Gas generating composition and gas generator using the same

• US 9,624,140 B2
• Filed: 09/20/2013
• Issued: 04/18/2017
• Est. Priority Date: 10/18/2012
• Status: Active Grant

• Current Assignee: Daicel Corporation
• Original Assignee: Daicel Corporation
• Inventors: Fujisaki, Yoji, Matsuda, Naoki
• Primary Examiner(s): BROWN, DREW J
• Application Number:
  US14/424,902
• Publication Number:
  US 20150225308A1
• Time in Patent Office: 1,306 Days
• CPC Class Codes: B60R 2021/26011 using a filter through which the inflation gas passes
• CPC Class Codes: B60R 2021/2642 comprising a plurality of combustion chambers or sub-chambers
• CPC Class Codes: B60R 21/264 using instantaneous generation of gas, e.g. pyrotechnic B60R21/268 takes precedence
• CPC Class Codes: B60R 21/2644 using only solid reacting substances, e.g. pellets, powder
• CPC Class Codes: C06B 23/02 for neutralising poisonous gases from explosives produced during blasting
• CPC Class Codes: C06B 31/00 Compositions containing an inorganic nitrogen-oxygen salt
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

Provided is a gas generating composition that maintains stable ignition performance for a long period. A gas generating composition includes: a gas generating agent including (a) fuel selected from a triazine compound and a guanidine compound, (b) an oxidizing agent including a Combination of (b-1) basic metal nitrate and (b-2) basic metal carbonate, and (c) a binder; and (d) an absorbent. The gas generating agent and the absorbent may not be integrally molded or may be integrally molded.

Claims

1. A gas generating composition comprising:

a gas generating agent including (a) fuel selected from the group consisting of triazine compounds and guanidine compounds, and (b) an oxidizing agent including a combination of (b-1) basic metal nitrate and (b-2) basic metal carbonate;

(c) a binder; and

(d) an absorbent.

2. The gas generating composition according to claim 1, wherein the fuel component (a) comprises melamine cyanurate (MC) and nitroguanidine (NQ), and a mass ratio (MC/NQ) of MC and NQ is 0.2 to 1.5.

3. The gas generating composition according to claim 1, wherein, in the oxidizing agent component (b), contents of the basic metal nitrate of the component (b-1) and the basic metal carbonate of the component (b-2) are in a relation of (b-1)>

(b-2).

4. The gas generating composition according to claim 1, wherein the absorbent is at least one selected from the group consisting of synthetic zeolite, natural zeolite, activated alumina, silica gel, activated carbon, and clay.

5. The gas generating composition according to claim 4, wherein the synthetic zeolite is selected from the group consisting of a 3A type (pore diameter 3 Å

), a 4A type (pore diameter 4 Å

), a 5A type (pore diameter 5 Å

), and a 13X type (pore diameter 10 Å

).

6. The gas generating composition according to claim 1, wherein the gas generating agent and the absorbent are not integrally molded.

7. The gas generating composition according to claim 1, wherein the gas generating agent and the absorbent are integrally molded.

8. A gas generator for an airbag apparatus using the gas generating composition according to claim 1,

the gas generator comprising:

a housing having a gas discharge port and serving as an outer shell container;

a cylindrical filter arranged in the housing having the gas discharge port, such that an outer circumferential surface thereof directly faces the gas discharge port via a cylindrical space and that both end surfaces thereof are in contact with a top surface and a bottom surface of the housing respectively; and

a combustion chamber formed by an inner space of the cylindrical filter, excluding an ignition device arranged in the center;

the gas generating composition being stored in the combustion chamber.

9. A gas generator for an airbag apparatus using the gas generating composition according to claim 1,

the gas generator comprising:

a housing having a gas discharge port and serving as an outer shell container;

a cylindrical filter arranged in the housing having the gas discharge port, such that an outer circumferential surface thereof directly faces the gas discharge port via a cylindrical space and that both end surfaces thereof are in contact with a top surface and a bottom surface of the housing respectively; and

a combustion chamber formed by an inner space of the cylindrical filter, excluding an ignition device arranged in the center,

the combustion chamber being divided into two chambers by an air-permeable partition plate, one of the two chambers charged with a gas generating agent, the other chamber charged with an absorbent.

10. A gas generator for an airbag apparatus using the gas generating composition according to claim 1,

the gas generator comprising:

a housing having a gas discharge port and serving as an outer shell container;

a cylindrical filter arranged in the housing having the gas discharge port, such that an outer circumferential surface thereof directly faces the gas discharge port via a cylindrical space and that both end surfaces thereof are in contact with a top surface and a bottom surface of the housing respectively;

a combustion chamber formed by an inner space of the cylindrical filter, excluding an ignition device arranged in the center;

the cylindrical space being divided by an air-permeable partition plate into a first space including the gas discharge port and a second space not including the gas discharge port;

a gas generating agent being charged in the combustion chamber; and

an absorbent being charged in the second space.

11. A gas generator for an airbag apparatus using the gas generating composition according to claim 1,

the gas generator comprising:

a housing having a gas discharge port and serving as an outer shell container;

a cylindrical filter arranged in the housing having the gas discharge port, such that an outer circumferential surface thereof directly faces the gas discharge port via a cylindrical space and that both end surfaces thereof are in contact with a top surface and a bottom surface of the housing respectively;

a combustion chamber formed by an inner space of the cylindrical filter, excluding an ignition device arranged in the center;

an annular recessed portion, which is formed by recessing an end surface of the cylindrical filter in an axial direction, being provided in at least one of boundary portions between the respective end surfaces of the cylindrical filter and the top surface and the bottom surface of the housing;

a gas generating agent being charged in the combustion chamber; and

an absorbent being charged in the annular recessed portion.

12. The gas generating composition according to claim 6, wherein the molded article of the gas generating agent is larger than the molded article of the absorbent.