Method and system for producing pipeline quality natural gas

• US 9,649,591 B2
• Filed: 01/30/2015
• Issued: 05/16/2017
• Est. Priority Date: 01/31/2014
• Status: Active Grant

• Current Assignee: Larry Lien
• Original Assignee: Larry Lien
• Inventors: Lien, Larry
• Primary Examiner(s): Nguyen, Tam M
• Application Number:
  US14/609,565
• Publication Number:
  US 20150217224A1
• Time in Patent Office: 837 Days
• Field of Search: None
• CPC Class Codes: B01D 2053/221 Devices
• CPC Class Codes: B01D 2311/02 Specific process operations before starting the membrane separation process
• CPC Class Codes: B01D 2315/10 Cross-flow filtration
• CPC Class Codes: B01D 2323/46 Impregnation
• CPC Class Codes: B01D 53/228 characterised by specific membranes
• CPC Class Codes: B01D 67/0088 Physical treatment with compounds, e.g. swelling, coating or impregnation
• CPC Class Codes: B01D 71/34 Polyvinylidene fluoride
• CPC Class Codes: C10L 3/101 Removal of contaminants

Abstract

A method and system for recovering natural gas liquids (NGLs) from hydrocarbon mixtures and for producing a pipeline quality natural gas (NG) stream from a NG stream with a BTU content greater than about 1100 BTU per standard cubic foot. An NG or petroleum gas stream containing NGLs is delivered to a crossflow semipermeable membrane filtration apparatus wherein the semipermeable membrane is wetted with an organic liquid to render the membrane oleophilic. The NG stream is delivered at a pressure of at least about 150 psig. NGLs permeate through the wetted oleophilic membrane at a backpressure of at least 120 psig and maintain the desirable membrane characteristics; they are collected as liquids at a pressure of at least about 15 psig. A pipeline quality, primarily methane retentate stream of not greater than about 1050 BTU/scf is produced.

Claims

1. A method for producing a pipeline quality natural gas (NG) stream from a NG stream with a BTU content greater than about 1100 BTU per standard cubic foot (scf), which method comprises:

providing such a natural gas stream containing natural gas liquids (NGLs),

providing a cross flow semipermeable membrane apparatus which has an inlet, a retentate outlet and a permeate outlet,

wetting the semipermeable membrane in the cross flow membrane apparatus with an organic liquid to render the membrane oleophilic,

delivering said stream at a pressure of at least about 150 psig (11.2 atm) to the inlet of the cross flow apparatus wherein said stream is exposed to said wetted oleophilic membrane, causing NGLs to permeate through said membrane,

removing NG retentate from the retentate outlet of the apparatus as a primarily methane stream having a BTU content not greater than 1050 BTU/scf, and

collecting permeating liquid NGLs exiting via the permeate outlet while maintaining a backpressure of at least 120 psig (9.2 atm) on the permeate outlet to preserve the oleophilic character of said wetted membrane.

2. The method of claim 1 wherein the permeate outlet is connected to a collection container and the pressure within the container is maintained at least about 15 psig (2 atm).

3. The method of claim 1 wherein the semipermeable membrane is a polymeric membrane.

4. The method of claim 1 wherein the membrane is a polymeric fluorocarbon.

5. The method of claim 4 wherein the membrane is a polyvinylidene difluoride (PVDF).

6. The method of claim 1 wherein the membrane is a polyimide, a polysulfone (PS or PES), a polyether ketone (PEK), or a polydimethylsiloxane (PDMS) on a PS base.

7. The method of claim 1 wherein the membrane is wetted with an organic liquid having a viscosity of not greater than about 2000 cps.

8. The method of claim 7 wherein the membrane is wetted with a hydrocarbon.

9. The method of claim 7 wherein the membrane is wetted with diesel fuel.

10. The method of claim 7 wherein the membrane is wetted with diesel fuel by feeding the diesel fuel into the inlet.

11. A method for removing natural gas liquids (NGLs) from a natural gas (NG) stream, which method comprises:

providing such a natural gas stream containing NGLs,

providing a cross flow semipermeable membrane apparatus which has an inlet, a retentate outlet and a permeate outlet,

wetting the semipermeable membrane in the cross flow membrane apparatus with an organic liquid to render the membrane oleophilic,

delivering said stream at an inlet pressure of at least about 150 psig (11.2 atm) to the inlet of the cross flow apparatus wherein said stream is exposed to said wetted oleophilic membrane, causing NGLs to permeate through said membrane,

removing NG retentate from the retentate outlet of the apparatus as a primarily methane stream, and

collecting permeating liquid NGLs exiting via the permeate outlet while maintaining a backpressure less than the inlet pressure of at least about 120 psig (9.2 atm) an the permeate outlet to preserve the oleophilic character of said wetted membrane.