Pressure-sensitive adhesive material particularly for encasing an electronic arrangement

• US 9,631,127 B2
• Filed: 07/04/2013
• Issued: 04/25/2017
• Est. Priority Date: 08/24/2012
• Status: Active Grant

• Current Assignee: Tesa SE (maxingvest GmbH & Co. KGaA)
• Original Assignee: Tesa SE (maxingvest GmbH & Co. KGaA)
• Inventors: Keite-Telgenbscher, Klaus, Ellinger, Jan
• Primary Examiner(s): Nutter, Nathan M
• Application Number:
  US14/422,203
• Publication Number:
  US 20150240134A1
• Time in Patent Office: 1,391 Days
• CPC Class Codes: C08K 11/00 Use of ingredients of unknown constitution, e.g. undefined reaction products
• CPC Class Codes: C08K 2003/222 Magnesia, i.e. magnesium oxide
• CPC Class Codes: C08K 3/22 of metals
• CPC Class Codes: C08L 27/16 Homopolymers or copolymers or vinylidene fluoride
• CPC Class Codes: C09J 127/12 containing fluorine atoms
• CPC Class Codes: C09J 127/16 Homopolymers or copolymers of vinylidene fluoride
• CPC Class Codes: H01L 2924/00 Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
• CPC Class Codes: H01L 2924/0002 Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
• CPC Class Codes: H05K 5/065 sealed by encapsulation, e.g. waterproof resin forming an integral casing, injection moulding
• CPC Class Codes: H10K 50/844 Encapsulations
• CPC Class Codes: H10K 59/873 Encapsulations

Abstract

Pressure-sensitive adhesive material for encasing an electronic arrangement to prevent permeate, which material comprises at least 70 percent by weight of a mixture of at least one fluorine-containing thermoplastic elastomer and at least one fluorine-containing liquid elastomer, wherein the mass ratio of the fluorine-containing liquid elastomer to the fluorine-containing thermoplastic elastomer is between 5:95 to 55:45.

Claims

1. A pressure-sensitive adhesive for encapsulating an electronic arrangement with respect to permeants, comprising to an extent of at least 70 wt. % based on the overall composition of the pressure-sensitive adhesive, a mixture of at least one fluorine-containing thermoplastic elastomer and at least one fluorine-containing liquid elastomer, the mass ratio of the fluorine-containing liquid elastomer to the fluorine-containing thermoplastic elastomer being between 5:

95 to 55;

45.

2. The pressure-sensitive adhesive (PSA) of claim 1, wherein the mass ratio of the fluorine-containing liquid elastomer to the fluorine-containing thermoplastic elastomer is between 15:

75 and 50;

50.

3. The pressure-sensitive adhesive of claim 1, wherein the fluorine-containing thermoplastic elastomer or elastomers are selected, individually or in any combination, from the group consisting of

a fluorine-containing elastomer having at least one soft segment, consisting of a terpolymer of vinylidene fluoride/hexafluoropropylene/tetrafluoroethylene or vinylidene fluoride/chlorotrifluoroethylene/tetrafluoroethylene, and at least one hard segment, consisting of a copolymer of tetrafluoroethylene/ethylene or chlorotrifluoroethylene/ethylene or polyvinylidene fluoride,

a fluorine-containing elastomer having at least one soft segment composed of a copolymer of tetrafluoroethylene/propylene and at least one hard segment composed of a copolymer of tetrafluoroethylene/ethylene, and

a fluorine-containing elastomer having at least one soft segment composed of an amorphous rubberlike copolymer of tetrafluoroethylene/perfluoroalkyl vinyl ether and at least one hard segment composed of a copolymer of tetrafluoroethylene/perfluoroalkyl vinyl ether in which the amount of perfluoroalkyl vinyl ether is less than in the soft segment.

4. The pressure-sensitive adhesive of claim 1, wherein the thermoplastic fluorine-containing elastomer is compatible with the fluorine-containing liquid elastomer.

5. The pressure-sensitive adhesive of claim 3, wherein the monomer composition of the soft segment of the thermoplastic elastomer or the monomer composition of the fluorine-containing copolymer or terpolymer is selected to be similar to the monomer composition of the liquid elastomer.

6. The pressure-sensitive adhesive of claim 3, wherein the PSA comprises the combination of a fluorine-containing liquid elastomer composed of vinylidene fluoride, hexafluoropropylene, and tetrafluoroethylene and of a fluorine-containing thermoplastic elastomer which comprises a soft segment composed of the same terpolymer as the liquid elastomer, or the combination of a fluorine-containing liquid elastomer which is a tetrafluoroethylene/propylene copolymer or a tetrafluoroethylene/perfluoropropyl vinyl ether copolymer, and of a fluorine-containing thermoplastic elastomer having a soft segment composed of the same copolymer as the liquid elastomer.

7. The pressure-sensitive adhesive of claim 3, wherein fluorine-containing liquid elastomers used are elastomers based on vinylidene fluoride/hexafluoropropylene, on vinylidene fluoride/hexafluoropropylene/tetrafluoroethylene, on tetrafluoroethylene/propylene, on hexafluoropropylene/ethylene, fluorosilicone elastomers and/or fluorine-substituted phosphazene elastomers.

8. The pressure-sensitive adhesive of claim 1, wherein the liquid elastomer has a number-average molecular weight M_n of 500 to 20 000.

9. The pressure-sensitive adhesive of claim 1, wherein the pressure-sensitive adhesive is crosslinked.

10. The pressure-sensitive adhesive of claim 1, wherein the pressure-sensitive adhesive comprises one or more additives selected from the group consisting of plasticizers, primary antioxidants, secondary antioxidants, process stabilizers, light stabilizers, processing assistants, endblock reinforcer resins and elastomeric polymers.

11. The pressure-sensitive adhesive of claim 1, wherein the pressure-sensitive adhesive comprises one or more fillers.

12. The pressure-sensitive adhesive of claim 1, wherein the pressure-sensitive adhesive is transparent in the visible light of the spectrum.

13. The pressure-sensitive adhesive of claim 1, wherein the pressure-sensitive adhesive exhibits a haze of less than 5.0%.

16. The adhesive of claim 1, wherein the adhesive comprises at least one resin which has a DACP of more than 30°

C. and an MMAP of more than 50°

C.

17. The pressure-sensitive adhesive of claim 1, wherein the pressure-sensitive adhesive comprises at least one resin which has a DACP of less than 20°

C. and an MMAP of less than 0°

C.

14. An adhesive for encapsulating an electronic arrangement with respect to permeants, which comprises a mixture of at least one fluorine-containing thermoplastic elastomer and at least one fluorine-containing liquid elastomer and also at least one tackifier resin, the adhesive comprising this mixture to an extent of at least 70 wt. %, based on the overall composition of the adhesive.

15. The adhesive of claim 14, wherein the mass ratio of the fluorine-containing liquid elastomer to the fluorine-containing thermoplastic elastomer is between 5:

95 to 55;

45.