Method of manufacturing bulked continuous filament

• US 9,630,354 B2
• Filed: 11/18/2014
• Issued: 04/25/2017
• Est. Priority Date: 05/31/2012
• Status: Active Grant

• Current Assignee: Aladdin Manufacturing Corporation (Mohawk Industries Incorporated)
• Original Assignee: Mohawk Industries Incorporated
• Inventors: Clark, Thomas R.
• Primary Examiner(s): Tentoni, Leo B
• Application Number:
  US14/546,837
• Publication Number:
  US 20150076725A1
• Time in Patent Office: 889 Days
• Field of Search: 264 401, 264101, 264102, 264140, 264169, 2641761, 26421121, 26421122, 26421123
• CPC Class Codes: B29B 17/0026 by agglomeration or compacting
• CPC Class Codes: B29B 17/02 Separating plastics from other materials
• CPC Class Codes: B29B 2017/0279 Optical identification, e.g. cameras or spectroscopy
• CPC Class Codes: B29B 7/426 with consecutive casings or screws, e.g. for charging, discharging, mixing
• CPC Class Codes: B29B 7/485 with three or more shafts provided with screws
• CPC Class Codes: B29B 7/487 with consecutive casings or screws, e.g. for feeding, discharging, mixing
• CPC Class Codes: B29B 7/7461 Combinations of dissimilar mixers
• CPC Class Codes: B29B 7/748 Plants B29B7/7433, B29B7/7485, B29B7/7495 take precedence
• CPC Class Codes: B29B 7/7485 with consecutive mixers, e.g. with premixing some of the components
• CPC Class Codes: B29C 2948/92514 Pressure
• CPC Class Codes: B29C 48/022 characterised by the choice of material
• CPC Class Codes: B29C 48/05 Filamentary, e.g. strands
• CPC Class Codes: B29C 48/277 of materials
• CPC Class Codes: B29C 48/38 using two or more serially arranged screws in the same barrel
• CPC Class Codes: B29C 48/385 using two or more serially arranged screws in separate barrels
• CPC Class Codes: B29C 48/40 using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
• CPC Class Codes: B29C 48/43 Ring extruders
• CPC Class Codes: B29C 48/435 Sub-screws
• CPC Class Codes: B29C 48/92 Measuring, controlling or regulating
• CPC Class Codes: B29D 99/0078 Producing filamentary materials
• CPC Class Codes: B29K 2023/065 : HDPE, i.e. high density polyethylene
• CPC Class Codes: B29K 2023/12 : PP, i.e. polypropylene
• CPC Class Codes: B29K 2025/04 : Polymers of styrene
• CPC Class Codes: B29K 2025/06 : PS, i.e. polystyrene
• CPC Class Codes: B29K 2067/00 : Use of polyesters or derivatives thereof, as moulding material
• CPC Class Codes: B29K 2067/003 : PET, i.e. poylethylene terephthalate
• CPC Class Codes: C08J 11/04 : of polymers
• CPC Class Codes: C08J 2367/02 : Polyesters derived from dicarboxylic acids and dihydroxy compounds; C08J2367/06 takes precedence
• CPC Class Codes: D01D 1/103 : De-aerating
• CPC Class Codes: D01D 1/106 : Filtering
• CPC Class Codes: D01F 6/62 : from polyesters
• CPC Class Codes: Y02P 70/10 : Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working
• CPC Class Codes: Y02W 30/62 : Plastics recycling; Rubber recycling

Abstract

A method of recycling polymers and other plastics comprises: (A) grinding recycled PET bottles (or other suitable recycled polymer) into a group of flakes; (B) washing the flakes; (C) identifying and removing impurities, including impure flakes, from the group of flakes; (D) passing the group of flakes through an MRS extruder while maintaining the pressure within the MRS portion of the MRS extruder below about 5 millibars; (E) passing the resulting polymer melt through at least one filter having a micron rating of less than about 50 microns; and (F) preparing the polymer melt for recycling into a new product. In various embodiments, the above process may be utilized in the recycling of, for example, polytrimethylene terephthalate (PTT), polypropylene, polyvinyl chloride (PVC), high-density polyethylene (HDPE), polystyrene (PS), expanded polystyrene (EPS), or any other suitable polymer or plastic.

