Methods for expanding and enriching hydrocarbon diluent pools

• US 9,637,685 B2
• Filed: 04/30/2013
• Issued: 05/02/2017
• Est. Priority Date: 05/10/2012
• Status: Active Grant

• Current Assignee: Texon LP
• Original Assignee: Texon LP
• Inventors: Mattingly, Larry D., Andrews, Ronnie D.
• Primary Examiner(s): Boyer, Randy
• Application Number:
  US13/873,506
• Publication Number:
  US 20130303809A1
• Time in Patent Office: 1,463 Days
• CPC Class Codes: C10C 3/005 by mixing several fractions (also coaltar fractions with petroleum fractions)
• CPC Class Codes: C10G 1/00 Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal mechanical winning of oil from oil-shales, oil-sand, or the like B03B
• CPC Class Codes: C10G 2300/802 Diluents
• CPC Class Codes: G05D 21/02 characterised by the use of electric means

Abstract

The invention provides a method for enriching diluents with butane so as not to violate pre-defined limits for liquid hydrocarbon fuels with respect to density, volatility and low density hydrocarbon content.

Claims

1. A method for the controlled production and distribution of LDH enriched diluents so as not to violate pre-defined limits selected from LDH content, volatility, density, and combinations thereof comprising:

a) providing a diluent stream having a flow rate, a line pressure, a LDH content, a volatility and a density;

b) providing a variable rate LDH injection unit in fluid connection with said diluent stream;

c) optionally providing a diluent/petroleum mixing unit in fluid connection with said LDH injection unit and said diluent stream;

d) obtaining values for one or more parameters of said diluent stream selected from LDH content, volatility, density, and combinations thereof;

e) calculating a target rate of injecting LDH into said diluent stream based upon the one or more parameter values in step (d) so as not to violate the foregoing pre-defined limits;

f) injecting LDH into the diluent stream from the LDH injection unit at a pressure greater than said diluent stream pressure, and an actual injection rate less than or equal to said target rate calculated in step (e); and

g) periodically repeating steps (d) and (e) and adjusting the injection rate in step (f) based upon the most recent calculation from step (e),

wherein the API gravity of said diluent stream after said LDH injection step (f) is between 46 and 86, and the LDH content of said diluent stream after said LDH injection step (f) is between 5.0% and 7.0%.

2. The method of claim 1 wherein said pre-defined limits include LDH content and volatility, and said parameter values obtained in step (d) include LDH content, volatility and density.

3. The method of claim 1 wherein said pre-defined limits include density, and said parameter values obtained in step (d) include density.

4. The method of claim 1 wherein said pre-defined limits include LDH content, volatility and density, and said parameter values obtained in step (d) include LDH content, volatility and density.

5. The method of claim 1 wherein said diluent flow rate varies over time, step (d) further comprises obtaining said flow rate, and step (e) is performed based upon the flow rate obtained in step (d).

6. The method of claim 1 wherein:

i) said variable rate LDH injection unit comprises a supply of LDH at a LDH pressure greater than said diluent stream pressure, and an on-off valve and regulating valve between said supply of LDH and said diluent stream, and

ii) said rate adjustment step (g) comprises modulating the orifice size in said regulating valve.

7. The method of claim 1 wherein:

i) said LDH content and volatility are obtained in step (d) upstream of said injection unit; and

ii) said density is obtained in step (d) downstream of said LDH injection unit.

8. The method of claim 1 wherein in step (d):

i) said volatility is obtained by measuring the volatility of said diluent stream;

ii) said LDH content is obtained by measuring the LDH content of said diluent stream; and

iii) said density is obtained by receiving a density measurement from an external source.

9. The method of claim 1 wherein in step (d):

i) said volatility is obtained by measuring the volatility of said diluent stream using a manometer; and

ii) said LDH content is obtained by measuring the LDH content of said diluent stream using liquid chromatography.

10. The method of claim 1 further comprising calculating a resulting LDH content and resulting volatility of said diluent stream downstream of said LDH injection unit based upon said target or actual LDH injection rate in step (f) of claim 1, said diluent flow rate, and said volatility and LDH content of said diluent stream upstream of said LDH injection unit.

