Capture of carbon dioxide (CO2) from air

• US 9,616,375 B2
• Filed: 01/24/2014
• Issued: 04/11/2017
• Est. Priority Date: 04/17/2007
• Status: Active Grant

• Current Assignee: Carbon Sink, Inc.
• Original Assignee: Carbon Sink, Inc.
• Inventors: Wright, Allen B., Lackner, Klaus S., Leon-Guerrero, Ed, Ginster, Ursula, Catterson, Tymothy, Madison, Karl, Ishikawa, Ryuhei, Grimm, George W., Malcomson, Mark, Liu, Ping
• Primary Examiner(s): Jones, Christopher P
• Application Number:
  US14/163,559
• Publication Number:
  US 20140370576A1
• Time in Patent Office: 1,173 Days
• CPC Class Codes: B01D 2253/202 Polymeric adsorbents
• CPC Class Codes: B01D 2253/206 Ion exchange resins
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2259/40083 Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
• CPC Class Codes: B01D 53/025 with wetted adsorbents; Chromatography analytical chromatography G01N30/00 - G01N30/96; for liquids B01D15/08
• CPC Class Codes: B01D 53/04 with stationary adsorbents B01D53/025 takes precedence
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

Disclosed is a method for removing carbon dioxide from a gas stream, comprising placing the gas stream in contact with a resin, wetting the resin with water, collecting water vapor and carbon dioxide from the resin, and separating the carbon dioxide from the water vapor. The resin may be placed in a chamber or a plurality of chambers connected in series wherein the first chamber contains resin that was first contacted by the gas, and each successive chamber contains resin which has been wetted and carbon dioxide collected from for a greater period of time than the previous chamber, and so on, until the last chamber. Secondary sorbents may be employed to further separate the carbon dioxide from the water vapor.

Claims

1. A method for removing carbon dioxide from a gas, comprising bringing said gas in contact with a resin in a chamber, evacuating said gas from the chamber, wetting said resin with a liquid, collecting liquid and carbon dioxide from said chamber, and separating said carbon dioxide from said liquid.

2. The method of claim 1, wherein the resin is wetted by immersion in a liquid.

3. The method of claim 2, wherein the liquid is water and also contains carbonic anhydrase.

4. The method of claim 1, wherein the liquid comprises a secondary sorbent.

5. The method of claim 4, wherein the secondary sorbent is a weak liquid amine.

6. The method of claim 4, wherein the carbon dioxide is released from the secondary sorbent upon an increase in temperature.

7. The method as recited in claim 1, wherein upon evacuating said gas stream, said chamber is at a near vacuum pressure.

8. The method as recited in claim 1, wherein a plurality of chambers comprising the resin are connected in series, and wherein the liquid enters the first chamber and exits through a last chamber, the carbon dioxide and liquid being collected from said last chamber.

9. A method for removing carbon dioxide from a gas, comprising bringing said gas in contact with a resin in a chamber, evacuating gas from the chamber, wetting said resin with liquid water, collecting liquid water and carbon dioxide from said resin, and separating said carbon dioxide from said liquid water.

10. The method of claim 9, wherein the resin is wetted by immersion in liquid water.

11. The method of claim 9, wherein the liquid water also contains carbonic anhydrase.