Claims

1. A method of preparing recycled polymer for use in the production of one or more new products, said method comprising:

(A) providing a crystallizer;

(B) passing recycled polymer through said crystallizer to at least partially dry a surface of said recycled polymer;

(C) providing a multi-screw extruder that comprises;

(i) a first satellite screw extruder, said first satellite screw extruder comprising a first satellite screw that is mounted to rotate about a central axis of said first satellite screw;

(ii) a second satellite screw extruder, said second satellite screw extruder comprising a second satellite screw that is mounted to rotate about a central axis of said second satellite screw;

(iii) a third satellite screw extruder, said third satellite screw extruder comprising a third satellite screw that is mounted to rotate about a central axis of said third satellite screw;

(iv) a fourth satellite screw extruder, said fourth satellite screw extruder comprising a fourth satellite screw that is mounted to rotate about a central axis of said fourth satellite screw, wherein said first satellite screw, said second satellite screw, said third satellite screw, and said fourth satellite screw are disposed at least partially within respective extruder barrels;

(v) a satellite screw extruder support system that is adapted to rotate said first, second, third, and fourth satellite screws about a main axis while said first, second, third and fourth satellite screws are rotating about their respective central axes, said main axis being substantially parallel to;

(a) said central axis of said first satellite screw;

(b) said central axis of said second satellite screw;

(c) said central axis of said third satellite screw; and

(d) said central axis of said fourth satellite screw; and

(vi) a pressure regulation system that is adapted to maintain a pressure within said first, second, third, and fourth satellite screw extruders between about 0 millibars and about 5 millibars;

(D) using said pressure regulation system to reduce a pressure within said first, second, third, and fourth satellite screw extruders to between about 0 millibars and about 5 millibars;

(E) after passing said recycled polymer through said crystallizer, while maintaining said pressure within said first, second, third, and fourth satellite screw extruders between about 0 millibars and about 5 millibars, passing a melt comprising said recycled polymer through said multi-screw extruder so that;

(1) a first portion of said melt passes through said first satellite screw extruder, (2) a second portion of said melt passes through said second satellite screw extruder, (3) a third portion of said melt passes through said third satellite screw extruder, and (4) a fourth portion of said melt passes through said fourth satellite screw extruder; and

(F) after said step of passing said melt of recycled polymer through said multi-screw extruder, preparing said polymer melt for use in production of one or more new products.

2. The method of claim 1, wherein said recycled polymer is selected from the group consisting of:

i. polyvinyl chloride;

ii. high-density polyethylene;

iii. polystyrene;

iv. expanded polystyrene; and

v. polytrimethylene terephthalate.

3. The method of claim 1, wherein said step of passing said melt of recycled polymer through said multi-screw extruder occurs while said first, second, third, and fourth satellite screw extruders are orbitally rotating about said main axis.

4. The method of claim 3, wherein said recycled polymer consists essentially of recycled polyvinyl chloride.

5. The method of claim 3, wherein said recycled polymer consists essentially of recycled high-density polyethylene.

6. The method of claim 3, wherein said recycled polymer consists essentially of recycled polystyrene.

7. The method of claim 3, wherein said recycled polymer consists essentially of recycled expanded polystyrene.

8. The method of claim 3, wherein said recycled polymer consists essentially of recycled polytrimethylene terephthalate.

9. A method of recycling polymer products, said method comprising:

(A) grinding a plurality of recycled polymer products into a group of polymer flakes;

(B) washing said group of polymer flakes to remove at least a portion of one or more contaminants from a surface of said flakes, said group of flakes comprising a first plurality of flakes that consist essentially of the recycled polymer and a second plurality of flakes that do not consist essentially of said recycled polymer;

(C) after said step of washing said first plurality of flakes;

(i) scanning said washed group of flakes to identify said second plurality of flakes,

(ii) separating said second plurality of flakes from said first plurality of flakes;

(D) providing a crystallizer;

(E) passing said first plurality of flakes through said crystallizer to at least partially dry a surface of said first plurality of flakes;

(F) melting said first plurality of flakes to produce a polymer melt;

(G) providing an extruder that extrudes material in a plurality of different extrusion streams, said extruder comprising;

at least four satellite screws wherein each respective satellite screw of said at least four satellite screws is mounted to rotate about its respective central axis; and

a single screw drum mounted to rotate about its central axis, wherein;

said central axis of said single screw drum is parallel to each respective central axis of said at least four satellite screws;

said at least four satellite screws are arranged within said single screw drum and at least partially housed within respective extruder barrels; and

each of said at least four satellite screws is configured to rotate about its said respective axis while said single screw drum rotates about said central axis of said single screw drum;

