Methods and systems for processing biomass material

• US 9,624,436 B2
• Filed: 05/16/2013
• Issued: 04/18/2017
• Est. Priority Date: 05/17/2012
• Status: Active Grant

• Current Assignee: Shell USA Incorporated (Shell Plc)
• Original Assignee: Shell Oil Company (Shell Plc)
• Inventors: Hamilton, Phillip Guy, Radtke, Corey William, Kreitman, Keith Michael, Weider, Paul Richard, Blackbourn, Robert Lawrence
• Primary Examiner(s): Claytor, Renee
• Assistant Examiner(s): BERKE-SCHLESSEL, DAVID W
• Application Number:
  US13/895,931
• Publication Number:
  US 20130309727A1
• Time in Patent Office: 1,433 Days
• Field of Search: None
• CPC Class Codes: C10G 1/002 in combination with oil conversion- or refining processes
• CPC Class Codes: C10G 1/02 by distillation
• CPC Class Codes: C10G 3/46 in combination with chromium, molybdenum, tungsten metals or compounds thereof
• CPC Class Codes: C10G 3/50 in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
• CPC Class Codes: C12F 3/10 from distillery slops
• CPC Class Codes: C12P 5/00 Preparation of hydrocarbons or halogenated hydrocarbons
• CPC Class Codes: C12P 5/02 acyclic C12P5/007 takes precedence
• CPC Class Codes: C12P 5/026 Unsaturated compounds, i.e. alkenes, alkynes or allenes
• CPC Class Codes: C12P 7/00 Preparation of oxygen-containing organic compounds
• CPC Class Codes: C12P 7/06 Ethanol, i.e. non-beverage
• CPC Class Codes: C12P 7/10 substrate containing cellulosic material
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02E 50/30 Fuel from waste, e.g. synthetic alcohol or diesel
• CPC Class Codes: Y02P 30/20 using bio-feedstock
• CPC Class Codes: Y02T 50/678 Aviation using fuels of non-fossil origin

Abstract

Embodiments of the present invention provide for efficient and economical production and recovery of ethanol or other volatile organic compounds. One embodiment comprises contacting a solid component of a biomass material with a solution adapted to facilitate saccharification. The solid component is generated by a method comprising: introducing a biomass material to a compartment of a solventless recovery system, wherein the biomass material contains one or more volatile organic compounds; contacting the biomass material with a superheated vapor stream in the compartment to vaporize at least a portion of an initial liquid content in the biomass material; separating a vapor component and a solid component from the heated biomass material; and retaining at least a portion of the gas component for use as part of the superheated vapor stream. In one embodiment, the solid component contacted with the solution is further subjected to enzymatic hydrolysis and/or fermentation.

Claims

1. A method for processing a prepared biomass material comprising:

(i) introducing a prepared biomass material to a pressurized compartment of a recovery system, wherein the prepared biomass material contains an initial liquid content comprising ethanol and wherein the prepared biomass material is generated by adding to a lignocellulosic biomass at least one additive selected from the group consisting of a microbe, an acid, an enzyme, or any combination thereof and storing the lignocellulosic biomass material with at least one additive for at least 24 hours;

(ii) contacting the prepared biomass material with a superheated vapor stream in the pressurized compartment to vaporize at least a portion of the initial liquid content in the prepared biomass material to provide a vapor component, wherein the superheated vapor stream is about 100°

C. to about 375°

C., and the recovery system is operated at a pressure range of about 3 psig to about 60 psig;

(iii) retaining an amount of the vapor component comprising ethanol in a range of 1 wt % to 50 wt % for use as part of the superheated vapor stream;

(iv) releasing from the recovery system at least a portion of the prepared biomass material after vaporization to provide a solid component; and

(vi) contacting at least a portion of the solid component with a solution adapted to facilitate saccharification.

2. The method of claim 1 wherein the solution adapted to facilitate saccharification comprises water having a temperature of at least about 170 degrees C.

3. The method of claim 1 wherein the solution adapted to facilitate saccharification comprises an acid solution adapted to hydrolyze at least a portion of the solid component to produce a product comprising a fermentable sugar.

4. The method of claim 3 wherein the acid solution comprises at least one alpha-hydroxysulfonic acid.

5. The method of claim 4 wherein the alpha-hydroxysulfonic acid is present in an amount of from about 1% wt. to about 55% wt., based on the solution.

