System and method for carbon dioxide capture and sequestration utilizing an improved substrate structure

• US 9,630,143 B2
• Filed: 03/03/2015
• Issued: 04/25/2017
• Est. Priority Date: 04/30/2010
• Status: Active Grant

• Current Assignee: Global Thermostat Operations LLC
• Original Assignee: Graciela Chichilnisky
• Inventors: Eisenberger, Peter, Buelow, Mark Thomas, Durilla, Michael, Kauffman, John, Tran, Pascaline
• Primary Examiner(s): Jones, Christopher P
• Application Number:
  US14/636,906
• Publication Number:
  US 20150273432A1
• Time in Patent Office: 784 Days
• CPC Class Codes: B01D 2251/304 of sodium
• CPC Class Codes: B01D 2251/604 Hydroxides
• CPC Class Codes: B01D 2252/204 Amines
• CPC Class Codes: B01D 2253/104 Alumina
• CPC Class Codes: B01D 2253/106 Silica or silicates
• CPC Class Codes: B01D 2253/20 Organic adsorbents
• CPC Class Codes: B01D 2253/25 Coated, impregnated or composite adsorbents
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2258/06 Polluted air
• CPC Class Codes: B01D 2259/4009 using hot gas
• CPC Class Codes: B01D 53/04 with stationary adsorbents B01D53/025 takes precedence
• CPC Class Codes: B01D 53/0462 Temperature swing adsorption
• CPC Class Codes: B01D 53/08 according to the "moving bed" method
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: B01D 53/81 Solid phase processes
• CPC Class Codes: B01D 53/82 with stationary reactants
• CPC Class Codes: B01D 53/83 with moving reactants
• CPC Class Codes: B01D 53/96 Regeneration, reactivation or recycling of reactants
• CPC Class Codes: B01J 20/08 comprising aluminium oxide or hydroxide; comprising bauxite
• CPC Class Codes: B01J 20/103 comprising silica
• CPC Class Codes: B01J 20/22 : comprising organic material
• CPC Class Codes: B01J 20/262 : obtained otherwise than by reactions only involving carbon to carbon unsaturated bonds, e.g. obtained by polycondensation macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds per se C08G
• CPC Class Codes: B01J 20/28016 : Particle form
• CPC Class Codes: B01J 20/28042 : Shaped bodies; Monolithic structures
• CPC Class Codes: B01J 20/28097 : being coated, filled or plugged with specific compounds
• CPC Class Codes: B01J 20/3425 : of sorbents or filter aids comprising organic materials
• CPC Class Codes: B01J 20/3466 : with steam
• CPC Class Codes: F01N 3/0857 : Carbon oxides
• CPC Class Codes: Y02A 50/20 : Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
• CPC Class Codes: Y02C 20/40 : of CO2
• CPC Class Codes: Y02P 20/151 : Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Abstract

A structure and system for the adsorption of carbon dioxide from air, the system comprising a sorbent structure comprising a porous substrate having a porous alumina coating on the surfaces of said substrate, and the sorbent for carbon dioxide is embedded on the surfaces of said porous alumina coating. The substrate is preferably a porous monolith, formed from silica or mesocellular foam. The sorbent is an amine group-containing material, preferably loaded at 40 to 60 percent by volume relative to the porous alumina coating.

Claims

1. A system for the adsorption of carbon dioxide from air, the system comprising a carbon dioxide capture structure exposed to a moving flow of ambient air;

the carbon dioxide capture structure comprising a porous silica substrate having an alumina coating on the surfaces of said substrate and on the surface of the alumina coating is supported an amine sorbent, which is capable of binding carbon dioxide from the moving flow of ambient air;

the porous silica substrate being a monolith having a plurality of channels passing between opposing surfaces of the monolith to allow the passage of air entering one end of the channel to exit at an opposite end of a channel, the alumina coating the internal surfaces of the channels;

a regeneration enclosure, capable of enclosing the carbon dioxide capture structure; and

process steam-directing apparatus in fluid flow connection with the regeneration enclosure, for separating the carbon dioxide from the sorbent and regenerating the sorbent, said process steam being at a temperature of not greater than about 120°

C., where the porous silica substrate is comprised of a silica or a mesocellular silica foam.

2. A sorbent structure comprising a substrate comprising a base structure formed of a monolithic porous silica or a mesocellular silica foam and a porous alumina coating on the surfaces of said silica substrate;

and

an amine sorbent embedded on said alumina coating;

the porous silica substrate being a monolith having a plurality of channels passing between opposing surfaces of the monolith to allow the passage of air entering one end of the channel to exit at an opposite end of a channel, the alumina coating the internal surfaces of the channels.

3. The sorbent structure of claim 2 wherein said silica substrate is a pancake-shaped monolith.

4. The sorbent structure of claim 2 wherein said amine sorbent is a poly(primary amine-substituted ethylene) group-containing material.

5. The sorbent structure of claim 4 wherein said poly(primary amine-substituted ethylene-group containing material is loaded at 40 to 60 percent by volume relative to the alumina coating.

6. The sorbent structure of claim 2, wherein the base structure is a pancake-shaped monolith formed of cordierite and having straight macro channels extending through the monolith.

7. The sorbent structure of claim 2, wherein the substrate comprises a silica porous monolith having straight macro channels extending through the monolith, and having the interior walls of the channels coated with a porous alumina coating.

8. A system for removing carbon dioxide from carbon dioxide laden air, the system comprising:

a carbon dioxide capture structure comprising a porous solid mass having a high surface area and formed of a porous silica substrate, with a porous alumina coating on the surfaces of said silica substrate, and an amine sorbent, that is capable of reversibly adsorbing, or binding, to carbon dioxide, supported on and distributed along the surface area of the porous alumina coating;

the porous silica substrate being a monolith wherein the length in one dimension is not greater than about 20 inches, and having channels passing the full length through the one dimension of the monolith and each of the two surfaces at each end of the one dimension to allow the passage of air entering one end of the channel to exit at an opposite end of a channel;

an air conduit, open at one end to the atmosphere and at a second end to the capture structure, for bringing a flow of carbon dioxide-laden ambient air to and through the carbon dioxide capture structure,

a sealable regeneration chamber capable of containing the capture structure;

an elevator structure for supporting and for moving the capture structure between a position exposed to the ambient air and a position sealed within the sealable regeneration chamber;

exhaust pump means in fluid flow connection with the sealable regeneration chamber to exhaust any atmosphere in the sealable regeneration chamber after the capture structure has been sealed into the sealable regeneration chamber;

a source of process heat steam for providing steam at a temperature of not greater than 120°

C.;

a valved hot fluid conduit connected between the source of process heat steam and the sealable regeneration chamber for directing such process heat steam at the carbon dioxide-loaded sorbent on the capture structure when the capture structure is located in the sealable regeneration chamber, to strip carbon dioxide from the sorbent;

a fluid conduit for carrying the stripped carbon dioxide away from the regeneration chamber; and

a collection chamber connected with the fluid conduit for collecting and holding the stripped carbon dioxide from the fluid conduit.