(H) providing at least one vacuum pump configured to reduce a pressure within said extruder between about 0 millibars and about 12 millibars;

(I) reducing a pressure within said extruder to between about 0 millibars and about 12 millibars;

(J) while maintaining said pressure within said extruder between about 0 millibars and about 12 millibars, passing said polymer melt through said extruder so that said polymer melt is divided into a plurality of extrusion streams so that at least a portion of said polymer melt passes through each of said at least four satellite screws, each having a pressure between about 0 millibars and about 12 millibars;

(K) after passing said polymer melt through said extruder, filtering said polymer melt through at least one filter; and

L) after passing said polymer melt through said filter, preparing said polymer melt for use in production of one or more new products.

10. The method of claim 9, wherein reducing said pressure within said extruder to between about 0 millibars and about 12 millibars comprises reducing said pressure within said extruder to about a particular pressure based at least in part on a type of said recycled polymer.

11. The method of claim 10 wherein said recycled polymer is selected from the group consisting of:

i. polypropylene;

ii. high-density polyethylene;

iii. polystyrene;

iv. expanded polystyrene; and

v. polytrimethylene terephthalate.

12. A method of recycling polytrimethylene terephthalate, said method comprising:

(A) providing a crystallizer;

(B) passing a plurality of flakes consisting essentially of recycled polytrimethylene terephthalate through said crystallizer to at least partially dry a surface of said plurality of flakes of recycled polytrimethylene terephthalate;

(C) providing a multi-screw extruder that comprises;

(i) a first satellite screw extruder, said first satellite screw extruder comprising a first satellite screw that is mounted to rotate about a central axis of said first satellite screw;

(ii) a second satellite screw extruder, said second satellite screw extruder comprising a second satellite screw that is mounted to rotate about a central axis of said second satellite screw;

(iii) a third satellite screw extruder, said third satellite screw extruder comprising a third satellite screw that is mounted to rotate about a central axis of said third satellite screw;

(iv) a fourth satellite screw extruder, said fourth satellite screw extruder comprising a fourth satellite screw that is mounted to rotate about a central axis of said fourth satellite screw;

(v) a single screw drum mounted to rotate about its central axis, wherein;

said central axis of said single screw drum is parallel to each respective central axis of said first satellite screw, said second satellite screw, said third satellite screw, and said fourth satellite screw;

said first satellite screw, said second satellite screw, said third satellite screw, and said fourth satellite screw are arranged within said single screw drum and at least partially housed within respective extruder barrels; and

each of said first satellite screw, said second satellite screw, said third satellite screw, and said fourth satellite screw is configured to rotate about its said respective central axis while said single screw drum rotates about said central axis of said single screw drum; and

(vi) a pressure regulation system that is adapted to maintain a pressure within said first, second, third, and fourth satellite screw extruders between about 0 millibars and about 18 millibars;

(D) using said pressure regulation system to reduce a pressure within said first, second, third, and fourth satellite screw extruders to between about 0 millibars and about 18 millibars;

(E) after passing said plurality of flakes consisting essentially of recycled polytrimethylene terephthalate through said crystallizer, while maintaining said pressure within said first, second, third, and fourth satellite screw extruders between about 0 millibars and about 18 millibars, passing said plurality of flakes consisting essentially of recycled polytrimethylene terephthalate through said multi-screw extruder to at least partially melts said plurality of flakes consisting essentially of recycled polytrimethylene terephthalate to for a melt of recycled polytrimethylene terephthalate so that;

(1) a first portion of said melt passes through said first satellite screw extruder, (2) a second portion of said melt passes through said second satellite screw extruder, (3) a third portion of said melt passes through said third satellite screw extruder, and (4) a fourth portion of said melt passes through said fourth satellite screw extruder; and

(F) after said step of passing said melt of recycled polytrimethylene terephthalate through said multi-screw extruder, preparing said polymer melt for use in production of one or more new products.

13. The method of claim 12, wherein preparing said polymer melt for use in production of one or more new products comprises spinning said polymer melt into polytrimethylene terephthalate fiber.

