Method of treating a fabric by washing with a detergent comprising an acrylamide/DADMAC cationic polymer

• US 9,617,501 B2
• Filed: 08/25/2015
• Issued: 04/11/2017
• Est. Priority Date: 08/27/2014
• Status: Active Grant

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Doria, Heather Anne, Aguilera-Mercado, Bernardo, Panandiker, Rajan Keshav, Sivik, Mark Robert, Fossum, Renae Dianna, Birkel, Susanne, Vetter, Nicholas David, Barrera, Carola, Flores-Figueroa, Aaron
• Primary Examiner(s): BOYER, CHARLES I
• Application Number:
  US14/834,466
• Publication Number:
  US 20160060574A1
• Time in Patent Office: 595 Days
• CPC Class Codes: C11D 1/22 derived from aromatic compounds
• CPC Class Codes: C11D 1/29 Sulfates of polyoxyalkylene ethers
• CPC Class Codes: C11D 1/62 Quaternary ammonium compounds
• CPC Class Codes: C11D 1/83 Mixtures of non-ionic with anionic compounds
• CPC Class Codes: C11D 17/0039 Coated compositions or coated components in the compositions, (micro)capsules
• CPC Class Codes: C11D 17/042 Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
• CPC Class Codes: C11D 17/043 Liquid or thixotropic (gel) compositions
• CPC Class Codes: C11D 17/045 Multi-compartment
• CPC Class Codes: C11D 2111/12 Soft surfaces, e.g. textile
• CPC Class Codes: C11D 2111/44 Multi-step processes
• CPC Class Codes: C11D 3/001 Softening compositions
• CPC Class Codes: C11D 3/0015 liquid
• CPC Class Codes: C11D 3/373 containing silicones
• CPC Class Codes: C11D 3/3738 Alkoxylated silicones
• CPC Class Codes: C11D 3/3769 (Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
• CPC Class Codes: C11D 3/505 encapsulated or adsorbed on a carrier, e.g. zeolite or clay

Abstract

A method of treating a fabric, where the method includes a washing step and a rinsing step. A multi-component fabric treatment system, wherein the system includes a first component comprising a detergent composition, and where the system further includes a second component comprising a softener composition.

Claims

1. A method of treating a fabric, said method comprising:

A. a washing step, wherein said washing step comprises contacting said fabric with an effective amount of a detergent composition, thereby forming a washed fabric, wherein said detergent composition comprises;

i. a surfactant system comprising an anionic surfactant and nonionic surfactant in a weight ratio of from about 1.1;

1 to about 4;

1;

ii. a silicone; and

iii. a cationic polymer, wherein the cationic polymer is characterized by

a. having a weight average molecular weight of from about 5 kDaltons to about 200 kDaltons;

b. comprising a first structural unit derived from acrylamide, and a second structural unit derived from DADMAC; and

c. wherein said first structural unit and said second structural unit are in a structural unit ratio of from about 5;

95 to about 45;

55; and

then

B. a rinsing step, wherein said washed fabric is contacted with an effective amount of a softener composition, thereby forming a treated fabric, wherein said softener composition comprises a fabric softening active (FSA) selected from the group consisting of a quaternary ammonium compound, silicone, fatty acids or esters thereof, sugars, fatty alcohols, alkoxylated fatty alcohols, polyglycerol esters, oily sugar derivatives, wax emulsions, fatty acid glycerides, or mixtures thereof.

2. A method according to claim 1, wherein said washing step comprises contacting said fabric with said detergent composition in the presence of water, wherein the detergent composition and the water form a wash liquor.

3. A method according to claim 2, wherein said wash liquor is substantially removed from said washed fabric before said rinsing step occurs.

4. A method according to claim 1, wherein said rinsing step comprises contacting said fabric with said softener composition in the presence of water, wherein the softener composition and the water form a rinse liquor.

5. A method according to claim 1, wherein said weight ratio is from about 1.5:

1 to about 2.5;

1.

6. A method according to claim 1, wherein said weight ratio is about 2:

1.

7. A method according to claim 1, wherein said anionic surfactant comprises linear alkylbenzene sulphonate (LAS), alkyl ethyoxylated sulfate (AES), or mixtures thereof.

8. A method according to claim 7, wherein said anionic surfactant comprises LAS and AES in a weight ratio of about 0.5:

1 to about 1.5;

1.

9. A method according to claim 1, wherein said FSA comprises a quaternary ammonium compound selected from the group consisting:

a) linear quaternary ammonium compounds

b) branched quaternary ammonium compounds

c) cyclic quaternary ammonium compounds

d) and mixtures thereof;

said quaternary ammonium compounds comprising;

one or more C₁₀-C₂₂ fatty acid moieties, C₁₆-C₂₀ fatty acid moieties, or C₁₆-C₁₈ fatty acid moieties, said fatty acid moieties having an Iodine value from 0 to about 95;

a counter ion; and

one or more moieties selected from the group consisting of alkyl moieties, ester moieties, amide moieties, and ether moieties said one or more moieties being covalently bound to the nitrogen of said quaternary ammonium compound.

10. A method according to claim 1, wherein said FSA comprises a silicone selected from the group consisting of polydimethylsiloxane (PDMS), aminosilicone, silicone polyether, cationic silicones, silicone polyurethane, silicone polyureas, or mixtures thereof.

11. A method according to claim 1, wherein said detergent composition and/or said fabric softener composition further comprises a perfume microcapsule.

12. A method according to claim 1, wherein said rinsing step results in Silicone Deposition on the treated fabric of from about 80 ug silicone/g to about 5000 ug silicone/g according to the method described herein.

13. A method according to claim 1, wherein said rinsing step results in a Silicone Deposition Index on the treated fabric of from about 4% to about 75%.

14. A method according to claim 1, wherein said anionic surfactant comprises fatty acids and salts thereof.

15. A method according to claim 1, wherein said detergent composition is encapsulated in a pouch, wherein said pouch comprises water-soluble film.

16. A multi-component fabric treatment system, wherein the system comprises a first component comprising a detergent composition as described in claim 1, and where the system further comprises a second component comprising a softener composition as described in claim 1.

17. A method according to claim 1, wherein the cationic polymer is characterized by a weight average molecular weight of from about 10 kDaltons to about 100 kDaltons.

18. A method according to claim 1, wherein the cationic polymer is characterized by a weight average molecular weight of from about 20 kDaltons to about 50 kDaltons.