Systems and methods for converting carbonaceous fuels

• US 9,616,403 B2
• Filed: 03/14/2014
• Issued: 04/11/2017
• Est. Priority Date: 03/14/2013
• Status: Active Grant

• Current Assignee: Ohio State Innovation Foundation (Ohio State University)
• Original Assignee: Ohio State Innovation Foundation (Ohio State University)
• Inventors: Fan, Liang-Shih, Wang, Dawei
• Primary Examiner(s): SEIFU, LESSANEWORK T
• Application Number:
  US14/774,730
• Publication Number:
  US 20160016137A1
• Time in Patent Office: 1,124 Days
• CPC Class Codes: B01J 2208/0038 Solids
• CPC Class Codes: B01J 2208/00752 Feeding
• CPC Class Codes: B01J 2208/00893 Feeding means for the reactants
• CPC Class Codes: B01J 2208/00902 Nozzle-type feeding elements
• CPC Class Codes: B01J 2208/00911 Sparger-type feeding elements
• CPC Class Codes: B01J 8/0015 Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
• CPC Class Codes: B01J 8/0025 by an ascending fluid
• CPC Class Codes: B01J 8/003 in a downward flow
• CPC Class Codes: B01J 8/005 Separating solid material from the gas/liquid stream separation processes per se B01D
• CPC Class Codes: B01J 8/0055 using cyclones
• CPC Class Codes: B01J 8/085 Feeding reactive fluids for solid material, see B01J8/0015
• CPC Class Codes: B01J 8/087 Heating or cooling the reactor
• CPC Class Codes: B01J 8/12 moved by gravity in a downward flow
• CPC Class Codes: B01J 8/125 with multiple sections one above the other separated by distribution aids, e.g. reaction and regeneration sections
• CPC Class Codes: B01J 8/1827 the fluidising gas being a reactant
• CPC Class Codes: B01J 8/1836 Heating and cooling the reactor B01J8/42 takes precedence
• CPC Class Codes: B01J 8/26 with two or more fluidised beds, e.g. reactor and regeneration installations
• CPC Class Codes: C10J 3/725 Redox processes

Abstract

A system for converting carbonaceous fuels is provided. The system includes a gaseous fuel conversion reactor, a solid fuel conversion reactor, and a fuel pretreatment fluidized bed reactor disposed between the gaseous fuel conversion reactor and the solid fuel conversion reactor. The fuel pretreatment fluidized bed reactor devolatilizes a solid fuel using heat to produce an off-gas and a devolatilized solid fuel. The gaseous fuel conversion reactor converts the off-gas from the fuel pretreatment fluidized bed reactor to a product gas stream comprising carbon dioxide and water. The solid fuel conversion reactor receives a mixture of oxygen carrier solids and devolatilized solid fuel from the pretreatment reactor discharge and reduces the devolatilized solid fuel with the oxygen carrier solids to convert the devolatilized solid fuel to an intermediate gas.

Claims

1. A system for converting carbonaceous fuels comprising a gaseous fuel conversion reactor, a solid fuel conversion reactor, and a fuel pretreatment fluidized bed reactor disposed between the gaseous fuel conversion reactor and the solid fuel conversion reactor;

the gaseous fuel conversion reactor comprising;

a gaseous fuel reactor oxygen carrier solid inlet,

a gaseous fuel reactor off-gas inlet configured to receive off-gas from the fuel pretreatment fluidized bed reactor, and

a gaseous fuel reactor oxygen carrier solid outlet,

wherein the gaseous fuel conversion reactor is configured to convert the off-gas and oxygen carrier solids to a product gas stream comprising carbon dioxide and water, thereby reducing at least a portion of the oxygen carrier solids to reduced oxygen carrier solids;

the fuel pretreatment fluidized bed reactor comprising;

a pretreatment reactor solid fuel inlet disposed in a fuel introduction section of the fuel pretreatment reactor,

a pretreatment reactor oxygen carrier inlet configured to receive a mixture of oxygen carrier solids and reduced oxygen carrier solids from the gaseous fuel reactor oxygen carrier solid outlet,

a pretreatment reactor intermediate gas inlet configured to receive intermediate gas from the solid fuel conversion reactor, the intermediate gas being used for fluidization, and

a pretreatment reactor discharge in communication with the gaseous fuel conversion reactor off-gas inlet,

wherein the fuel pretreatment fluidized bed reactor is configured to volatilize solid fuel using heat from the mixture of oxygen carrier solids and reduced oxygen carrier solids to produce a devolatilized solid fuel and off-gas, and subsequently discharge the off-gas, the devolatilized solid fuel, and the mixture of oxygen carrier solids and reduced oxygen carrier solids via the pretreatment reactor discharge;