6. The method of claim 4 wherein the alpha-hydroxysulfonic acid is produced from (a) a carbonyl compound or a precursor to a carbonyl compound with (b) sulfur dioxide or a precursor to sulfur dioxide and (c) water.

7. The method of claim 4 wherein the solid component is contacted with the acid solution at a temperature in a range of about 50 degrees C. to about 150 degrees C. and a pressure within the range of 1 barg to about 10 barg.

8. The method of claim 4 wherein further comprising removing the alpha-hydroxysulfonic acid in its component form from the product by heating and/or reducing pressure to produce an acid-removed product containing at least one fermentable sugar substantially free of the alpha-hydroxysulfonic acid.

9. The method of claim 8 further comprising hydrolyzing and fermenting the acid-removed product to generate a fermented product comprising a plurality of VOCs.

10. The method of claim 1 wherein the lignocellulosic biomass is selected from the group consisting of sorghum, sugar cane, corn, tropical corn, sugar beet, energy cane, and any combination thereof.

11. The method of claim 1 wherein the pressurized compartment comprises a cylindrical body in a shape of a loop within which the superheated vapor stream flows.

12. The method of claim 1 wherein the separating step is achieved using a cyclone separating component coupled to the pressurized compartment, wherein the cyclone separating component is configured to discharge the separated solid component from the pressurized component.

13. The method of claim 1 wherein the biomass has an average size distribution of about 3 mm to about 80 mm.

14. The method of claim 1 further comprises feeding at least a portion of the solid component from the recovery system directly to the contacting step.

15. The method of claim 1 wherein the solid component contacted with the solution adapted to facilitate saccharification is not agitated during at least a portion of the contact.

17. The method of claim 1 wherein the initial liquid content in the biomass material is up to about 80 wt % based on the biomass material.

18. The method of claim 1 wherein the initial liquid content comprises from about 2 wt % to about 50 wt % ethanol based on the initial liquid content.

19. The method of claim 1 wherein at least a portion of the solid component exiting the recovery system has a temperature of less than about 50 degrees C.

21. The method of claim 1 further comprising:

removing less than 100% of the ethanol in the prepared biomass material.

22. The method of claim 1 comprising:

removing in a range of 50% to 90% of the ethanol in the prepared biomass material.

23. The method of claim 1 wherein the superheated vapor stream comprises between about 1 wt % and about 50 wt % ethanol.

24. The method of claim 1 wherein the superheated vapor stream comprises between 4 wt % and about 15 wt % ethanol.

26. The method of claim 1, wherein during steady state operation of the recovery system, the superheated vapor stream consists essentially of the vapor component.

16. A method for processing a prepared biomass material comprising:

contacting a solid component of a prepared biomass material with a solution adapted to facilitate saccharification, wherein the solid component is generated by a method comprising;

introducing the prepared biomass material to a pressurized compartment of a recovery system, wherein the prepared biomass material is generated by adding to a lignocellulosic biomass at least one of a microbe, an acid, and an enzyme; and

storing the lignocellulosic biomass for at least about 24 hours;

contacting the prepared biomass material with a superheated vapor stream in the pressurized compartment to vaporize at least a portion of an initial liquid content in the prepared biomass material to provide a vapor component, wherein the initial liquid content comprises ethanol, and wherein the superheated vapor stream is about 100°

C. to about 375°

C. and the recovery system is operated at a pressure range of about 3 psig to about 60 psig;

retaining in the recovery system an amount of the vapor component comprising ethanol in a range of 1 wt % to 50 wt % for use as part of the superheated vapor stream;

releasing from the recovery system at least a portion of the prepared biomass material after vaporization to provide the solid component for said contact with the solution adapted to facilitate saccharification.

20. The method of claim 16 wherein the lignocellulosic biomass comprises a crop selected from the group consisting of sorghum, sugar cane, corn, tropical corn, sugar beet, energy cane, and any combination thereof.

25. The method of claim 16 wherein the solution adapted to facilitate saccharification comprises an acid solution adapted to hydrolyze at least a portion of the solid component to produce a product comprising a fermentable sugar, wherein the acid solution comprises at least one alpha-hydroxysulfonic acid.

27. The method of claim 16 wherein at least a portion of the solid component exiting the recovery system has a temperature of less than about 50 degrees C.

28. The method of claim 16 wherein the superheated vapor stream comprises between 4 wt % and about 15 wt % ethanol.

29. The method of claim 16, wherein during steady state operation of the recovery system, the superheated vapor stream consists essentially of the vapor component.