Vacuum infusion adhesive and methods related thereto

• US 9,624,411 B2
• Filed: 11/27/2013
• Issued: 04/18/2017
• Est. Priority Date: 07/01/2010
• Status: Active Grant

• Current Assignee: Westech Aerosol Corporation
• Original Assignee: David W. Carnahan
• Inventors: Carnahan, David W., Yuodelis, Robert R., Manlove, James C.
• Primary Examiner(s): Feely, Michael J
• Application Number:
  US14/092,513
• Publication Number:
  US 20140091496A1
• Time in Patent Office: 1,238 Days
• Field of Search: None
• CPC Class Codes: B29C 65/48 using adhesives , i.e. using supplementary joining material; solvent bonding
• CPC Class Codes: B29C 65/4805 characterised by the type of adhesives
• CPC Class Codes: B29C 70/443 and impregnating by vacuum or injection
• CPC Class Codes: B29K 2063/00 Use of EP, i.e. epoxy resins or derivatives thereof, as moulding material
• CPC Class Codes: B29K 2913/00 Use of textile products or fabrics as mould materials
• CPC Class Codes: B29L 2009/00 Layered products
• CPC Class Codes: C08G 59/4246 polymers with carboxylic terminal groups
• CPC Class Codes: C08G 59/4253 Rubbers
• CPC Class Codes: C08L 63/00 Compositions of epoxy resins; Compositions of derivatives of epoxy resins
• CPC Class Codes: C09J 163/00 Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
• CPC Class Codes: C09J 163/10 Epoxy resins modified by unsaturated compounds
• CPC Class Codes: C09J 2463/00 Presence of epoxy resin
• CPC Class Codes: C09J 5/00 Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers

Abstract

An epoxy adhesive that is adapted to enable spray delivery and seamless polymerization during epoxy resin vacuum infusion techniques is disclosed. The epoxy adhesive can include one or more epoxy resins and one or more solvents that are used to dissolve the one or more epoxy resins. An adduct, a tackifier, and fumed silica can also be added to the adhesive.

Claims

1. A spray adhesive composition for epoxy resin vacuum infusion techniques comprising a mixture of epoxy resins dissolved in (4) one or more solvents;

wherein the mixture of epoxy resins comprises;

(1) an epoxy resin with a weight per epoxide value of 1500 to 4000 grams per equivalent,

(2) an epoxy polyacrylate resin with a weight per epoxide value of 200 to 350 grams per equivalent and a viscosity of 200 to 1500 cP at 25°

C., and

(3) a carboxyl terminated butadiene nitrile (CTNB) modified epoxy resin with a weight per epoxide value of 180 to 1000 grams per equivalent;

wherein the spray adhesive composition is capable of cross-linking and structurally integrating with a catalyzed epoxy infusion resin to form a single integrated cured structure.

2. The spray adhesive composition of claim 1, wherein:

(1) the epoxy resin has a weight per epoxide value of 2300 to 3800 grams per equivalent,

(2) the epoxy polyacrylate resin has a weight per epoxide value of 300 to 320 grams per equivalent and a viscosity of 800 to 1100 cP at 25°

C., and

(3) the CTNB modified epoxy resin has a weight per epoxide value of 195 to 210 grams per equivalent.

3. The spray adhesive composition of claim 1, wherein the mixture of epoxy resins comprises bisphenol A/epichlorohydrin resins.

4. The spray adhesive composition of claim 1, wherein the mixture of epoxy resins features a weight ratio of (1) the epoxy resin to (3) the CTBN modified epoxy resin ranging from 0.4 parts by weight to 0.6 parts by weight of (1) the epoxy resin to one part by weight of (3) the CTBN modified epoxy resin.

5. The spray adhesive composition of claim 1, wherein the mixture of epoxy resins features a weight ratio of (2) the epoxy polyacrylate resin to (3) the CTBN modified epoxy resin ranging from 0.05 parts by weight to 0.7 parts by weight of (2) the epoxy acrylate resin to one part by weight of (3) the CTBN modified epoxy resin.

6. The spray adhesive composition of claim 1, wherein the spray adhesive contains a total amount of epoxy resin of 40 to 75 wt %, based on the weight of the spray adhesive.

7. The spray adhesive composition of claim 1, wherein (4) the one or more solvents is an organic ketone.

8. The spray adhesive composition of claim 1, wherein (4) the one or more solvents is acetone.

9. The spray adhesive composition of claim 1, wherein the spray adhesive contains a total amount of solvent of 25 to 60 wt %, based on the weight of the spray adhesive.

10. The spray adhesive composition of claim 1, further comprising (5) fumed silica suspended therein.

11. The spray adhesive composition of claim 10, wherein the spray adhesive contains an amount of (5) the fumed silica of up to 5 wt %, based on the weight of the spray adhesive.

12. The spray adhesive composition of claim 10, wherein:

(1) the epoxy resin has a weight per epoxide value of 2300 to 3800 grams per equivalent and is present in an amount of 13 wt %, based on the weight of the spray adhesive;

(2) the epoxy polyacrylate resin has a weight per epoxide value of 300 to 320 grams per equivalent, a viscosity of 800 to 1100 cP at 25°

C., and is present in an amount of 14 wt %, based on the weight of the spray adhesive;

(3) the CTNB modified epoxy resin has a weight per epoxide value of 195 to 210 grams per equivalent and is present in an amount of 22 wt %, based on the weight of the spray adhesive;

(4) the one or more solvents is acetone and is present in an amount of 48 wt %, based on the weight of the spray adhesive; and

(5) the fumed silica is present in an amount of 3 wt %, based on the weight of the spray adhesive.

13. A process of preparing a laminate structure comprising the steps of:

applying the spray adhesive composition of claim 1 to a surface of a first layer of the laminate;

contacting the surface of the first layer to a surface of a second layer of the laminate;

forming a vacuum around the first and second layers;

infusing the first and second layers with a catalyzed epoxy resin; and

curing said catalyzed epoxy resin, causing it to cross-link and structurally integrate with the spray adhesive composition to form a single integrated cured structure.

14. The process of claim 13, wherein the spray adhesive composition is applied to the surface of the first layer of the laminate at a rate from 15 to 50 grams per square meter as measured wet.

15. The process of claim 13, further comprising applying the spray adhesive composition of claim 1 to the surface of the second layer of the laminate prior to contacting the surface of the first layer to the surface of the second layer of the laminate.

16. An improved epoxy resin vacuum infusion process comprising:

applying the spray adhesive composition of claim 1 to a surface of a first layer structure;

contacting the surface of the first layer structure to a surface of a second layer structure;

forming a vacuum around the first and second layer structures;

infusing said first and second layer structures with a catalyzed epoxy resin; and

curing said catalyzed epoxy resin, causing it to cross-link and structurally integrate with the spray adhesive composition to form a single integrated cured structure.

17. The process of claim 16, wherein the spray adhesive composition is applied to the surface of the first layer structure at a rate from 15 to 50 grams per square meter as measured wet.

18. The process of claim 16, further comprising applying the spray adhesive composition of claim 1 to the surface of the second layer structure prior to contacting the surface of the first layer structure to the surface of the second layer structure.