the solid fuel conversion reactor comprising;

a solid fuel conversion reactor inlet configured to receive the mixture of oxygen carrier solids and reduced oxygen carrier solids and devolatilized solid fuel from the pretreatment reactor discharge and

a solid fuel conversion reactor intermediate gas outlet in communication with the pretreatment reactor intermediate gas inlet, and

a solid fuel conversion reactor oxygen carrier solid outlet,

wherein the solid fuel conversion reactor is configured to react the devolatilized solid fuel with the mixture of oxygen carrier solids and reduced oxygen carrier solids to produce the intermediate gas comprising carbon dioxide and water, thereby further reducing oxygen carrier solids to reduced oxygen carrier solids.

2. The system of claim 1, further comprising an oxidation reactor configured to react the reduced oxygen carrier solids from the solid fuel conversion reactor oxygen carrier solid outlet with an oxidation gas stream to convert the reduced oxygen carrier solid back to the oxygen carrier solid, the oxidation reactor comprising

a reduced oxygen carrier solid inlet configured to receive the reduced oxygen carrier solid, and

an oxidation reactor discharge configured to discharge the oxygen carrier solid and an oxygen depleted oxidation gas stream.

3. The system of claim 1, further comprising a pretreatment gas-solids separation unit in communication with the pretreatment reactor discharge and configured to separate the off-gas from the devolatilized solid fuel and the oxygen carrier solid exiting the fuel pretreatment fluidized bed reactor.

4. The system of claim 1, wherein the gaseous fuel conversion reactor is divided into two or more staged reactors in series.

5. The system of claim 1, wherein the solid fuel conversion reactor is divided into two or more staged reactors in series.

6. The system of claim 1, wherein the gas velocity of the off-gas through the gaseous fuel conversion reactor is less than the minimum fluidization velocity of the oxygen carrier solid.

7. The system of claim 1, further comprising a conversion enhancement gas inlet configured to introduce a conversion enhancement gas into the solid fuel conversion reactor to enhance conversion of the devolatilized solid fuel.

8. The system of claim 7, wherein the conversion enhancement gas is the product gas stream from the gaseous fuel conversion reactor.

9. The system of claim 7, wherein the gas velocity of the conversion enhancement gas through the solid fuel conversion reactor is less than the minimum fluidization velocity of the oxygen carrier solid.

10. The system of claim 2, further comprising an oxidizer gas-solids separation unit in communication with the oxidation reactor discharge and configured to separate the oxygen depleted oxidation gas stream from the oxygen carrier solid exiting the oxidation reactor.

11. The system of claim 2, further comprising a non-mechanical seal separating the solid fuel conversion reactor and the oxidation reactor, the non-mechanical seal configured to prevent gases generated in the solid fuel conversion reactor and the oxidation gas stream in the oxidation reactor from transferring between the solid fuel conversion reactor and the oxidation reactor while allowing the reduced oxygen carrier solid to pass through.

12. The system of claim 10, further comprising a non-mechanical seal separating the gaseous fuel conversion reactor and oxidizer gas-solids separation unit, the non-mechanical seal configured to prevent the product gas stream of the gaseous fuel conversion reactor and the oxygen depleted oxidation gas stream in the oxidizer gas-solids separation unit from transferring between the gaseous fuel conversion reactor and the oxidizer gas-solids separation unit or oxygen carrier solid storage vessel while allowing the oxygen carrier solid to pass through.

13. The system of claim 1, wherein the fuel pretreatment reactor further comprises a substantially cone shaped bottom in communication with a gas-solids jet configured to provide a uniform distribution of the intermediate gas and the oxygen carrier solid into the fuel pretreatment fluidized bed reactor;

wherein the gas-solids jet comprises the pretreatment reactor intermediate gas inlet and the pretreatment reactor oxygen carrier inlet.

14. The system of claim 1, wherein the fuel pretreatment reactor further comprises a supply chamber and a mixing chamber with a crossflow slit disposed between the supply chamber and the mixing chamber configured to allow passage of the oxygen carrier solid through the crossflow slit;

wherein an aeration inlet provides an aeration gas from the bottom or from the side of the supply chamber to propel the oxygen carrier solid through the crossflow slit into the mixing chamber.

15. The system of claim 1, wherein the fuel pretreatment reactor further comprises a gas introduction zone and a solids mixing zone separated by a meshed gas distributor configured to distribute the intermediate gas uniformly across the fuel pretreatment fluidized bed reactor.