11. The method of claim 1 further comprising:

a) providing an informational database on which are stored said pre-defined limits;

b) providing one or more information processing units logically programmed to;

i) receive said parameter values for volatility, LDH content and density of said diluent stream;

ii) calculate said target LDH injection rate based upon said flow rate, volatility, LDH content and density of said diluent stream and said pre-defined limit stored in said information database; and

iii) control said actual LDH injection rate so as to correlate with said target LDH injection rate.

12. The method of claim 1 wherein said parameter values for LDH content and volatility are obtained in step (d) of claim 1 upstream of said injection unit, further comprising:

a) obtaining or calculating a resulting LDH content and resulting volatility of said diluent stream downstream of said LDH injection unit;

b) associating in an information database said resulting LDH content and resulting volatility with a time point to provide associated temporal data;

c) recording said associated temporal data in an informational database;

d) periodically repeating steps (a), (b) and (c) of this claim 10.

13. The method of claim 12 wherein said time point is received in said information database from an external source.

14. The method of claim 1, further comprising providing a pipeline comprising two or more sequential batches of differing petroleum products, wherein at least one of said batches comprises said diluent stream.

15. The method of claim 14 wherein said diluent stream is associated with a stream batch code, further comprising:

a) providing an informational database on which are stored said diluent batch code;

b) providing one or more information processing units logically programmed to;

i) halt or permit injection of LDH through said injection unit;

ii) obtain and compare said stream batch code and said diluent batch code; and

iii) when said stream and diluent batch codes match, permit injection of LDH into said diluent stream.

16. The method of claim 1 wherein:

i) said method is performed at a diluent storage and distribution facility;

ii) said facility comprises a pooled supply of diluent that is upstream and in fluid communication with said LDH injection unit, and downstream and in fluid communication with one or more incoming diluent streams; and

iii) measuring one or more attributes of said incoming diluent streams where the attribute is selected from volatility, density and LDH content.

17. The method of claim 1 for the controlled production and distribution of LDH enriched diluents so as not to violate pre-defined limits of LDH content and volatility comprising:

a) obtaining predefined limits for allowable LDH content and volatility;

b) measuring LDH content and volatility of said diluent stream upstream of said injection unit;

c) calculating a target rate of injecting LDH into said diluent stream based upon the so as not to violate the foregoing pre-defined limits;

d) injecting LDH into the diluent stream from the LDH injection unit at a pressure greater than said diluent stream pressure, and an actual injection rate less than or equal to said target rate calculated in step (c);

e) periodically repeating steps (b) and (c) and adjusting the injection rate in step (d) based upon the most recent calculation from step (c);

f) measuring the density of said diluent stream downstream of said injection unit; and

g) recording the density from step (f) in an informational database.

27. The method of claim 26 wherein said second LDH content and second volatility are calculated based upon said target LDH injection rate calculated in step (e) of claim 16 or said actual LDH injection rate in step (f) of claim 21, said diluent flow rate, and said LDH content of said diluent stream upstream of said LDH injection unit.

30. A method of reducing the viscosity of crude oil comprising blending said crude oil with LDH enriched diluent produced by the method of claim 1, 18, or 21.

31. The method of claim 1 wherein the butane content of said diluent stream after said LDH injection step (f) is between 5.0% and 7.0%.

18. A method for the controlled production and distribution of a LDH enriched diluent stream so as not to violate pre-defined limits for LDH content, volatility and density, comprising:

a) providing a diluent stream having a flow rate, pressure, LDH content, volatility and density;

b) providing a variable rate LDH injection unit in fluid connection with said diluent stream;

c) optionally providing a LDH injection unit in fluid connection with said LDH injection unit and said diluent stream;

d) obtaining respective parameter values for the LDH content and volatility upstream of said injection unit;

e) obtaining respective parameter values for the density and flow rate of said diluent stream downstream of said injection unit;

f) calculating a target rate of injecting LDH into said diluent stream based upon the parameter values for the flow rate, LDH content, volatility and density, in steps (d) and (e), so as not to violate the foregoing pre-defined limits for LDH content, volatility and density;

g) injecting LDH into the diluent stream from the LDH injection unit at a pressure greater than said diluent stream pressure, and an actual injection rate less than or equal to the target rate calculated in step (f); and

a) periodically repeating steps (d), (e) and (f), and adjusting the injection rate in step (g) based upon the most recent calculation from step (f),

wherein the API gravity of said diluent stream after said LDH injection step (f) is between 46 and 86, and the LDH content of said diluent stream after said LDH injection step (g) is between 5.0% and 7.0%.

