Potentiostat/galvanostat with digital interface

• US 9,632,059 B2
• Filed: 09/03/2015
• Issued: 04/25/2017
• Est. Priority Date: 09/03/2015
• Status: Active Grant

• Current Assignee: Ashwin-Ushas Corporation, Inc.
• Original Assignee: Ashwin-Ushas Corporation, Inc.
• Inventors: Chandrasekhar, Prasanna, Chai, Yanjie
• Primary Examiner(s): Kaur, Gurpreet
• Application Number:
  US14/844,367
• Publication Number:
  US 20170067848A1
• Time in Patent Office: 600 Days
• CPC Class Codes: G01N 27/416 Systems G01N27/27 takes precedence
• CPC Class Codes: G01N 27/4163 checking the operation of, or calibrating, the measuring apparatus G01N27/3274, G01N27/4175 and G01N33/0006 take precedence

Abstract

A potentiostat/galvanostat employs a controller for providing digital control signals to a digital-to-analog converter (DAC) that generates an analog output signal in response to digital control signals. A high current driver produces a high current output in response to the analog output signal from the DAC. A high current monitor monitors the output from the high current driver to produce a feedback signal for the high current driver to control the current produced by the high current driver and to produce an output dependent on the current supplied from the high current driver for monitoring by the controller. A counter electrode contact for a counter electrode is connected with the output of the high current monitor. A working electrode contact for a working electrode is electrically connected with a fixed stable voltage potential to enable electrochemical analysis of material between the counter electrode and the working electrode. A low current driver produces a low current range output in response to an analog output signal from the DAC. A low current monitor monitors the working electrode contact to detect current at the working electrode contact to supply an output dependent on the current detected for monitoring by the controller and for providing a feedback signal to the low current driver in order to control the output of the low current driver to control current between the counter electrode contact and the working electrode contact.

Claims

1. An electrochemical instrument comprising:

a. a controller for providing digital control signals;

b. a digital-to-analog converter (DAC) in electrical communication with the controller for generating an analog output signal in response to digital control signals from the controller;

c. a high current driver in electrical communication with the DAC to produce a high current range output in response to the analog output signal from the DAC;

d. a high current monitor in electrical communication with the high current driver, the high current monitor producing a current feedback signal for the high current driver in response to the current monitored by the high current monitor to control the current produced by the high current driver and for supplying an output dependent on the current produced from the high current driver for monitoring by the controller;

e. a counter electrode contact for electrical communication with a counter electrode and connectable in electrical communication with the output of the high current monitor; and

f. a working electrode contact for electrical communication with a working electrode connectable in electrical communication with a fixed stable voltage potential for enabling electrochemical analysis of material between the counter electrode and the working electrode, wherein the high current monitor includes a first high current range monitoring circuit for monitoring current in a first current range and a second high current monitoring circuit for monitoring current in a second current range.

2. The instrument of claim 1 wherein the high current monitor includes a first high current range monitoring circuit for monitoring current in a first current range and a second high current monitoring circuit for monitoring current in a second current range and a first high current monitor switch for electrically connecting the first high current range monitoring circuit in and out of electrical communication with the counter electrode contact and a second high current monitoring switch for electrically connecting the second high current monitoring circuit in and out of electrical communication with the counter electrode contact.

3. The instrument of claim 1 including a reference electrode contact for electrical communication with a reference electrode for positioning relative to the working electrode and the counter electrode in communication with the material, and a buffer for electrical communication with the reference electrode contact for detecting voltage at the reference electrode contact and for supplying an output dependent on the voltage at the reference electrode contact buffered from the reference electrode contact for monitoring by the controller and for providing a feedback signal for the high current driver to control the output produced by the high current driver to control the voltage at the reference electrode contact.

4. The instrument of claim 3 including a feedback analog multiplexer in electrical communication with the controller and in electrical communication with the high current monitor for receiving the feedback signal from the high current monitor and the buffer for receiving the feedback signal from the buffer for switchably selecting which of the feedback signals is output by the feedback analog multiplexer for the high current driver under the control of the controller.

5. The instrument of claim 4 wherein the controller controls the feedback analog multiplexer to supply the feedback signal from the high current monitor for the high current driver when operating in high current mode, and to supply the feedback signal from the buffer to the high current driver when operating in voltage mode.

6. The instrument of claim 4 wherein the high current monitor includes a first high current range monitoring circuit for monitoring current in a first current range and a second high current range monitoring circuit for monitoring current in a second current range wherein the first high current range monitoring circuit provides a first high current feedback signal for the feedback analog multiplexer and the second high current range monitoring circuit provides a second high current feedback signal for the feedback analog multiplexer, and wherein the feedback analog multiplexer under control of the controller selectively supplies the first high current feedback signal from the first high current range monitoring circuit for the high current driver when operating in the first high current range and selectively supplies the second high current feedback signal from the second high current range monitoring circuit for the high current driver when operating in the second high current range.

7. The instrument of claim 6 wherein the first high current range monitoring circuit includes a first sense resistor connected in series between the high current driver and the counter electrode contact and a first differential amplifier connected across the first sense resistor to detect the voltage generated by current flow through the first sense resistor to produce the first high current feedback signal, and wherein the second high current range monitoring circuit includes a second sense resistor connected in series between the high current driver and the counter electrode contact and a second differential amplifier connected across the second sense resistor to detect the voltage generated by the current flow through the second sense resistor to produce the second high current feedback signal.

8. The instrument of claim 7 wherein the first and second differential amplifiers include an instrumentation amplifier.

9. The instrument of claim 3 including an analog-to-digital converter (ADC) in electrical communication with the controller and in electrical communication with the outputs of the buffer and the high current monitor to convert the output signals of the buffer and the high current monitor to a digital signal for supply to the controller.

10. The instrument of claim 1 including a high current switch for switchably connecting the high current driver in and out of electrical communication with the counter electrode contact, such that the controller controls the high current switch to switchably connect and disconnect the high current driver in and out of electrical communication with the counter electrode contact.