14. The method of claim 12, further comprising forming said polymer melt into bulked continuous carpet filament.

15. The method of claim 12, wherein said method further comprises:

using said pressure regulation system to reduce said pressure within said first, second, third, and fourth satellite screw extruders to between about 0 millibars and about 12 millibars; and

while maintaining said pressure within said first, second, third, and fourth satellite screw extruders between about 0 millibars and about 12 millibars, passing said melt comprising recycled polytrimethylene terephthalate through said multi-screw extruder so that;

(1) a first portion of said melt passes through said first satellite screw extruder, (2) a second portion of said melt passes through said second satellite screw extruder, (3) a third portion of said melt passes through said third satellite screw extruder, and (4) a fourth portion of said melt passes through said fourth satellite screw extruder.

16. The method of claim 15, wherein said method further comprises:

using said pressure regulation system to reduce said pressure within said first, second, third, and fourth satellite screw extruders to between about 0 millibars and about 5 millibars; and

while maintaining said pressure within said first, second, third, and fourth satellite screw extruders between about 0 millibars and about 5 millibars, passing said melt comprising recycled polytrimethylene terephthalate through said multi-screw extruder so that;

(1) a first portion of said melt passes through said first satellite screw extruder, (2) a second portion of said melt passes through said second satellite screw extruder, (3) a third portion of said melt passes through said third satellite screw extruder, and (4) a fourth portion of said melt passes through said fourth satellite screw extruder.

17. The method of claim 12, wherein:

said multi-screw extruder further comprises;

(i) a fifth satellite screw extruder, said fifth satellite screw extruder comprising a fifth satellite screw that is mounted to rotate about a central axis of said fifth satellite screw; and

(ii) a sixth satellite screw extruder, said sixth satellite screw extruder comprising a sixth satellite screw that is mounted to rotate about a central axis of said sixth satellite screw; and

said method further comprises;

using said pressure regulation system to reduce a pressure within said fifth and sixth satellite screw extruders to between about 0 millibars and about 18 millibars; and

while maintaining said pressure within said first, second, third, fourth, fifth, and sixth satellite screw extruders between about 0 millibars and about 18 millibars, passing said melt comprising recycled polytrimethylene terephthalate through said multi-screw extruder so that;

(1) a first portion of said melt passes through said first satellite screw extruder, (2) a second portion of said melt passes through said second satellite screw extruder, (3) a third portion of said melt passes through said third satellite screw extruder, (4) a fourth portion of said melt passes through said fourth satellite screw extruder, (5) a fifth portion of said melt passes through said fifth satellite screw extruder, and (6) a sixth portion of said melt passes through said sixth satellite screw extruder.

18. The method of claim 17, wherein said method further comprises:

using said pressure regulation system to reduce said pressure within said first, second, third, fourth, fifth, and sixth satellite screw extruders to between about 0 millibars and about 12 millibars; and

while maintaining said pressure within said first, second, third, fourth, fifth, and sixth satellite screw extruders between about 0 millibars and about 12 millibars, passing said melt comprising recycled polytrimethylene terephthalate through said multi-screw extruder so that;

(1) a first portion of said melt passes through said first satellite screw extruder, (2) a second portion of said melt passes through said second satellite screw extruder, (3) a third portion of said melt passes through said third satellite screw extruder, (4) a fourth portion of said melt passes through said fourth satellite screw extruder, (5) a fifth portion of said melt passes through said fifth satellite screw extruder, and (6) a sixth portion of said melt passes through said sixth satellite screw extruder.

19. The method of claim 18, wherein said method further comprises:

using said pressure regulation system to reduce said pressure within said first, second, third, fourth, fifth, and sixth satellite screw extruders to between about 0 millibars and about 5 millibars; and

while maintaining said pressure within said first, second, third, fourth, fifth, and sixth satellite screw extruders between about 0 millibars and about 5 millibars, passing said melt comprising recycled polytrimethylene terephthalate through said multi-screw extruder so that;

(1) a first portion of said melt passes through said first satellite screw extruder, (2) a second portion of said melt passes through said second satellite screw extruder, (3) a third portion of said melt passes through said third satellite screw extruder, (4) a fourth portion of said melt passes through said fourth satellite screw extruder, (5) a fifth portion of said melt passes through said fifth satellite screw extruder, and (6) a sixth portion of said melt passes through said sixth satellite screw extruder.