19. The method of claim 18 further comprising:

a) obtaining or calculating a resulting LDH content and resulting volatility of said diluent stream downstream of said LDH injection unit;

b) associating in an informational database said density, resulting LDH content and resulting volatility with a time point to provide associated temporal data;

c) recording said associated temporal data in an informational database; and

d) periodically repeating steps (a), (b) and (c).

20. The method of claim 18 wherein:

i) said method is performed at a diluent storage and distribution facility;

ii) said facility comprises a pooled supply of diluent that is upstream and in fluid communication with said LDH injection unit, and downstream and in fluid communication with one or more incoming diluent streams; and

iii) measuring one or more attributes of said incoming diluent streams selected from volatility, density and LDH content.

32. The method of claim 18 wherein the butane content of said diluent stream after said LDH injection step (g) is between 5.0% and 7.0%.

21. A method for the controlled production and distribution of a LDH enriched diluent stream so as not to violate pre-defined limits for LDH content, comprising:

a) providing a diluent stream having a flow rate, pressure, LDH content, volatility and density;

b) providing a variable rate LDH injection unit in fluid connection with said diluent stream;

c) optionally providing a petroleum/diluent blending unit in fluid connection with said LDH injection unit and said diluent stream;

d) obtaining respective parameter values for the LDH content and flow rate upstream of said diluent stream;

e) calculating a target rate of injecting LDH into said diluent stream based upon the flow rate and LDH content obtained in step (d), so as not to violate the foregoing pre-defined limits for LDH content;

f) injecting LDH into the diluent stream from the LDH injection unit at an actual injection rate less than or equal to said target rate calculated in step (e); and

g) periodically repeating steps (d) and (e) and adjusting the injection rate in step (f) based upon the most recent calculation from step (e),

wherein the API gravity of said diluent stream after said LDH injection step (f) is between 46 and 86, and the LDH content of said diluent stream after said LDH injection step (f) is between 5.0% and 7.0%.

22. The method of claim 21 wherein:

i) said LDH content is obtained in step (d) upstream of said injection unit; and

ii) said flow rate is obtained in step (d) downstream of said LDH injection unit.

23. The method of claim 21 wherein in step (d):

i) a parameter value for said LDH content is obtained by measuring the LDH content of said diluent stream; and

ii) a parameter value for said flow rate is obtained by receiving a flow rate measurement from an external source.

24. The method of claim 21 wherein in step (d) a parameter value for said LDH content is obtained by measuring the LDH content of said diluent steam using liquid chromatography.

25. The method of claim 21 further comprising:

a) providing an informational database on which is stored said pre-defined limit;

b) providing one or more information processing units logically programmed to;

i) receive parameter values for said flow rate and LDH content of said diluent stream;

ii) calculate said target LDH injection rate based upon said LDH content and flow rate and said pre-defined limit stored in said one or more informational databases; and

iii) control said actual LDH injection rate so as to match said target LDH injection rate.

26. The method of claim 21 wherein a parameter value for said LDH content is obtained in step (c) of claim 21 upstream of said injection unit, further comprising:

a) obtaining a parameter value for or calculating a resulting LDH content of said diluent stream downstream of said LDH injection unit;

b) associating in an informational database said resulting LDH content with a time point to provide associated temporal data;

c) recording said associated temporal data in an informational database; and

d) repeating steps (a), (b) and (c) of this claim 26 whenever said injection rate is adjusted in step (g) of claim 21.

28. The method of claim 26 wherein said time point is received in said informational database from an external source.

29. The method of claim 21 wherein:

i) Said method is performed at a diluent storage and distribution facility;

ii) Said facility comprises a pooled supply of diluent that is upstream and in fluid communication with said LDH injection unit, and downstream and in fluid communication with one or more incoming diluent streams; and

iii) Measuring ore or more attributes of said incoming diluent streams selected from volatility, density and LDH content.

33. The method of claim 21 wherein the butane content of said diluent stream after said LDH injection step (f) is between 5.0% and 7.0%.