Multi nitrogen expansion process for LNG production

• US 9,671,160 B2
• Filed: 10/22/2012
• Issued: 06/06/2017
• Est. Priority Date: 10/21/2011
• Status: Active Grant

• Current Assignee: Single Buoy Moorings of America Incorporated (Single Buoy Moorings)
• Original Assignee: Single Buoy Moorings of America Incorporated (Single Buoy Moorings)
• Inventors: Wyllie, Michael, Criminisi, Francesco
• Primary Examiner(s): RAYMOND, KEITH MICHAEL
• Application Number:
  US14/352,827
• Publication Number:
  US 20140245780A1
• Time in Patent Office: 1,688 Days
• CPC Class Codes: F25J 1/0022 Hydrocarbons, e.g. natural gas
• CPC Class Codes: F25J 1/0042 by liquid expansion with extraction of work
• CPC Class Codes: F25J 1/005 by expansion of a gaseous refrigerant stream with extraction of work
• CPC Class Codes: F25J 1/0052 by vaporising a liquid refrigerant stream
• CPC Class Codes: F25J 1/0057 after expansion of the liquid refrigerant stream with extraction of work
• CPC Class Codes: F25J 1/0072 Nitrogen
• CPC Class Codes: F25J 1/0204 as a single flow SCR cycle
• CPC Class Codes: F25J 1/0283 Gas turbine as the prime mechanical driver
• CPC Class Codes: F25J 1/0288 using work extraction by mechanical coupling of compression and expansion of the refrigerant, so-called companders
• CPC Class Codes: F25J 1/0294 Multiple compressor casings/strings in parallel, e.g. split arrangement
• CPC Class Codes: F25J 2220/62 Separating low boiling components, e.g. He, H2, N2, Air
• CPC Class Codes: F25J 2270/14 External refrigeration with work-producing gas expansion loop
• CPC Class Codes: F25J 2270/16 with mutliple gas expansion loops of the same refrigerant
• CPC Class Codes: F25J 2270/42 Quasi-closed internal or closed external nitrogen refrigeration cycle

Abstract

A method of natural gas liquefaction includes at least two nitrogen refrigerant streams. Each stream undergoes a cycle of compression, cooling, expansion and heating, during which each of the nitrogen streams is expanded to a different pressure other than for the others of the at least two nitrogen streams, and,

the heating occurs in one or more heat exchangers.

The expanded nitrogen streams are in a heat exchanging relationship with a stream of the natural gas and with the one or more compressed nitrogen streams in at least one of the one or more heat exchangers. At least one expanded nitrogen stream is compressed as a side stream in a stage of a main nitrogen compressor so as to combine the compressed side stream with another compressed nitrogen stream after passing the nitrogen compressor stage.

Claims

1. A method of natural gas liquefaction comprising at least two nitrogen refrigerant streams, each of said at least two nitrogen streams undergoing a cycle of compression, cooling, expansion and heating, during which each of the at least two nitrogen streams is expanded to a different pressure than the others of the at least two nitrogen streams, and, the heating occurs in one or more heat exchangers;

the at least two expanded nitrogen streams being in a heat exchanging relationship with a stream of the natural gas and with the at least two compressed nitrogen streams in at least one of said one or more heat exchangers, wherein at least one of said at least two expanded nitrogen streams, after having been in said heat exchanging relationship in the at least one of the one or more heat exchangers, is compressed as a side stream in a stage of a main nitrogen compressor comprising at least two compressor stages, a first compressor stage (22) and a second compressor stage (23), and wherein an outlet of the first compressor stage (22) is coupled to an inlet of the second compressor stage (23) in such a way that a compressor outlet stream from a low pressure turbo expander (L) after being pressurized in the first compressor stage (22) is added to a compressor outlet stream from a high pressure turbo expander (H) before the inlet of the second compressor stage (23) so as to combine the compressed side stream with another compressed nitrogen stream after passing said nitrogen compressor stage.

2. The method according to claim 1, wherein the main nitrogen compressor comprises at least two compressors coupled on a common drive shaft.

3. The method according to claim 1, wherein a compressed nitrogen stream from the compressor stages is divided over at least two parallel placed expanders to different pressure levels.

4. The method according to claim 3, wherein each expander is connected over a common drive shaft to a compressor for compressing a nitrogen flow.

5. The method according to claim 1, wherein the main nitrogen compressor is gas turbine driven or electric motor driven or steam turbine driven.

6. The method according to claim 1, wherein the expansion comprises a high pressure, an intermediate pressure and a low pressure expansion stage in a respective expander.

7. The method according to claim 1, wherein the main nitrogen compressor comprises three compressor stages and receives two side streams with different pressures.

8. The method according to claim 7, wherein the three compressors are coupled on a common drive shaft.

9. The method according to claim 1, wherein a third expander which is a Joule-Thompson valve is placed parallel with said low pressure and high pressure turbo expanders.

10. A natural gas liquefaction apparatus comprising a heat exchanger system of one or more heat exchangers for placing the natural gas in a heat exchanging relationship with multiple nitrogen refrigerant streams;

at least two compressors for compressing a first and an at least second nitrogen refrigerant stream;

a first turbo expander comprising a first expander for expanding the first nitrogen stream to a first pressure, and at least a second turbo expander comprising a second expander for expanding the at least second nitrogen stream to an at least second, lower pressure than the first pressure, wherein the apparatus further comprises a main nitrogen compressor with at least two compressor stages, each compressor stage being arranged for receiving an associated nitrogen stream, wherein an outlet of a first compressor stage (22) is coupled to an inlet of a second compressor stage (23) in such a way that a compressor outlet stream from the low pressure turbo expander (L) after being pressurized in the first compressor stage (22) is added to a compressor outlet stream from the high pressure turbo expander (H) before the inlet of the second compressor stage (23) and wherein each nitrogen stream has a different pressure other than the other of the at least two nitrogen streams, one nitrogen stream being a side stream which will be combined with the other nitrogen stream.

11. The apparatus according to claim 10, wherein the one nitrogen stream is combined with the other nitrogen stream after passing the first compressor stage and before entry of the other nitrogen stream into the second compressor stage.

12. The apparatus according to claim 10, wherein the main nitrogen compressor comprises at least two compressors coupled on a common drive shaft.

13. The apparatus according to claim 10, wherein the compressed nitrogen stream from the main nitrogen compressor is divided over at least two parallel placed expanders to different pressure levels.

14. The apparatus according to claim 12, wherein each expander is connected over a common drive shaft to a compressor arranged for compressing a nitrogen flow.

15. The apparatus according to claim 14, wherein at least one compressor receives and compresses at least a part of the nitrogen stream that passed the heat exchanger system before said part of the nitrogen stream flows to the main nitrogen compressor.

16. The apparatus according to claim 11, wherein the main nitrogen compressor unit is gas turbine driven or electric motor driven or steam turbine driven.

17. The apparatus according to claim 11, wherein the first and at least second expander comprise a high pressure, an intermediate pressure and a low pressure expansion stage in a respective expander.

18. The apparatus according to claim 11, wherein the main nitrogen compressor comprises three compressors and receives two side streams with different pressures.

19. The apparatus according to claim 18, comprising a third expander placed parallel with said first and second turbo expander, wherein said third expander is a Joule-Thompson valve.