Organic electroluminescent device

• US 9,650,245 B2
• Filed: 06/08/2007
• Issued: 05/16/2017
• Est. Priority Date: 08/09/2002
• Status: Active Grant

• Current Assignee: Semiconductor Energy Laboratory Co., Ltd.
• Original Assignee: Semiconductor Energy Laboratory Co., Ltd.
• Inventors: Tsutsui, Tetsuo
• Primary Examiner(s): VETERE, ROBERT A
• Application Number:
  US11/811,437
• Publication Number:
  US 20070243786A1
• Time in Patent Office: 3,630 Days
• Field of Search: 427 64, 427 66- 68
• CPC Class Codes: B82Y 20/00 Nanooptics, e.g. quantum optics or photonic crystals
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: H10K 50/11 characterised by the electroluminescent [EL] layers
• CPC Class Codes: H10K 50/18 Carrier blocking layers
• CPC Class Codes: H10K 50/19 Tandem OLEDs
• CPC Class Codes: H10K 71/841 Applying alternating current [AC] during manufacturing or treatment
• CPC Class Codes: Y10S 428/917 Electroluminescent

Abstract

An organic EL device that has good yields and high reliability as well as high current efficiency is provided by introducing the new concept to the conventional organic EL device structure. An EL device comprising a first electrode 101, a second electrode 102, an electroluminescent layer 103, conductive particles 104, wherein conductive particles 104 are dispersed in the EL layer 103, is used. Current efficiency will be increased since conductive particles serve as the conventional charge generation layer. In addition, fabricating processes will become simplified and fabricating costs will be reduced because the conductive particles and the EL layer can be formed simultaneously.

Claims

1. A method for manufacturing an organic electroluminescent device comprising:

forming a first electrode over a first plastic substrate;

mixing a first organic compound a second organic compound, and a metal particle into a solvent to prepare a first solution;

forming a first electroluminescent layer over the first plastic substrate provided with the first electrode by applying the first solution on the first electrode so that the metal particle is surrounded by a bipolar layer comprising the first organic compound and the second organic compound;

forming a second electrode over a second plastic substrate;

bonding the second plastic substrate provided with the second electrode to the first plastic substrate provided with the first electrode so that the first electroluminescent layer is interposed between the first electrode and the second electrode to form a bonded substrate,

wherein a hole transporting property is higher than an electron transporting property in the first organic compound,

wherein an electron transporting property is higher than a hole transporting property in the second organic compound,

wherein the metal particle injects a hole and an electron to the bipolar layer by applying an alternative current so that the bipolar layer emits light.

2. A method for manufacturing an organic electroluminescent device according to claim 1, further comprising:

forming a first insulating layer between the first electrode and the first electroluminescent layer for preventing a carrier injection from the first electrode to the first electroluminescent layer, and

forming a second insulating layer for preventing a carrier injection from the first electrode to the first electroluminescent layer over the second electrode.

3. A method for manufacturing an organic electroluminescent device according to claim 1, wherein the metal particle has an average diameter of 2 nm to 50 nm.

4. A method for manufacturing an organic electroluminescent device according to claim 1, further comprising:

fitting a lead wiring with the first electrode and the second electrode.

5. A method for manufacturing an organic electroluminescent device according to claim 1, further comprising:

mixing the first organic compound, the second organic compound, and a conductive particle into a solvent to prepare a second solution; and

forming a second electroluminescent layer over the second plastic substrate provided with the second electrode by applying the second solution over the second electrode.

6. A method for manufacturing an organic electroluminescent device according to claim 1, wherein the first plastic substrate comprise polyester or polyimide.

7. A method for manufacturing an organic electroluminescent device according to claim 1, further comprising:

forming a spacer film on a periphery portion of the first plastic substrate; and

heating the bonded substrate.

8. A method for manufacturing an organic electroluminescent device according to claim 1, wherein the metal particle comprises one of gold and silver.

9. A method for manufacturing an organic electroluminescent device comprising:

forming a first electrode over a substrate;

forming a layer comprising a first organic compound, a second organic compound, and metal particles over the first electrode; and

forming a second electrode over the layer,

wherein the metal particles are surrounded by a bipolar layer comprising the first organic compound and the second organic compound,

wherein a hole transporting property is higher than an electron transporting property in the first organic compound, and

wherein an electron transporting property is higher than a hole transporting property in the second organic compound,

wherein the metal particle injects a hole and an electron to the bipolar layer by applying an alternative current so that the bipolar layer emits light.

10. A method for manufacturing an organic electroluminescent device according to claim 9, wherein the metal particle comprises one of gold and silver.