.

8. The method according to claim 1 wherein the second stream from the first separation together with the bottom stream from the second separation comprises in the range 70 to 75% of the supply stream.

9. The method according to claim 1 wherein the overhead stream from the second separation comprises in the range 25 to 30% of the supply stream.

10. The method according to claim 1 wherein the supply stream is taken from a natural gas pipeline and the second stream and the bottom stream are returned to the pipeline.

11. The method according to claim 1 wherein the supply stream is a stranded gas well and the second stream from the first separation and the bottom stream from the second separation are consumed locally as a natural gas supply.

12. The method according to claim 1 wherein the supply stream is from a pipe line and the method is used for peak shaving by tapping into the pipe line during periods of low demand to store gas for use in periods of high demand.

13. The method according to claim 1 including extracting cool from the bottom stream from the second separation to act as a source of cooling recycling cold energy back into the supply stream.