Toner and two-component developer

• US 9,665,026 B2
• Filed: 07/27/2016
• Issued: 05/30/2017
• Est. Priority Date: 09/20/2013
• Status: Active Grant

• Current Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Original Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Inventors: Kaneko, Hideki, Iwasaki, Yosuke, Komatsu, Nozomu, Takenaka, Kohji, Hashimoto, Takeshi, Kanno, Ichiro, Fujikawa, Hiroyuki, Kobori, Takakuni
• Primary Examiner(s): LE, HOA VAN
• Application Number:
  US15/220,594
• Publication Number:
  US 20160334728A1
• Time in Patent Office: 307 Days
• CPC Class Codes: G03G 9/0831 Chemical composition of the magnetic components
• CPC Class Codes: G03G 9/0837 Structural characteristics of the magnetic components, e.g. shape, crystallographic structure
• CPC Class Codes: G03G 9/09708 Inorganic compounds
• CPC Class Codes: G03G 9/09716 treated with organic compounds
• CPC Class Codes: G03G 9/09725 Silicon-oxides; Silicates
• CPC Class Codes: G03G 9/1085 with non-ferrous metal oxide, e.g. MgO-Fe2O3
• CPC Class Codes: G03G 9/1131 Coating methods; Structure of coatings
• CPC Class Codes: G03G 9/1133 obtained by reactions only involving carbon-to-carbon unsaturated bonds

Abstract

Provided are a toner and a two-component developer each of which: shows a small fluctuation in charge quantity and a small fluctuation in image density even under a high-temperature and high-humidity environment; and does not cause any member contamination even after endurance and hence can stably output an image. The toner and the two-component developer each have a feature in that positively chargeable strontium titanate fine particles are added to toner particles having fixed thereto negatively chargeable silica fine particles.

Claims

1. An image forming method comprising a step of developing with a developer containing a toner, the toner comprising:

toner particles each of which contains a binder resin, a wax, and a coloring agent;

negatively chargeable silica fine particles A on surfaces of the toner particles, the silica fine particles A having a number-average particle diameter (D1) of 60 to 300 nm, and an amount of the silica fine particles A is 2.0 parts by mass or more and 10.0 parts by mass or less when an amount of the toner particles is set to 100 parts by mass,

positively chargeable strontium titanate fine particles B adhering to the silica fine particles A electrostatically, the strontium titanate fine particles B have a fixing rate of 0.10 to 0.60, and an amount of the strontium titanate fine particles B is 0.2 part by mass or more and 1.0 part by mass or less when an amount of the toner particles is set to 100 parts by mass, wherein

Y/X is 0.75 or more, where a coverage rate of the surfaces of the toner particles with the silica fine particles A is X (%), X being 20 to 95%, and a coverage rate with the silica fine particles A fixed to the surfaces of the toner particles is Y (%),

the step of developing includes a step of peeling the silica fine particles A and the strontium titanate fine particles B to increase a charge quantity of the toner.

2. The image forming method according to claim 1, wherein surfaces of the silica fine particles A are treated with one of hexamethyldisilazane and a silicone oil, and

surfaces of the strontium titanate fine particles B are treated with one of a fatty acid and a fatty acid metal salt.

3. The image forming method according to claim 1, wherein primary particles of the strontium titanate fine particles B have a number-average particle diameter of 30 to 300 nm, and

the strontium titanate fine particles B each have a perovskite crystal, and particle shapes of the strontium titanate fine particles B each have one of a cubic shape, a rectangular parallelepiped shape, and a mixture thereof.

4. The image forming method according to claim 1, wherein the silica fine particles A have a number-average particle diameter (D1) of 70 to 280 nm.

5. The image forming method according to claim 1, wherein the developer is a two-component developer comprising the toner and a magnetic carrier.

6. The image forming method according to claim 5, wherein the magnetic carrier has a carrier core, a surface of the carrier core is covered with a copolymer, and the copolymer contains, as copolymerization components:

a monomer having a structure represented by the following formula (1);