16. The system of claim 15, further comprising an ash separator disposed between the solid fuel conversion intermediate gas outlet and the pretreatment reactor intermediate gas inlet and is configured to separate ash and/or unconverted carbon from the intermediate gas before the intermediate gas is provided to the fuel pretreatment fluidized bed reactor.

17. A system for converting carbonaceous fuels comprising a gaseous fuel conversion reactor, a solid fuel conversion reactor, a fuel pretreatment fluidized bed reactor disposed between the gaseous fuel conversion reactor and the solid fuel conversion reactor, an oxidation reactor disposed downstream of the solid fuel conversion reactor, and a pretreatment gas-solids separation unit;

the gaseous fuel conversion reactor comprising;

a gaseous fuel reactor oxygen carrier solid inlet,

a gaseous fuel reactor off-gas inlet configured to receive off-gas from the fuel pretreatment fluidized bed reactor, and

a gaseous fuel reactor oxygen carrier solid outlet,

wherein the gaseous fuel conversion reactor is configured to convert the off-gas and oxygen carrier solids to a product gas stream comprising carbon dioxide and water, thereby reducing at least a portion of the oxygen carrier solids to reduced oxygen carrier solids;

the fuel pretreatment fluidized bed reactor comprising

a pretreatment reactor solid fuel inlet disposed in a fuel introduction section of the fuel pretreatment reactor,

a pretreatment reactor oxygen carrier inlet configured to receive a mixture of oxygen carrier solids and reduced oxygen carrier solids from the gaseous fuel reactor oxygen carrier solid outlet,

a pretreatment reactor intermediate gas inlet configured to receive intermediate gas from the solid fuel conversion reactor, the intermediate gas being used for fluidization, and

a pretreatment reactor discharge in communication with the gaseous fuel conversion reactor off-gas inlet,

wherein the fuel pretreatment fluidized bed reactor is configured to volatilize solid fuel using heat from the mixture of oxygen carrier solids and reduced oxygen carrier solids to produce a devolatilized solid fuel and off-gas, and subsequently discharge the off-gas, the devolatilized solid fuel, and the mixture of oxygen carrier solids and reduced oxygen carrier solids via the pretreatment reactor discharge;

the solid fuel conversion reactor comprising;

a solid fuel conversion reactor inlet configured to receive the mixture of oxygen carrier solids and reduced oxygen carrier solids and devolatilized solid fuel from the pretreatment reactor discharge,

a solid fuel conversion reactor intermediate gas outlet in communication with the pretreatment reactor intermediate gas inlet, and

a solid fuel conversion reactor oxygen carrier solid outlet,

wherein the solid fuel conversion reactor is configured to react the devolatilized solid fuel with the mixture of oxygen carrier solids and reduced oxygen carrier solids to produce the intermediate gas comprising carbon dioxide and water, thereby further reducing oxygen carrier solids to reduced oxygen carrier solids;

the oxidation reactor comprising;

a reduced oxygen carrier solid inlet configured to receive the reduced oxygen carrier solid and

an oxidation reactor discharge configured to discharge the oxygen carrier solid and an oxygen depleted oxidation gas stream,

wherein the oxidation reactor is configured to react the reduced oxygen carrier solids from the solid fuel conversion reactor oxygen carrier solid outlet with an oxidation gas stream to convert the reduced oxygen carrier solid back to the oxygen carrier solid; and

wherein the pretreatment gas-solids separation unit is in communication with the pretreatment reactor discharge and configured to separate the off-gas from the devolatilized solid fuel and the oxygen carrier solid exiting the fuel pretreatment reactor.

18. The system of claim 17, further comprising an oxidizer gas-solids separation unit in communication with the oxidation reactor discharge and configured to separate the oxygen depleted oxidation gas stream from the oxygen carrier solid exiting the oxidation reactor.

19. The system of claim 17, wherein the fuel pretreatment reactor further comprises a supply chamber and a mixing chamber with a crossflow slit disposed between the supply chamber and the mixing chamber configured to allow passage of the oxygen carrier solid through the crossflow slit;

wherein an aeration inlet provides an aeration gas from the bottom or from the side of the supply chamber to propel the oxygen carrier solid through the crossflow slit into the mixing chamber.

20. The system of claim 17, wherein the fuel pretreatment reactor further comprises a gas introduction zone and a solids mixing zone separated by a meshed gas distributor configured to distribute the intermediate gas uniformly across the fuel pretreatment fluidized bed reactor.